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Architecture of new Concave Host Molecules

  • F. Vögtle
  • C. Seel
  • R. Berscheid
  • J. Groß
  • P.-M. Windscheif
Chapter
Part of the NATO ASI Series book series (ASIC, volume 426)

Abstract

Two new types of multiply bridged cyclophanes with intramolecular cavity have been designed and prepared. Macrobicyclic tris(diynes) like 1 and 2 with relatively rigid and large hydrophobic cavity form crystalline inclusion complexes with nitriles. The related bis-(triphenylmethyl) dication 7 can be considered as a concave dye. The spherical hydrocarbon C36H36 (10) forms a 1:1 complex with silver tritiate.

Keywords

Supramolecular Chemistry C36H36 Molecule Macrocyclic Host Phenyl Lithium Silver Triflate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 1994

Authors and Affiliations

  • F. Vögtle
    • 1
  • C. Seel
    • 1
  • R. Berscheid
    • 1
  • J. Groß
    • 1
  • P.-M. Windscheif
    • 1
  1. 1.Institut für Organische Chemie Biochemie der UniversitätGermany

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