Abstract
In this review the concept of immobilizing electrophilic centers in synthetic cyclic and acyclic (clefts) receptors will be described. Our first attempts using first-row transition metals did not lead to the desired receptors but resulted in hetero-di- and hetero-trinuclear complexes. The properties will be discussed. The use of the uranyl cation (UO2 2+) gave metallocycles and -clefts which are able to complex both neutral polar molecules as anions. The synthesis, X-ray analysis, and complexation behavior will be discussed. Molecular mechanics calculations have been performed in order to rationalize the results.
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© 1994 Springer Science+Business Media Dordrecht
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van Veggel, F.C.J.M., van Hoorn, W.P., Reinhoudt, D.N. (1994). Metallocycles and -Clefts. In: Wipff, G. (eds) Computational Approaches in Supramolecular Chemistry. NATO ASI Series, vol 426. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1058-7_17
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