Skip to main content

Cage Effect and Molecular Dynamics of Cl2 in Rare Gas Solids

  • Conference paper
Reaction Dynamics in Clusters and Condensed Phases

Part of the book series: The Jerusalem Symposia on Quantum Chemistry and Biochemistry ((JSQC,volume 26))

Abstract

Over the past few years, a strong interest has developed for the study of elementary photochemistry of small molecules embedded in rare gas crystals. This stems from the fact that such systems are considered as models for condensed phase photochemistry and are more easily amenable to computer simulations. In addition, laser applications are foreseen.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Schwentner, N., Chergui, M., (1992) “Photochemistry, Charge Transfer States and Laser Applications of Small Molecules in Rare Gas Crystals” in Optical Properties of Excited States of Solids, ed.: B. Di Bartolo (Plenum Press, New York), 499–524 and references therein Chergui, M., Schwentner, N. (1993) “Cage effect on the photodissociation of small molecules in van der Waals clusters and crystals” in Research Trends: Chemical Physics, ed.: J. Menon (Trivandum, India) and references therein

    Chapter  Google Scholar 

  2. Harris, A.L., Brown, J.K., and Harris, C.B. (1988) “The Nature of simple photodissociation reactions in Liquids on ultrafast time scales” Ann. Rev. Phys. Chem. 39, 341–366 and references therein

    Article  CAS  Google Scholar 

  3. Bondybey, V.E., Fletcher, C. (1976) “Photophysics of low lying Electronic states of Cl2 in rare gas solids”, J. Chem. Phys. 64, 3615–3620

    Article  CAS  Google Scholar 

  4. Kunz, H. (1991) “Photodissoziation von Cl2 in Edelgasmatrizen und spektroskopische Untersuchung der Dissoziationsfragmente”, thesis, FU Berlin

    Google Scholar 

  5. Peyerimhoff, S.D. and Buenker, R.J. (1991) “Electronically excited and ionized states of the Chlorine Molecule”, Chem. Phys. 57, 279–296

    Article  Google Scholar 

  6. Kunz, H., McCaffrey, J.G., Schriever, R., and Schwentner, N. (1991) “Spectroscopy and photodissociation of molecular chlorine in argon matrices”, J. Chem. Phys. 94, 1039–1045

    Article  CAS  Google Scholar 

  7. McCaffrey, J.G., Kunz, H., and Schwentner, N. (1992) “Spectroscopy and photodissociation of chlorine monomers and clusters in argon matrices”, J. Chem. Phys. 96, 155–164

    Article  CAS  Google Scholar 

  8. Alimi, R., Gerber, R.B., McCaffrey, J.G., Kunz, H., and Schwentner, N. (1992) “Delayed and direct cage exit in photodissociation of Cl2 in solid Ar”, Phys. Rev. Lett. 69, 856–

    Article  CAS  Google Scholar 

  9. Fajardo, M.E., Withnall, R., Feld, J., Okada, F., Lawrence, W., Wiedemann, L., and Apkarian, V.A. (1988) “Condensed phase laser induced harpoon reactions”, Laser Chemistry, 9, 1–12

    Article  CAS  Google Scholar 

  10. Fajardo, M.E. and Apkarian, V.A. (1988) “Charge Transfer Photodynamics in Halogen Doped Xenon Matrices II: Photoinduced Harpooning and the Delocalized Charge Transfer States of Solid Xenon Halides (F, Cl, Br)”, J. Chem. Phys. 89, 4102–4123

    Article  CAS  Google Scholar 

  11. McCaffrey, J.G., Kunz, H., and Schwentner, N. (1992) “Photodissociation of molecular chlorine in Xe matrices”, J. Chem. Phys. 96, 2825–2833

    Article  CAS  Google Scholar 

  12. Gersonde, I.H., and Gabriel, H. (1993) “Molecular dynamics of photodissociation in matrices including nonadiabatic processes”, J. Chem. Phys. 98, 2094–2106

    Article  CAS  Google Scholar 

  13. Alimi, R., Brokman, A. and Gerber, R.B. (1989) “Molecular dynamics simulations of reactions in solids: Photodissociation of Cl2 in crystalline Xe”, J. Chem. Phys. 91, 1611–1617

    Article  CAS  Google Scholar 

  14. Hoffmann, J. and Apkarian, V.A. (1991) “Photodynamics of (Cl2)n clusters trapped in Solid Krypton”, J. Phys. Chem. 95, 5372–5374

    Article  Google Scholar 

  15. Kunz, H., McCaffrey, J.G., Chergui, M., Schriever, R., Ünal, Ö., Stepanenko, V., and Schwentner, N. (1991) “Rydberg series of charge transfer excitations: Cl and H in rare gas crystals”, J. Chem. Phys. 95, 1466–1472

    Article  CAS  Google Scholar 

  16. Chergui, M., Schwentner, N., Böhmer, W. (1986) “Rydberg states of NO in rare gas matrices”, J. Chem. Phys. 85, 2472–2482

    Article  CAS  Google Scholar 

  17. Bondybey, V.E., Brus, L.E. (1980) “Nonradiative processes in small molecules in low—temperature solids”, Adv. Chem. Phys. 41, 260–320

    Google Scholar 

  18. Roncin, J.Y. (1968) “Electronic Transitions of CO, N2 and NO Molecules trapped in Solid Rare gas Matrices: Qualitative Discussion”, J. Mol. Spect. 26, 105–110

    Article  CAS  Google Scholar 

  19. Robinson, G.W. (1967) “Intensity Enhancement of Forbidden Electronic Transitions by Weak Intermolecular Interactions”, J. Chem. Phys. 46, 572–585

    Article  CAS  Google Scholar 

  20. Gürtler, P., Kunz, H., Le Calve, J. (1989) “Vacuum ultraviolet spectroscopy of the Cl2 molecule trapped in pure neon, pure argon or mixed neon—argon matrices”, J. Chem. Phys. 91, 6020–6028

    Article  Google Scholar 

  21. Chergui, M. Schwentner, N. (1992) “Rydbergvalence perturbations in matrix-isolated NO”, J. Chem. Phys. 97, 2881–2890

    Article  CAS  Google Scholar 

  22. Chergui, M., Gödderz, K.H., Schriever, R., Schwentner, N., Stepanenko, V. “Absorption by dissociative continua of matrix—isolated molecules: H2O and HCl”, J. Chem. Phys. (submitted)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer Science+Business Media Dordrecht

About this paper

Cite this paper

Schwentner, N., Chergui, M., Kunz, H., McCaffrey, J. (1994). Cage Effect and Molecular Dynamics of Cl2 in Rare Gas Solids. In: Jortner, J., Levine, R.D., Pullman, B. (eds) Reaction Dynamics in Clusters and Condensed Phases. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 26. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0786-0_35

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-0786-0_35

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4337-3

  • Online ISBN: 978-94-011-0786-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics