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NMR Characterization of Solid Fossil Fuels. Coal and Oil Shale

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Nuclear Magnetic Resonance in Modern Technology

Part of the book series: NATO ASI Series ((ASIC,volume 447))

Abstract

1H and 13C NMR experiments based on magic-angle spinning (MAS) and other techniques are enormously useful in the characterization of coals and oil shales, even though the level of chemical shift resolution achieved is limited. The most popular technique 13C CP-MAS, is easy and efficient, but requires detailed characterization of the relevant spin dynamics for quantitation. 13C MAS experiments that rely on direct polarization (DP) via 13C spin-lattice relaxation (DP-MAS) are more time consuming, but quantitative determinations are more straightforward. Large-volume MAS rotors render quantitation in 13C experiments by both CP-MAS and DP-MAS techniques, as well as 1H-13C dipolar-dephasing elucidation of CH and CH2 groups, more routinely feasible.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Colorado State University, Fort Collins, Colorado, 80523, USA

    Gary E. Maciel

  2. Chemistry Department, Çukurova University, Adana PKI, Turkey

    Oktay Erbatur

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  1. Gary E. Maciel
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  2. Oktay Erbatur
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Editors and Affiliations

  1. Department of Chemistry, Colorado State University, Fort Collins, Colorado, USA

    Gary E. Maciel

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© 1994 Springer Science+Business Media Dordrecht

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Maciel, G.E., Erbatur, O. (1994). NMR Characterization of Solid Fossil Fuels. Coal and Oil Shale. In: Maciel, G.E. (eds) Nuclear Magnetic Resonance in Modern Technology. NATO ASI Series, vol 447. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0756-3_8

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  • DOI: https://doi.org/10.1007/978-94-011-0756-3_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4325-0

  • Online ISBN: 978-94-011-0756-3

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