Abstract
The role of multinuclear NMR, especially 1H MAS spectroscopy, in studying acidic sites relevant to catalysis is examined, especially for zeolites. The relationship between the chemical shift of a hydroxyl proton and its acidity is discussed The appearance of various kinds of Brönsted and Lewis acid sites of zeolites in 1H, 29Si and 27Al NMR spectra are examined, and comparisons are made to related IR data.
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References
J. E. Bartmess, J. A. Scott, R. T. McIver: J. Am. Chem. Soc. 101 (1979) 6046.
J. Sauer: J. Mol. Cat. 54 (1989) 312.
J. P. Chauvel, N. S. True: Chem. Phys. 95 (1985) 435.
R. W. Taft, I. A. Koppel, R. D. Topsom, F. Anvia: J. Am. Chem. Soc. 112 (1990) 2047.
R. T. Sanderson: Chemical Bonds and Bond Energy, Academic Press, New York 1976.
H. Pfeifer: Colloids and Surfaces 36 (1989) 312.
D. Freude, M. Hunger, H. Pfeifer, W. Schwieger: Chem. Phys. Lett. 128 (1986) 62.
H. Pfeifer, D. Freude, J. Kärger: Studies in Surface Sci. and Catalysis 65 (1991) 89.
H. Pfeifer, D. Freude, M. Hunger: Zeolites 5 (1985) 274.
H. Ernst: Z. Phys. Chemie, Leipzig 269 (1988) 1073.
E. Lippmaa, A. V. Samoson, V. V. Brey, Y. I. Gorlov: Doklady Akad. Nauk 259 (1981) 403.
G. Engelhardt, D. Michel: High-Resolution Solid-State NMR of Silicates and Zeolites, J. Wiley & Sons, New York, 1987.
P. A. Jacobs, W. J. Mortier: Zeolites 2 (1982) 226.
D. Freude, M. Hunger, H. Pfeifer, W. Schwieger: Chem. Phys. Lett. 128 (1986) 62.
V. M. Mastikhin, I. L. Mudrakovsky, A.V. Nosov: Bruker report 2 (1989), 18.
M. Hunger: Thesis (Prom. B), University of Leipzig 1991.
H. Pfeifer, W. Meiler, D. Deininger: Annual Reports on NMR Spectroscopy (Ed: G. A. Webb) 15 (1983) 291.
E. Brunner: J. Chem. Soc., Faraday Trans. 86 (1990) 3957.
E. Brunner, D. Freude, B. C. Gerstein, H. Pfeifer: J. Magn. Res. 90 (1990) 90.
C. A. Fyfe: Solid State NMR for Chemists, C.F.C. Press, Guelph 1983.
J. Böhm, D. Fenzke, H. Pfeifer: J. Magn. Res. 55 (1983) 197.
H. Pfeifer, D. Freude, J. Kärger: Studies in Surface Science and Catalysis (Eds. G. Öhlmann, H. Pfeifer, R. Fricke ) 65 (1991) 89.
S. Halik, J. A. Lercher, H. Mayer: J. Chem. Soc. Faraday Trans.I 84 (1988) 4457.
E. Brunner, H.-G. Karge, H. Pfeifer: Z. Phys. Chemie (in press).
J. Dwyer, J.Dewing, N. E. Thompson, P. J. O’Malley, K. Karim: J. Chem. Soc., Chem. Comm. (1989) 843.
R. R. Ernst, G. Bodenhausen, A. Wokaun: Principles of Nuclear Magnetic Resonance in One and Two Dimensions, Clarendon Press, Oxford 1986.
D. Fenzke, M. Hunger, H. Pfeifer: J. Magn. Res. 95 (1991) 477.
K.-P. Schröder, J. Sauer, M. Leslie, C. R. A. Catlow, J. M. Thomas: Chem. Phys. Lett. 188 (1992) 320.
A. Abragam: The Principles of Nuclear Magnetism, Oxford 1961.
T. J. Gluszak, D.T. Chen, S. B. Sharma, J. A. Dumesic, T. W. Root: Chem. Phys. Lett. 190 (1992) 36.
H. Rosenberger, H. Ernst, G. Scheler, I. Jünger, R. Sonnenberger: Z. phys. Chemie, Leipzig 263 (1982) 864.
M. Hunger, D. Freude, T. Fröhlich, H. Pfeifer, W. Schwieger: Zeolites 7 (1987) 108.
A. E. Hirschler: J. Catal. 2 1963 428
A. E. Hirschler: J. Catal. 2 (1963) 428;C. J. Plank, Proceedings of the Third International Congress on Catalyis, Amsterdam, 1964, Vol.1, p.568.
M. Hunger, D. Freude, H. Pfeifer, D. Prager, W. Reschetilowski: Chem. Phys. Lett. 163 (1989) 221.
J. Sauer: Proc. Int. Symp. Zeolite Catal., Siofok (Hungary), 1985, p.19.
J. Sauer, P. Hobza: Theor. Chim. Acta (Berlin) 65 (1984) 279 and 291.
M. Hunger, D. Freude, H. Pfeifer: J. Chem. Soc., Faraday Trans. 87 (1991) 657.
P. Batamack, C. Doremieux-Morin, J. Fraissard, D. Freude: J. Phys. Chem. 95 (1991) 3790.
L. M. Kustov, V. B. Kazanski: J. Chem. Soc. Faraday Trans. 87 (1991) 2675.
L. M. Kustov, V. B. Kazanski, S. Beran, L. Kubelkova, P. Jiru: J. Phys. Chem. 91 (1987) 5247.
J. Dwyer in W. Mortier et al. (Eds), Innovation in Zeolite Materials Science, Elsevier, Amsterdam 1998, p.333.
H. G. Karge in G. Öhlmann et al. (Eds.), Studies in Surface Science and Catalysis, Vol. 65, Elsevier 1991, 133.
E. Lippmaa, A. Samoson, J. Mägi: J. Am. Chem. Soc. 108 (1986) 1730.
L. Kellberg, M. Linsten, H. J. Jakobsen: Chem. Phys. Lett. 182 (1991) 120.
D. Müller, W. Gessner, H. J. Behrens, G. Scheler: Chem. Phys. Lett. 79 (1981) 59.
J. P. Gilson, G. C. Edwards, A. W. Peters, K. Rajagopalan, R. F. Wormsbecher, T. G. Roberie, M. P. Shatlock: J. Chem. Soc., Chem. Comm. (1987) 91.
J. Klinowski, C. A. Fyfe, G. C. Gobbi:J. Chem. Soc., Faraday Trans.I 81 (1985) 3003.
D. Freude, M. Hunger, H. Pfeifer: Z. Phys. Chemie NF 152 (1987) 171.
P. J. Grobet, H. Geerts, M. Tielen, J. A. Martens, P. A. Jacobs: Stud. Surface Sci. Catal. 46 (1989) 721.
A. Samoson, E. Lippmaa, G. Engelhardt, U. Lohse, H. G. Jerschkewitz: Chem. Phys. Lett. 134 (1987) 589.
D. E. Woessner, H. K. C. Timken: J. Magn. Res. 90 (1990) 411.
A. Samoson, A. Pines: Rev. Sci. Instr. 60 (1989) 3239.
G. E. Maciel, J. F. Haw, I. Chuang, B. L. Hawkins, T. A. Early, D. R. McKay, L. Petrakis: J. Am. Chem. Soc. 105 (1983) 5529.
J. A. Ripmeester: J. Am. Che. Soc. 105 (1983) 2925.
P. D. Majors, P. D. Ellis: J. Am. Che. Soc. 109 (1987) 1648.
D. Schulze, H. Ernst, D. Fenzke, W. Meiler, H. Pfeifer: J. Phys. Chem. 94 (1990) 3499.
J. H. Lunsford, W. P. Rothwell, V. Shen: J. Am. Chem. Soc. 107 (1985) 1540.
L. Baltusis, J. S. Frye, G. E. Maciel: J. Am. Chem. Soc. 109 (1987) 40.
A. Michael, W. Meiler, D. Michel, H. Pfeifer: Chem. Phys. Lett. 84 (1981) 30.
A. Michael, W. Meiler, D. Michel, H. Pfeifer, D. Hoppach, J. Delmau: J. Chem. Soc., Faraday Trans.I 82 (1986) 3053.
T. Wutscherk: Thesis, University of Leipzig 1990.
V. M. Mastikhin, J. L. Mudrakowsky, S. V. Filimonova: Chem. Phys. Lett: 149 (1988) 175.
J. H. Lunsford, P. N. Tutunjian, P. Chu, E. B. Yeh, D. J. Zalewski: J. Phys. Chem. 93 (1989) 2590.
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Pfeifer, H. (1994). Applications of NMR Spectroscopy to Surfaces and Catalysts: Acidic Sites and Adsorbed Species. In: Maciel, G.E. (eds) Nuclear Magnetic Resonance in Modern Technology. NATO ASI Series, vol 447. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0756-3_16
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