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Phase-Transfer Catalysis: Fundamentals II

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Phase-Transfer Catalysis

Abstract

Phase-transfer catalytic (PTC) systems are characterized by the presence of at least two phases and at least one interfacial region separating the phases [1–8]. Reactions taking place in such systems usually involve (1) transfer of an anionic reactant from its “normal” phase into the reaction phase or interfacial region, (2) reaction of the transferred anion with the nontransferred reactant located in the reaction phase or interfacial region, and (3) transfer of the anionic product from the reaction phase or interfacial region into its “normal” phase. Thus, PTC reactions involve several steps occurring in series and/or in parallel. As a consequence, a quantitative description of the entire process necessitates defining the reactions and corresponding rates taking place within each of the phases and within the interfacial region, and the rates of mass transfer of the reactant and product anions into and through the interfacial region.

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Authors and Affiliations

  1. Cimmaron Technical Associates, Tulsa, OK, 74119, USA

    Charles M. Starks

  2. Department of Chemistry, Georgia Institute of Technology, Atlanta, GA, 30332, USA

    Charles L. Liotta

  3. Sybron Chemicals, Cherry Hill, NJ, 08002, USA

    Marc E. Halpern

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  1. Charles M. Starks
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  2. Charles L. Liotta
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Starks, C.M., Liotta, C.L., Halpern, M.E. (1994). Phase-Transfer Catalysis: Fundamentals II. In: Phase-Transfer Catalysis. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0687-0_3

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  • DOI: https://doi.org/10.1007/978-94-011-0687-0_3

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