Skip to main content

Phase-Transfer Catalysis: Industrial Perspective

  • Chapter
Phase-Transfer Catalysis

Abstract

In the early 1990s, it was estimated that approximately 500 commercial phase-transfer catalysis (PTC) processes were being performed using at least 25 million pounds per year of catalyst. It was also estimated that sales of products manufactured by processes consisting of at least one major PTC step were at least $10 billion/year (approximately $5 billion in polymers; $3 billion in pharmaceuticals; $2 billion in agricultural chemicals; $1 billion in monomers; and unestimated sales in general chemicals, flavors and fragrances, dyes, surfactants, explosives, and others).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. V. Krishnakumar and M. Sharma, Ind. Eng. Chem. Proc. Des. Dev., 23, 410 (1984).

    Article  Google Scholar 

  2. U. Dolling, E. Grabowski, and S. Pines (Merck, Sharpe and Dohme), U.S. Patent 4,605,761 (1986).

    Google Scholar 

  3. D. Brunelle, Stable Catalysts for Phase-Transfer at Elevated Temperatures, in “Phase-Transfer Catalysis, ACS Symposium 326, C. Starks, ed., Washington D.C., pp. 38-53 (1987).

    Chapter  Google Scholar 

  4. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 76,718 (1981);

    Google Scholar 

  5. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 60,171 (1981);

    Google Scholar 

  6. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 43,303 (1980);

    Google Scholar 

  7. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 21,868 (1980)

    Google Scholar 

  8. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 22,387 (1979);

    Google Scholar 

  9. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 21,927 (1979);

    Google Scholar 

  10. G. Soula, et al. (Rhone-Poulenc), Eur. Patents 16,673 (1979).

    Google Scholar 

  11. S. Matson and T. Stanley, Sepracor, U.S. Patent Appl. 938,230 (1986).

    Google Scholar 

  12. T. Stanley and J. Quinn, Chem. Eng. Sci., 42, 2313 (1987).

    Article  CAS  Google Scholar 

  13. Y. Okahat and K. Ariga, J. Org. Chem., 51, 5064 (1986).

    Article  Google Scholar 

  14. V. Ragaini, G. Verzella, A. Ghignone, and G. Colombo, Ind. Eng. Chem. Process Des. Dev., 25, 878 (1986).

    Article  CAS  Google Scholar 

  15. J. Kinkel and E. Tomlinson, Sep. Sci. Tech., 18, 857 (1983).

    Article  CAS  Google Scholar 

  16. L. Maurin, DuPont, U.S. Patent 4,418,232 (1983).

    Google Scholar 

  17. M. Ikeda, Y. Suzuki, and A. Aoshima (Asahi Chemical), JP 03,154,683 (1991) [CA 115: 165683q].

    Google Scholar 

  18. T. Pinnavaia and C. Lin, Michigan State University, U.S. Patent 5,099,054 (1992).

    Google Scholar 

  19. A. Sarkar and B. Rao, Tetrahedron Lett., 32, 1247 (1991).

    Article  CAS  Google Scholar 

  20. H. Alper, Adv. Organomet. Chem., 19, 183 (1981).

    Article  CAS  Google Scholar 

  21. V. Krishnakumar and M. Sharma, Ind. Eng. Chem. Proc. Des. Dev., 23, 410 (1984).

    Article  CAS  Google Scholar 

  22. N. Dutta, S. Borthakur, and G. Patil, Sep. Sci. Technol., 27, 1435 (1992).

    Article  CAS  Google Scholar 

  23. D. Brunelle, General Electric, U.S. Patent 4,410,422 (1983).

    Google Scholar 

  24. Environ. Sci. Technol., 23, 1030 (Sept 1989).

    Google Scholar 

  25. R. Kostyanovski, G. Kadorkina, and A. Mkhitaryan, USSR Patent SU 1,668,359 (1989) [CA 116:128640q].

    Google Scholar 

  26. E. Saphores, A. Gleisner, J. Vega, and W. Mardones, U.S. Patent 5,011,965 (1991).

    Google Scholar 

  27. H. Freedman, Pure Appl. Chem., 58, 857 (1986).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Starks, C.M., Liotta, C.L., Halpern, M.E. (1994). Phase-Transfer Catalysis: Industrial Perspective. In: Phase-Transfer Catalysis. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0687-0_15

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-0687-0_15

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4297-0

  • Online ISBN: 978-94-011-0687-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics