Abstract
An overview is presented of radicals generated on porous metal oxide surfaces such as zeolites whose main source of generation has been ionizing radiation. Attention is primarily paid to ESR studies on structures and reactions of organic neutral and ionic radicals. A short introduction is also given to paramagnetic metal ions and clusters formed in zeolites and other related materials.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. Lund and M. Shiotani (Eds.): Radical Ionic Systems. Properties in Condensed Phases, Kluwer Academic Publishers, Dordrecht (1991).
L. B. Knight, Jr.:’ Generation and study of inorganic cations in rare gas matrices by electron spin resonance’, in A. Lund and M. Shiotani (Eds.), Radical Ionic Systems. Properties in Condensed Phases, Kluwer Academic Publishers, Dordrecht (1991).
P. P. Edwards, L. L. Woodall, P. A. Anderson, A. R. Armstrong, and M. Slaski: Chem. Soc. Rev. 305 (1993).
K. B. Yoon: Chem. Rev. 93, 321 (1993).
J. Sohma and M. Shiotani: Magnetic Resonance in Colloidal and Interface Science: ACS Symposium Series, 34, 141 (1976).
M. Shiotani, F. Yuasa, and J. Sohma: J. Phys. Chem. 79, 2669 (1975).
S. Kudo, A. Hasegawa, T. Komatsu, M. Shiotani, and J. Sohma: Chem. Lett. 705 (1973).
K. Toriyama, K. Nunome, and M. Iwasaki: J. Am. Chem. Soc. 109, 4496 (1987).
L. B. Knight, Jr., J. Steadman, D. Feller, and E. R. Davidson: J. Am. Chem. Soc. 106, 3700 (1984).
S. Kubota, M. Iwaizumi, and T. Isobe: Bull. Chem. Soc. Jpn. 44, 2684 (1971).
T. Katsu, M. Yanagida, and Y. Fujita: J. Phys. Chem. 75, 4064 (1971).
Y. Fujita, T. Katsu, M. Sato., and K. Takahashi: J. Chem. Phys. 61, 4307 (1974).
K. Hatano, N. Shimamoto, T. Katsu, and T. Fujita: Bull. Chem. Soc. Jpn. 47, 4 (1974).
(a) K. Toriyama, K. Nunome, and M. Iwasaki: J. Chem. Phys. 77, 5891 (1982). (b) G. Dolivo and A. Lund: J. Phys. Chem. 89, 3977 (1985). (c) M. Lindgren, A. Lund, and G. Dolivo: Chem. Phys. 99, 103 (1985).
M. Shiotani, M. Lindgren, F. Takahashi, and T. Ichikawa: Chem. Phys. Lett. 170, 201 (1990).
M. V. Barnabas, D. W. Werst, and A. D. Trifunac: Chem. Phys. Lett. 204, 435 (1993).
M. V. Barnabas, D. W. Werst, and A. D. Trifunac: Chem. Phys. Lett. 187, 565 (1991).
V. I. Melekhov, O. A. Anisimov, L. Sjoqvist, and A. Lund: Chem. Phys. Lett. 174, 95 (1991).
M. Lindgren, M. Matsumoto, and M. Shiotani: J. Chem. Soc. Perkin Trans. II, 1397 (1992).
(a) V. A. Bol’shov and A. M. Volodin: React. Kinet. Catal. Lett. 43, 87 (1991). (b) C. J. Rhodes: J. Chem. Soc, Chem. Commun. 13, 900 (1991). (c) Ch. Gullyev, L. A. Surina, S. A. Surin, and G. D. Chukin: Neftekhimiya 30(4), 492 (1990) (Russ).
V. A. Bol’shov and A. M. Volodin: React. Kinet. Catal. Lett. 46, 337 (1992).
M. K. Carter and G. Vincow: J. Chem. Phys. 47, 292 (1967).
T. R. Tuttle, and S. I. Weissman: J. Am. Chem. Soc. 80, 3542 (1958).
O. Edlund, P.-O. Kinell, A. Lund, and A. Shimizu: J. Phys. Chem. 46, 3679 (1967).
T. Komatsu, A. Lund, and P.-O. Kinell: J. Phys. Chem. 76, 1721 (1972).
M. Iwasaki, K. Toriyama, and K. Nunome: J. Chem. Soc, Chem. Commun. 320 (1983).
R. Erickson, M. Lindgren, A. Lund, and L. Sjoqvist: Colloids and Surfaces A:72, 207 (1993).
(a) D. G. Streets and G. P. Ceaser: J. Phys. Chem. 66, 257 (1977). (b) J. D. Clark and D. C. Frost: J. Am. Chem. Soc. 89, 244 (1967).
J. C. Vedrine et al.: J. Catalysis 59, 248 (1979).
D. N. Stamieres and J. Turkevich: J. Am. Chem. Soc. 86, 749 (1964).
A. E. Hirchler, W. C. Neikam, D. S. Barmby, and R. L. James: J. Catal. 4, 628 (1965).
S. Shih: J. Catal. 79, 390 (1983).
T. Iehikawa, M. Yamaguchi, and H. Yoshida: J. Phys. Chem. 91, 6400 (1987).
M. V. Barnabas and A. D. Trifunac: J. Chem. Soc, Chem. Commun. 813 (1993).
P. L. Corio and S. Shih: J. Phys. Chem. 75, 3475 (1971).
C. J. Rhodes: J. Chem. Soc, Faraday Trans. 87, 3179 (1991).
R. Crockett and E. Roduner: J. Chem. Soc, Perkin Trans II (1993).
C. J. Rhodes and M. Standing: J. Chem. Soc, Perkin Trans II, 1455 (1992).
M. V. Barnabas, D. W. Werst, and A. D. Trifunac: Chem. Phys. Lett. 206, 21 (1993).
M. V. Barnabas and A. D. Trifunac: Chem. Phys. Lett. 193, 298 (1992).
X. Z. Qin and A. D. Trifunac: J. Phys. Chem. 95, 6466 (1991).
M. Shiotani and K. Ohta: unpublished results.
C. Periera, G. T. Kokotalio, and R. J. Gorte: J. Phys. Chem. 95, 705 (1991).
S. D. Cox and G. D. Stucky: J. Phys. Chem. 95, 710 (1991).
S. Bordiga, G. Ricchiardi, G. Spoto, D. Scarano, L. Carnrelli, A. Zecchina, and C. O. Arean: J. Chem. Soc, Faraday Trans. 89, 1843 (1993).
M. Shiotani and K. Yamaji: unpublished results.
P. H. Kasai: J. Chem. Phys. 43, 3322 (1965).
J. A. Rabo, C. L. Angell, P. H. Kasai, and V. Schomaker: J. Chem. Soc, Disc. Faraday Soc 41, 328 (1966).
P. H. Kasai and R. J. Bishop, Jr.: J. Phys. Chem. 77, 2308 (1973).
P. H. Kasai and R. J. Bishop, Jr.: J. Am. Chem. Soc. 94, 5560 (1972).
P. P. Edwards, M. R. Harrison, J. Klinowski, S. Ramdas, J. M. Thomas, D. C. Johnson, and C. J. Page: J. Chem. Soc, Chem. Commun. 982 (1984).
M. R. Harrison: J. Solid. State Chem. 54, 330 (1984).
R. E. H. Breuer, E. de Boer, and G. Geismar: Zeolites 9, 336 (1989).
P. A. Anderson, R. J. Singer, and P. P. Edwards: J. Chem. Soc, Chem. Commun. 914 (1991).
P. A. Anderson and P. P. Edwards: J. Chem. Soc, Chem. Commun. 915 (1991).
Y. Kim, Y. W. Han, and K. Seff: J. Phys. Chem. 97, 12663 (1993).
S. H. Song, U. S. Kim, Y. Kim, and K. Seff: J. Phys. Chem. 96, 10937 (1992).
S. H. Song, Y. Kim, and K. Seff: J. Phys. Chem. 95, 9919 (1991).
M. S. Jeong, Y. Kim, and K. Seff: J. Phys. Chem. 97, 10139 (1993).
L. R. M. Martens, P. J. Grobet, and P. A. Jacobs: Nature 315, 568 (1985).
B. Xu and L. Kevan: J. Phys. Chem. 96, 2642 (1992).
B. Xu, X. Chen, and L. Kevan: J. Chem. Soc, Faraday Trans. 87, 3157 (1991).
B. Xu and L. Kevan: J. Phys. Chem. 96, 3647 (1992).
K. B. Yoon and J. K. Kochi: J. Chem. Soc, Chem. Commun. 510 (1988).
G. A. Kuranova: High Energy Chem. 91, 25 (1992).
X. Liu and J. K. Thomas: Chem. Phys. Lett. 192, 555 (1992).
P. A. Andersson, D. Barr, and P. P. Edwards: Angew. Chem. Intern. Ed. Engl. 30, 1551 (1991).
K.-K. Iu, X. Liu, and J. K. Thomas: J. Phys. Chem. 97, 8165 (1993).
L. Shields: Trans. Faraday. Soc. 62, 1042 (1966). (b) C. E. Forbes and M. C. R. Symons: Mol. Phys. 27, 467 (1974). A. D. Stevens and M. C. R. Symons: Chem. Phys. Lett. 109, 514 (1984).
J. A. Howard, K. F. Preston, and B. Mile: J. Am. Chem. Soc. 103, 6226 (1981). (b) J. A. Howard, R. Sutcliffe, and B. Mile: J. Phys. Chem. 87, 2268 (1983). K. Kernisant, G. A. Thompson, and D. M. Lindsay: J. Chem. Phys. 82, 4739 (1985).
H. K. Beyer, P. A. Jacobs, and J. B. Uytterhoeven: J. Chem. Soc, Faraday Trans. 72, 674 (1976). (b) P. A. Jacobs, J. P. Linart, H. Nijs, J. B. Uytterhoeven, and H. K. Beyer: J. Chem. Soc, Faraday Trans. 73, 1745 (1977). (c) P. A. Jacobs, J. B. Uytterhoeven, and H. K. Beyer: J. Chem. Soc, Faraday Trans. I 73, 1755 (1977). (d) P. A. Jacobs and J. B. Uytterhoeven: J. Chem. Soc, Faraday Trans. I 75, 56 (1979). (e) L. R. Gellens, W. J. Mortier, R. A. Schoonheydt, and J. B. Uytterhoeven: J. Phys. Chem. 85, 2783 (1981). (f) L. R. Gellens, W. J. Mortier, and J. B. Uytterhoeven: Zeolites 1, 11 (1981).
J. Texter, R. Kellermann, and T. Gonsiorowski: J. Phys. Chem. 90, 2118–2124 (1986).
L. R. Gellens, W. J. Mortier, R. A. Schoonheydt, and J. B. Uytterhoeven: J. Phys. Chem. 85, 2783 (1981).
D. Hemmerschmidt and R. Haul: Ber. Bunsen-Ges. Phys. Chem. 84, 902 (1980).
Y. Kim and K. Seff: J Am. Chem. Soc. 100, 6989 (1978).
J. R. Morton and K. F. Preston: J. Magn. Reson. 68, 121 (1986). (b) J. R. Morton and K. F. Preston: Zeolites 7, 2 (1987). (c) J. R. Morton, K. F. Preston, A. Sayari, and J. S. Tse: J. Phys. Chem. 91, 2117 (1987).
P. Grobet and R. A. Schoonheydt: Surf. Sci. 156, 893 (1985). (b) R. A. Schoonheydt and H. Leeman: J. Phys. Chem. 93, 2048 (1989).
J. Michalik and L. Kevan: J. Am. Chem. Soc. 108, 4247 (1986).
M. Narayana, A. S. W. Li, and L. Kevan: J. Phys. Chem. 85, 132 (1981).
M. Narayana and L. Kevan: J. Chem. Phys. 76, 3999 (1982).
A. van der Pol, E. J. Reijerse, E. de Boer, T. Wasowicz, and J. Michalik: Mol. Phys. 75, 37 (1992). (b) T. Wasowicz and J. Michalik: Radiat. Phys. Chem. 37, 427 (1991).
J. Michalik, A. van der Pol, E. J. Reijerse, T. Wasowicz, and E. de Boer: Appl. Magn. Reson. 3, 19 (1992). (b) J. Michalik, T. Wasowicz, J. Sadlo, and A. van der Pol: Colloids and Surfaces A 72, 81 (1993).
C. Cros and J.-C. Benejat: Bull. Soc. Chim. France 5, 1739 (1972). (b) C. Cros, M. Pouchard, and P. Hagenmuller: J. Sol. State. Chem. 2, 570 (1970).
A. F. Hebard. M. J. Rosseinsky, R. C. Haddon, D. W. Murphy, S. H. Glarum, T. T. Palstra, A. P. Ramirez, and A. R. Kortan: Nature 350, 600 (1991).
S. B. Roy, K. E. Sim, and A. D. Caplin: Philisophical Magazine B 65, 1445 (1992).
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Shiotani, M., Lindgren, M. (1995). Radicals on Surfaces Formed by Ionizing Radiation. In: Lund, A., Rhodes, C.J. (eds) Radicals on Surfaces. Topics in Molecular Organization and Engineering, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0493-7_7
Download citation
DOI: https://doi.org/10.1007/978-94-011-0493-7_7
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4221-5
Online ISBN: 978-94-011-0493-7
eBook Packages: Springer Book Archive