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Surface Trapped Electrons on Metal Vapour Modified Magnesium Oxide. Nature of the Surface Centres and Reactivity with Adsorbed Molecules

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Book cover Radicals on Surfaces

Part of the book series: Topics in Molecular Organization and Engineering ((MOOE,volume 13))

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Abstract

The first part of the present paper reports a wide investigation on the interaction between metals of low ionisation energy (magnesium and alkali metals) and the surface of the ionic oxide MgO. The interaction basically consists in the ionisation of the metal and in the stabilisation of both the released electrons and the corresponding cations at the surface. Various types of paramagnetic electron centers have been identified including surface F centers, monoalkali cationic centers and ionic clusters. In the second part the reactivity of the electron rich MgO surface with simple inorganic molecules is described.

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Authors and Affiliations

  1. Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, Via Pietro Giuria 9, 10125, Torino, Italy

    Elio Giamello & Damien Murphy

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  1. Elio Giamello
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  2. Damien Murphy
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Anders Lund Christopher J. Rhodes

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Giamello, E., Murphy, D. (1995). Surface Trapped Electrons on Metal Vapour Modified Magnesium Oxide. Nature of the Surface Centres and Reactivity with Adsorbed Molecules. In: Lund, A., Rhodes, C.J. (eds) Radicals on Surfaces. Topics in Molecular Organization and Engineering, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0493-7_6

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  • DOI: https://doi.org/10.1007/978-94-011-0493-7_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4221-5

  • Online ISBN: 978-94-011-0493-7

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