Skip to main content
SpringerLink
Log in

Investigation of Radical Ions with Time-Resolved Surface Enhanced Raman Spectroscopy

  • Chapter
Radicals on Surfaces

Part of the book series: Topics in Molecular Organization and Engineering ((MOOE,volume 13))

  • 109 Accesses

Abstract

Time-resolved surface enhanced Raman scattering (TRSERS) spectroscopic methods are discussed for the study of radical ions produced photochemically and electrochemically at silver or gold metal surfaces. Both single shot and pump-probe TRSERS experimental methods are illustrated which use an optical multichannel analyzer, OMA, forms (single shot) to ns (pump-probe) time resolution. Fundamental chemical and physical processes for photochemically and electrochemically induced radical ion formation are described for adsorbed molecules at the metal-solution interface. Emphasis is given to the possibility of laser photoinduced radical ion formation by a direct molecule-to-metal charge transfer process. Applications of TRSERS techniques are discussed for the study of radical ions formed by various photochemical and electrochemical reactions at the surface of SERS active metals. These adsorbed reaction systems encompass electroreduction processes of adsorbed alkylviologens, p-nitrobenzoate, 4-cyanopyridine, 4-pyridine carboxaldehyde, 4-hydroxymethylpyrid-ine, and direct photoinduced radical cation formation from flavin mononucleotide, FMN.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. C. Shi, W. Zhang. R.L. and J. R. Lombardi: J. Phys. Chem. 96, 10093 (1992).

    Article  CAS  Google Scholar 

  2. J. R. Birk and S. P. Perone: Anal. Chem. 40, 466 (1986).

    Google Scholar 

  3. A. Henglein: Pulse Radiolysis and Polarography: Electrode Reactions of Short-lived Free Radicals, in A. J. Bard (ed.), Electroanalytical Chemistry, Vol. 9, Marcel Dekker, Inc., New York (1976), pp. 163–244.

    Google Scholar 

  4. G. C. Pimental (ed.): Opportunities in Chemistry, National Academy Press, Washington, S. 86 ff. (1985).

    Google Scholar 

  5. R. R. Cavanagh, D. S. King, J. C. Stephenson, and T. F. Heinz: J. Phys. Chem. 97, 786 (1993).

    Article  CAS  Google Scholar 

  6. T. E. Furtak: Optical and Electronic Resonances: “The Underlying Sources of Surface Enhanced Raman Spectroscopy” in B. Garetz and J. R. Lombardi (eds.), Advances in Laser Spectroscopy, Vol. 2, John Wiley and Son, Chichester (1984), pp. 175–205.

    Google Scholar 

  7. R. K. Chang and B. L. Laube: ’Surface-Enhanced Raman Scattering and Nonlinear Optics Applied to Electrochemistry’, in CRC Critical Reviews in Solid State and Material Science, Vol. 12, pp. 1–73, CRC Press, Inc., Boca Raton (1984).

    Google Scholar 

  8. R. L. Birke and J. R. Lombardi: ’Surface-Enhanced Raman Scatterings’, in R. J. Gale (ed.), Spectroelectrochemistry: Theory and Practice, Plenum Press, New York (1988), pp. 263–348.

    Google Scholar 

  9. E. J. Zeman and G. C. Schatz: J. Phys. Chem. 91, 634 (1987).

    Article  CAS  Google Scholar 

  10. J. R. Lombardi. R. L. Birke, T. Lu, and J. Xu: J. Chem. Phys. 84, 4174 (1986).

    Article  CAS  Google Scholar 

  11. J. R. Lombardi, R. L. Birke, L. A. Sanchez, I. Bernard, and S. C. Sun: Chem. Phys. Lett. 104, 240 (1984).

    Article  CAS  Google Scholar 

  12. R. P. Van Duyne: ’Laser Excitation of Raman Scattering from Adsorbed Molecules on Electrodes Surfaces’, in C. B. Moore (ed.), Chemical and Biochemical Applications of Lasers, Vol. IV, Academic Press Inc., New York (1979), pp. 101–185.

    Google Scholar 

  13. R. L. Birke, T.-H. Lu, and J. R. Lombardi: ’Surface-Enhanced Raman Spectroscopy’, in R. Varmi and J. R. Selman (eds.), Techniques for the Characterization of Electrodes and Electrochemical Processes, John Wiley and Son, Inc., New York (1991), pp. 211–277.

    Google Scholar 

  14. A. Vivoni, J. R. Lombardi, and R. L. Birke: unpublished results (1993).

    Google Scholar 

  15. J. Billman and A. Otto: Solid State Commun. 44, 105 (1982).

    Article  Google Scholar 

  16. T. E. Furtak and S. H. Macomber: Chem. Phys. Lett. 95, 328 (1983).

    Article  CAS  Google Scholar 

  17. Ph. Avouris and B. N. J. Persson: J. Phys. Chem. 88, 837 (1984).

    Article  CAS  Google Scholar 

  18. J. Bokor: Science 246, 1130 (1989).

    Article  CAS  Google Scholar 

  19. E. P. March, F. L. Tabares, M. R. Schneider, and J. P. Cowin: J. Vac. Sci. Technol. A5, 519 (1987).

    Google Scholar 

  20. E. P. Marsh, M. R. Schneider, T. L. Gilton, F. L. Tabares, W. Meier, and J. P. Cowin: Phys. Rev. Lett. 60, 2551 (1988).

    Article  CAS  Google Scholar 

  21. E. P. Marsh. T. L. Gilton, W. Meier, M. R. Schneider, and J. P. Cowin: Phys. Rev. Lett. 61, 2725 (1988).

    Article  CAS  Google Scholar 

  22. S. A. Costello. B. Roop, Z.-M. Liu, and J. M. White: J. Phys. Chem. 92, 1019 (1988).

    Article  CAS  Google Scholar 

  23. Z. M. Liu, S. A. Costello, B. Roop, S. R. Coon, S. Akhter, and J. M. White: J. Phys. Chem. 93, 7681 (1989).

    Article  CAS  Google Scholar 

  24. C. C. Cho, B. A. Collings, R. E. Hammer, J. C. Polanyi, C. D. Stanners, J. H. Wang, and G.-P. Xu: J. Phys. Chem. 93, 7761 (1989).

    Article  CAS  Google Scholar 

  25. B. Roop, S. A. Costello, C. M. Greenlief, and J. M. White: Chem. Phys. Lett. 143, 38 (1988).

    Article  CAS  Google Scholar 

  26. X. L. Zhou and J. M. White: J. Phys. Chem. 94, 2643 (1990).

    Article  CAS  Google Scholar 

  27. G. M. Goncher and C. A. Harris: J. Chem. Phys. 77, 3767 (1982).

    Article  CAS  Google Scholar 

  28. G. M. Goncher, C. A. Parsons, and C. A. Harris: J. Phys. Chem. 88, 4200 (1984).

    Article  CAS  Google Scholar 

  29. A. Nitzan and L. E. Brus: J. Chem. Phys. 74, 5321 (1981).

    Article  CAS  Google Scholar 

  30. A. Nitzan and L. E. Brus: J. Chem. Phys. 75, 2205 (1981).

    Article  CAS  Google Scholar 

  31. K. H. Drexhage, H. Kuhn, and F. P. Schafer: Ber. Bunsenges. Phys. Chem. 22, 329 (1968).

    Google Scholar 

  32. R. R. Chance, A. Prock, and R. Silbey: J. Chem. Phys. 60, 2744 (1974).

    Article  CAS  Google Scholar 

  33. R. R. Chance, A. Prock, and R. Silbey: Adv. Chem. Phys. 37, 1 (1978).

    Article  CAS  Google Scholar 

  34. B. J. N. Persson: J. Phys. C 11, 4251 (1978).

    Article  CAS  Google Scholar 

  35. B. J. N. Persson and N. D. Lang: Phys. Rev. B 26, 5409 (1982).

    Article  CAS  Google Scholar 

  36. H. Metiu and J. W. Gadzuk: J. Chem. Phys. 74, 2641 (1981).

    Article  Google Scholar 

  37. H. Morawitz and M. R. Philpot: Phys Rev. B 10, 4863 (1974).

    Article  Google Scholar 

  38. R. Rupin: J. Chem. Phys. 76, 1681 (1982).

    Article  Google Scholar 

  39. J. Gersten and A. Nitzan: J. Chem. Phys. 74, 1139 (1981).

    Article  Google Scholar 

  40. Ph. Avouris and B. N. J. Persson: J. Chem. Phys. 79, 5156 (1983).

    Article  Google Scholar 

  41. S. Sun, R. L. Birke, J. R. Lombardi, K. P. Leung, and A. Z. Genack: J. Phys. Chem. 92, 5965 (1988).

    Article  CAS  Google Scholar 

  42. P. Avouris and R. E. Walkup: ‘Fundamental Mechanisms of Desorption and Fragmentation Induced by Electronic Transitions at Surfaces’ in H. Stock, G. T. Babcock, and C. B. Moore (eds.), Annual Reviews of Physical Chemistry. Vol. 40. Annual Reviews Inc., Palo Alto (1989), p. 173.

    Google Scholar 

  43. R. Meming and G. Kursten: Ber. Bunsenges. Physik. Chem. 76, 4 (1972).

    Google Scholar 

  44. W. Schmickler: J. Electroanal. Chem. 100, 533 (1979).

    Article  CAS  Google Scholar 

  45. W. L. Reynolds and R. W. Lumry: Mechanisms of Electron Transfer, The Ronald Press Co., New York (1966), pp. 149–154.

    Google Scholar 

  46. L. N. Mackey and T. Kuwana: Bioelectrochem. Bioenerg. 3, 596 (1976).

    Article  CAS  Google Scholar 

  47. C. J. Schoot, J. J. Ponjee, H. T. van Dam, R. A. Van Doom, and P. T. Bolwijn: Appl. Phys. Lett. 23, 64 (1973): H. T. van Dam and J. J. Ponjee: J. Electrochem. Soc. 121, 1555 (1974).

    Article  CAS  Google Scholar 

  48. R. Jasinski: J. Electrochem. Soc. 124, 533 (1979).

    Google Scholar 

  49. R. C. Ciesliski and N. R. Armstrong: J. Electrochem. Soc. 127, 2605 (1980).

    Article  Google Scholar 

  50. F. F. Fan, B. Reichman, and A. Bard: J. Am. Chem. Soc. 102, 1488 (1980).

    Article  CAS  Google Scholar 

  51. A. Regis and J. Corset: J. Chim. Phys. 78, 687 (1981).

    CAS  Google Scholar 

  52. C. A. Melendres, P. C. Lee. and D. Meisel: J. Electrochem. Soc. 130, 1523 (1983).

    Article  CAS  Google Scholar 

  53. T. Lu, R. L. Birke, and J. R. Lombardi: Langmuir 2, 305 (1986).

    Article  CAS  Google Scholar 

  54. Q. Feng and T. M. Cotton: J. Phys. Chem. 90, 983 (1986).

    Article  CAS  Google Scholar 

  55. A. Yasuda, H. Kondo, M. Itbashi, and J. Seto: Electroanal. Chem. 210, 265 (1986).

    Article  CAS  Google Scholar 

  56. T. Lu and T. M. Cotton: J. Phys. Chem. 91, 5978 (1987).

    Article  CAS  Google Scholar 

  57. Q. Feng, W. Yue. and T. M. Cotton: J. Phys. Chem. 94, 2082 (1990).

    Article  CAS  Google Scholar 

  58. M. J. S. Dewar and N. Trinajstic: Collec. Czech. Chem. Commun. 35, 3136 (1970).

    CAS  Google Scholar 

  59. Y. Misono, K. Shibasaki, N. Yamasara, Y. Mineo, and K. Itoh: J. Phys. Chem. 97, 6054 (1993).

    Article  CAS  Google Scholar 

  60. G. L. Mclntire, D. M. Chiappardi, R. L. Casselberry, and H. N. Blount: J. Chem. Phys. 86, 2632 (1982).

    Article  Google Scholar 

  61. A. J. Fry: in S. Patai (ed.), The Chemistry of Amino, Nitroso. Nitro Compounds and their Derivatives, Part I, John Wiley and Son, New York (1982), p. 320.

    Google Scholar 

  62. I. Rubinstein: J. Electroanal. Chem. 183, 379 (1985).

    Article  CAS  Google Scholar 

  63. W. J. Albery, B. A. Coles, and A. M. Couper: J. Electroanal. Chem. 65, 901 (1975).

    Article  CAS  Google Scholar 

  64. C. Shi, W. Zhang, R. L. Birke, and J. R. Lombardi: J. Phys. Chem. 94, 4767 (1990).

    Google Scholar 

  65. C. Shi, W. Zhang, R. L. Birke, and J. R. Lombardi: J. Phys. Chem. 95, 6276 (1991).

    Article  CAS  Google Scholar 

  66. P. Gao, D. Gosztola, and M. J. Weaver: J. Phys. Chem. 92, 7122 (1988).

    Article  CAS  Google Scholar 

  67. P. Gao, D. Gosztola, and M. J. Weaver: Anal’. Chim. Acta 212, 201 (1988).

    Article  CAS  Google Scholar 

  68. C. Nishihara and M. Kaise: J. Electroanal. Chem. 149, 287 (1983).

    Article  CAS  Google Scholar 

  69. C. Shi, W. Zhang, R. L. Birke, and J. R. Lombardi: unpublished results (1993).

    Google Scholar 

  70. P. F. Heelis: Chem. Soc. Rev. 11, 15 (1982).

    Article  CAS  Google Scholar 

  71. J. Yamase: Photochem. Photobiol. 34, 11 (1981).

    Google Scholar 

  72. W. Zhang, R. L. Birke, and J. R. Lombardi: unpublished results (1993).

    Google Scholar 

  73. M. Abe: in R. J. H. Clark and R. E. Hester (eds.). Spectroscopy of Biological Systems, Ch. 7. John Wiley & Sons Ltd (1986) and references cited therein.

    Google Scholar 

  74. P. F. Heelis, B. J. Parsons, B. Thomas, and G. O. Phillips: J. Chem. Soc. Chem. Commun. 954 (1985).

    Google Scholar 

  75. P. F. Heelis, B. J. Parsons, G. O. Phillips, and A. J. Swallow: J. Phys. Chem. 90, 6833 (1986).

    Article  CAS  Google Scholar 

  76. N. Getoff, S. Solar, and D. B. McCormick; Science 201, 616 (1978).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, The City College of The City University of New York, Convent Avenue at 138th Street, New York, NY, 10031, USA

    Ronald L. Birke & John R. Lombardi

Authors
  1. Ronald L. Birke
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. John R. Lombardi
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Anders Lund Christopher J. Rhodes

Rights and permissions

Reprints and permissions

Copyright information

© 1995 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Birke, R.L., Lombardi, J.R. (1995). Investigation of Radical Ions with Time-Resolved Surface Enhanced Raman Spectroscopy. In: Lund, A., Rhodes, C.J. (eds) Radicals on Surfaces. Topics in Molecular Organization and Engineering, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0493-7_11

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-0493-7_11

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4221-5

  • Online ISBN: 978-94-011-0493-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation