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Carbonyl Migratory Insertions

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Theoretical Aspects of Homogeneous Catalysis

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 18))

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Abstract

Carbonyl insertion into an M-R bond, which is also called migratory insertion, (equation 1) has been implicated as one of the key steps in various catalytic cycles such as hydroformylation [1]. When the migrating groups are alkyl, aryl, and alkenyl, insertion has been observed to take place in many transition metal complexes [1].

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Author information

Authors and Affiliations

  1. School of Informatics and Sciences and Graduate School of Human Informatics, Nagoya University, Nagoya, 464-01, Japan

    Nobuaki Koga

  2. Cherry L. Emerson Center for Scientific Computation and Dept. of Chemistry, Emory University, Atlanta, GA, 30323, USA

    Keiji Morokuma

Authors
  1. Nobuaki Koga
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  2. Keiji Morokuma
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Editor information

Editors and Affiliations

  1. Van ’t Hoff Research Institute, University of Amsterdam, The Netherlands

    Piet W. N. M. Van Leeuwen

  2. C.L. Emerson Center, Emory University, Atlanta, USA

    Keiji Morokuma

  3. Theoretical Chemistry Group, University of Utrecht, The Netherlands

    Joop H. Van Lenthe

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Koga, N., Morokuma, K. (1995). Carbonyl Migratory Insertions. In: Van Leeuwen, P.W.N.M., Morokuma, K., Van Lenthe, J.H. (eds) Theoretical Aspects of Homogeneous Catalysis. Catalysis by Metal Complexes, vol 18. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0475-3_4

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  • DOI: https://doi.org/10.1007/978-94-011-0475-3_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4212-3

  • Online ISBN: 978-94-011-0475-3

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