Abstract
Near infrared absorption (NIR) has been known to activate proton transfer in molecular crystals containing hydrogen bonds [1]. In presented experiments, the same process is observed in water solution of L-glutamic and poly-L-glutamic sodium salt in presence of spin probe TEMPO — a free radical.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Komorowska, M., Wójcik, G. and Szostak, M. M. (1994) EPR studies of NIR induced unpaired spins in two polymorphs of meta-nitrophenol, EUCMOS XXII-Essen, Germany, Conf. Proc. (in press).
Malik, N. A., Smith, E. A. and Symons, M. C. R. (1989) Solvent effects on the N14 hyperfine coupling constants and spin exchange rates for di-t butyl nitroxide and peroxylamidisul-phonate ions, J. Chem. Soc. Faraday Trans. L 85 (10), 3246–3256.
Marsh, D. (1981) Electron spin resonance; spin labels, [in] Grell, E. (ed.) Membrane Spectroscopy, Springer-Verlag, Berlin-Heidelberg-New York, pp. 51—137.
Rozancew, E. G. and Szolle, W. D. (1985) Chemia wolnych rodników (in Polish), PWN (ed.), Warszawa.
Komorowska, M. (1995) in preparation.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Komorowska, M., Norek, V. (1995). Oscillations in Water Solutions of Mixture Polyaminoacids and Tempo Spin Probe Irradiated by Near Infrared. In: Merlin, J.C., Turrell, S., Huvenne, J.P. (eds) Spectroscopy of Biological Molecules. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0371-8_20
Download citation
DOI: https://doi.org/10.1007/978-94-011-0371-8_20
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4166-9
Online ISBN: 978-94-011-0371-8
eBook Packages: Springer Book Archive