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Asymmetric Complex Catalysis in Micellar Systems

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Aqueous Organometallic Chemistry and Catalysis

Part of the book series: NATO ASI Series ((ASHT,volume 5))

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Abstract

The development of organometallic chemistry is closely connected to the application of organic solvents especially solvents with coordinating properties.

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References

  1. Hartley, F. R. (1987) Supported metal complex catalysts in F. R. Hartley (ed.), The Chemistry of the Metal-Carbon Bond, Wiley & Sons Inc., Chichester, chapter 14

    Google Scholar 

  2. Gates, B. C., Guczi, L., Knözinger, H. (1986) Metal Clusters in Catalysis, Elsevier, Amsterdam

    Google Scholar 

  3. Southern, T. G. (1989) Bi-phasic and phase transfer catalysis, Polyhedron 8, 407–413

    Article  CAS  Google Scholar 

  4. Keim, W. (1984) Pros and cons of homogeneous transition metal catalysis, illustraded for SHOP [Shell higher olefin process], Chem.-Ing.-Tech. 56, 850–853

    Article  CAS  Google Scholar 

  5. Kuntz, E. G. (1987), Homogeneous catalysis in water, CHEMTECH 570–575

    Google Scholar 

  6. Herrmann, W. A., Kohlpainter, C. W. (1993), Wasserlösliche Liganden, Metallkomplexe und Komplexkatalysatoren: Synergismen aus Homogen- und Heterogenkatalyse, Angew. Chem. 105, 1588–1609

    CAS  Google Scholar 

  7. Paetzold, E., Kinting, A., Oehme, G. (1987), Synthesis of phosphino alkane sulfonates and their corresponding sulfonic acids by reaction of alkalimetal-phosphides with sultones, J. Prakt. Chem. 329, 725–731

    Article  CAS  Google Scholar 

  8. Paetzold, E., Oehme, G. (1993) Water soluble palladium(II) phosphine complexes as catalysts in the hydrodehalogenation of allyl and benzyl halogenides under biphasic and phase transfer conditions, J. Prakt. Chem./Chem. Ztg. 335, 181–184

    Article  CAS  Google Scholar 

  9. Brown, J. ML, Baker, S. K., Colens, A., Darwent, J. R. (1980) Micellar catalysis, in P. Dunnill, A. Wiseman, N. Blakebrough (eds.), Enzymic and Non-Enzymic Catalysis, Horwood, Chichester, chapter 5

    Google Scholar 

  10. Kunitake, T., Shinkai, S. (1980) Catalysis by micelles, membranes and other aqueous aggregates as models for enzyme action, Adv. Phys. Org. Chem. 17, 435–487

    Article  CAS  Google Scholar 

  11. Fendler, J. H. (1983) Photochemistry in organized media, J. Chem. Educ. 60, 872–876

    Article  CAS  Google Scholar 

  12. Blokzijl, W., Engberts, J. B. F. N. (1993) Hydrophobe Effekte - Ansichten und Tatsachen, Angew. Chem. 105, 1610–1648

    CAS  Google Scholar 

  13. Bunton, C. A., Savelli, G. (1986) Organic reactivity in aqueous micelles and similar assemblies, Adv. Phys. Org. Chem. 22, 213–309

    Article  CAS  Google Scholar 

  14. Meisel, D., Matheson, M. S. (1989) Photocatalysis in organized assemblies, in N. Serpone, E. Pelizzetti (eds.) Photocatalysis, Wiley & Sons Inc., New York, pp. 385–419 see also 11.

    Google Scholar 

  15. Lecomte, L., Sinou, D., Bakos, J., Toth, I. Heil, B. (1989) Chiral sulphonated phosphines II. Influence of water on the enantioselectivity in the reduction of dehydro-aminoacids, J. Organomet. Chem. 370, 277–284

    Article  CAS  Google Scholar 

  16. Oehme, G., Paetzold, E., Selke, R. (1992) Increase in activity and enantioselectivity in asymmetric hydrogenation reactions catalysed by chiral rhodium(I) complexes as a consequence of the action of amphiphiles, J. Mol. Catal. 71, L1–L5

    Article  CAS  Google Scholar 

  17. Achiwa, K. (1976) Asymmetric hydrogenation with new chiral functionalized bisphosphine-rhodium complexes, J. Am. Chem. Soc. 98, 8265–8266

    Article  CAS  Google Scholar 

  18. Kagan, H. B., Dang, T. P. (1972) Asymmetric catalytic reduction with transition metal complexes I. A catalytic system of rhodium(I) with (-)-2,3–0-isopropylidene-2,3-dihydroxy-l,4-bis(diphenylphosphino)butane,a new chiral diphosphine, J. Am. Chem. Soc. 94, 6429–6433

    Article  CAS  Google Scholar 

  19. Selke, R. (1989) Carbohydrate phosphinites as chiral ligands for asymmetric synthesis catalyzed by complexes V. New rhodium(I) chelates prepared by precipitation from the equilibrium between neutral and cationic complexes and hydrolysis of their bonded ligands, J. Organomet. Chem. 370, 241–248

    Article  CAS  Google Scholar 

  20. Grassert, I., Paetzold, E., Oehme, G. (1993) Influence of different types of amphiphiles on the rhodium(I) complex catalyzed asymmetric hydrogenation of (Z)-methyl-a-acetamidocinnamate in aqueous medium, Tetrahedron 49, 6605–6612

    Article  CAS  Google Scholar 

  21. Brij compounds (polyoxyethylene monoalkylethers) were purchased from Fluka, Tween compounds (polyoxyethylenesorbitan monoesters) were purchased from Sigma

    Google Scholar 

  22. Ueoka, R. Matsumoto, Y., Moss, R. A., Swarup, S., Sugii, A., Harada, K. Kikuchi, J., Murakami, Y. (1988) Membrane matrix for the hydrolysis of amino acid esters with marked enantioselectivity, J. Am. Chem. Soc. 110, 1588–1595

    Article  CAS  Google Scholar 

  23. Paleos, C. M. (1992) Polymerization of micelle-forming monomers, in C. M.Paleos (ed.) Polymerization in Organized Media, Gordon and Breach,Philadelphia, chapter 3

    Google Scholar 

  24. Andre, B., Boyer, B., Lamaty, G., Roque, J.-P. (1991) Efficient catalytic activity of polymerized micelle-forming surfactants, Tetrahedron Lett. 32, 1881–1884

    Article  CAS  Google Scholar 

  25. Anton, P., Köberle, P., Laschewsky, A. (1993) Recent developments in the field of micellar polymers, Makromol Chem. 194, 1–27

    Article  CAS  Google Scholar 

  26. Flach, H. N., Grassert, I., Oehme, G. (in press) Polymeric surfactant systems in the asymmetric hydrogenation of amino acid precursors with a rhodium complex, Macromol. Chem. Phys.

    Google Scholar 

  27. Heller, B., Oehme, G., to be published

    Google Scholar 

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Oehme, G., Grassert, I., Flach, N. (1995). Asymmetric Complex Catalysis in Micellar Systems. In: Horváth, I.T., Joó, F. (eds) Aqueous Organometallic Chemistry and Catalysis. NATO ASI Series, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0355-8_24

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  • DOI: https://doi.org/10.1007/978-94-011-0355-8_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4158-4

  • Online ISBN: 978-94-011-0355-8

  • eBook Packages: Springer Book Archive

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