Abstract
In recent years, the extensive study was made of transition metal complexes containing ambivalent P,0 ligands (review see [1]). Although their hemilability could affect favourably transition metal-catalyzed processes, much less attention has been paid to their application as catalysts, except for methanol carbonylation (cf.[2]). Our interest in poly(oxyalkylene)phosphines as potential ligands of water-soluble transition metal catalysts led us to examine also the behaviour of parent ether-phosphines Ph2P(CH2)nOR (n=2, R= Me, Et, Bu; n= 1,4-dioxanyl, 2-tetrahydrofuranyl). In present work, ruthenium-ether-phosphine complexes containing the above ligands were used as catalysts in the title reaction and their efficiency was compared with that of reported homogeneous [3,4] and water- soluble [5] Ru(II) complexes.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Bader, A. and Lindner, E. (1991) Coordination chemistry and catalysis with hemilabile oxygen-phosphorus ligands, Coord. Chem. Rev. 108, 27– 110
Lindner, E., Speidel, R., Fawzi, R., and Hiller, W. (1990) Novel basic ligands for the homogeneous catalytic carbonylation of methanol. XXVIII. Synthesis, properties and fluxional behaviour of (ether-phosphine)palladium complexes, Chem. Ber. 123, 2255–2260.
Bar, R., Sasson, Y., and Blum, J. (1984) Transition metal-catalyzed transfer reduction of saturated aldehydes and ketones by sodium formate under phase transfer conditions, J. Mol. Catal. 26, 327–332.
Bar, R., Bar, L.K.,and Sasson, Y. (1985) Phase transfer-catalyzed reduction of aromatic aldedehydes by aqueous sodium formate in the presence of dichlorotris(triphenylphosphine)ruthenium(II): a kinetic study, J. Mol. Catal 33, 161–177.
Bényei, A. and Joó, F. (1990) Organometallic catalysis in aqueous solutions: the biphasic transfer hydrogenation of aldehydes catalyzed by water-soluble phosphine complexes of ruthenium, rhodium and iridium, J. Mol. Catal. 58, 151–163.
Lindner, E., Schober, R., Fawzi, R., Englert, U., and Wegner, P. (1987) Synthesis and reactivity of ruthenium(II) complexes containing ether-phosphine ligands, Chem. Ber. 120, 1621 -1628.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Šabata, S., Včelák, J., Hetflejš, J. (1995). Comparative Study of Biphase Reduction of Carbonyl Compounds Catalyzed by Homogeneous and Water Soluble Ru Catalysts. In: Horváth, I.T., Joó, F. (eds) Aqueous Organometallic Chemistry and Catalysis. NATO ASI Series, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0355-8_17
Download citation
DOI: https://doi.org/10.1007/978-94-011-0355-8_17
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4158-4
Online ISBN: 978-94-011-0355-8
eBook Packages: Springer Book Archive