Abstract
Chemistry is not just a science that involves the study of electron movement to rearrange and connect atoms. It is a philosophy, a way of thinking about the world. It is a way of thinking about die architecture, complexity and function of matter throughout the dimensional hierarchy of the universe, from the simplest atoms to the most complex phenomena-namely life itself. The ideas described here evolved from such a scientific and a philosophical perspective. They deal to a large extent with the analysis and mimicry of simple but pervasive patterns observed in Nature. Furthermore, they focus on the organization of monomer or branch cell units around atomic or molecular reference cores according to dendritic rules and principles. These synthetic constructions have allowed molecular level mimicry of pervasive architectural and mathematical patterns observed at either the macroscopic or at the atomic levels of matter.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Dvornic, P.R. and Tomalia, D.A. (1994) A family tree for polymers. Chemistry in Britain, 30, 641–645.
Tomalia, D.A., Baker, H., Dewald, J., Hall, M., Kallos, G., Martin, S., Roeck, J., Ryder, J., and Smith, P. (1985) A new class of polymers: starburst-dendritic macromolecules, Polymer J. (Tokyo), 17, 117–132.
Buhleier, E., Wehner, W., and Vögtle, F. (1978) “Cascade”— and “nonskid-chain-like” syntheses of molecular cavity topologies, Synthesis, 155–158.
Denkewalter, R.G., Kolc, J.F., and Lukasavage, W.J. (1983) U.S. Pat. 4410688; (1984) Chem. Abstr., 100, 103907p.
Newkome, G.R., Yao, Z.-Q., Baker, G.R., and Gupta, V.K. (1985) Cascade molecules: a new approach to micelles. A [27]-arborol, J. Org. Chem., 50, 2003–2004.
Tomalia, D.A. (1986) Dendritic macromolecules: synthesis of starburst dendrimers, Macromolecules, 19, 2467–2468.
Tomalia, D.A., Naylor, A.M., and Goddard III, W.A. (1990) Starburst dendrimers: molecular-level control of size, shape, surface chemistry, topology, and flexibility from atoms to macroscopic matter, Angew. Chem., 102, 119–157; (1990) Angew. Chem. Int. Ed. Engl., 29, 138-175.
Tomalia, D.A., and Durst, H.D. (1993) Genealogically directed synthesis: starburst*/cascade dendrimers and hyperbranched structures, in E. Weber (ed.), Topics in Current Chemistry Vol. 165; Supramolecular Chemistry I — Directed Synthesis and Molecular Recognition, Springer-Verlag, Berlin Heidelberg, pp. 93–313.
Hawker, C.J., and Fréchet, J.M.J. (1990) Preparation of polymers with controlled molecular architecture. A new convergent approach to dendritic macromolecules, J. Am. Chem. Soc., 112, 7638–7647.
Tomalia, D.A. (1993) Starburst™/cascade dendrimers: fundamental building blocks for a new nanoscopic chemistry set, Aldrichimica Acta, 26, 91–101.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Tomalia, D.A. (1995). Dendrimers — Nanoscopic Supermolecules According to Dendritic Rules and Principles. In: Siegel, J.S. (eds) Supramolecular Stereochemistry. NATO ASI Series, vol 473. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0353-4_4
Download citation
DOI: https://doi.org/10.1007/978-94-011-0353-4_4
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4157-7
Online ISBN: 978-94-011-0353-4
eBook Packages: Springer Book Archive