Abstract
Selectivity is at the heart of Chemistry and the control of reactions using lasers has been a goal for decades. Recently, we[1]–[20] and other groups[21]–[30] have demonstrated theoretically that one can achieve this goal by using quantum interference phenomena. We showed that phases acquired by a quantum systems while excited by lasers enable one to control quantum interferences, and hence the outcome, of many dynamical processes. Initial experimental tests[31]–[36] of our approach, termed Coherent Control (CC), have confirmed many of the theoretical predictions and proven the viability of the method.
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References
P.Brumer and M. Shapiro, Chem. Phys. Lett. 126, 541 (1986).
M. Shapiro and P. Brumer, J. Chem. Phys. 84, 4103 (1986).
P. Brumer and M. Shapiro, Faraday Disc. Chem. Soc. 82, 177 (1986).
M. Shapiro and P. Brumer, J. Chem. Phys. 84, 4103 (1986).
C. Asaro, P. Brumer and M. Shapiro, Phys. Rev. Lett. 60, 1634 (1988).
M. Shapiro, J. Hepburn and P. Brumer, Chem. Phys. Lett. 149, 451 (1988).
P. Brumer and M. Shapiro, J. Chem. Phys. 90, 6179 (1989).
G. Kurizki, M. Shapiro and P. Brumer, Phys. Rev. B 39, 3435 (1989).
T. Seideman, M. Shapiro and P. Brumer, J. Chem. Phys. 90, 7136 (1989).
J. Krause, M. Shapiro and P. Brumer, J. Chem. Phys. 92, 1126 (1990).
I. Levy, M. Shapiro and P. Brumer J. Chem. Phys. 93, 2493 (1990).
P. Brumer and M. Shapiro, Accounts Chem. Res. 22, 407 (1989).
P. Brumer and M. Shapiro, Chem. Phys. 139, 221 (1989).
C.K. Chan , P. Brumer and M. Shapiro, J. Chem. Phys. 94, 2688 (1991).
M. Shapiro and P. Brumer, J. Chem. Phys. 95, 8658 (1991).
P. Brumer and M. Shapiro, Ann. Rev. Phys. Chem., 43, 257 (1992).
M. Shapiro and P. Brumer, J. Chem. Phys. 97, 6259 (1992).
Z. Chen, P. Brumer and M. Shapiro, Chem. Phys. Lett. 198, 498 (1992).
X-P. Jiang, P. Brumer and M. Shapiro “Partially Coherent Laser Pulses in Coherent Control of Chemical Reactions” J. Chem. Phys., ( to be submitted).
J. Dods, P. Brumer and M. Shapiro, “Two Color Coherent Control with SEP Preparation: Electronic Branching in the Na2 Photodissociation” Can. J. Chem., submitted.
D. J. Tannor and S. A. Rice, J. Chem. Phys. 83, 5013 (1985)
D. J. Tannor, R. Kosloff and S. A. Rice, J. Chem. Phys. 85, 5805 (1986).
S.A. Rice, D.J. Tannor, and R. Kosloff, J. Chem. Soc. Faraday Trans. 2, 82, 2423 (1986)
D.J. Tannor, and S.A. Rice, Adv. Chem. Phys. 70, 441 (1988).
R. Kosloff, S.A. Rice, P. Gaspard, S. Tersigni, and D.J. Tannor , Chem. Phys. 139, 201 (1989).
S. Tersigni , P. Gaspard and S.A. Rice, J. Chem. Phys. 93, 1670 (1990).
S. Shi, A. Woody, and H. Rabitz, J. Chem. Phys. 88, 6870 (1988)
S. Shi and H. Rabitz, Chem. Phys. 139, 185 (1989).
A.P. Peirce, M. Dahleh, and H. Rabitz, Phys. Rev. A 37, 4950 (1988).
S. Shi, and H. Rabitz, J. Chem. Phys. 92, 364 (1990).
J.L. Krause, R.M. Whitnell, K.R. Wilson, Y. Yan and S. Mukamel, J. Chem. Phys. 99, 6562 (1993)
W. Jakubetz, B. Just, J. Manz, and H.-J. Schreier, J. Phys. Chem. 94, 2294 (1990).
C. Chen, Y-Y. Yin, and D.S. Elliott, Phys. Rev. Lett. 64, 507 (1990)
ibid ,65, 1737 (1990).
S.M. Park, S-P. Lu, and R.J. Gordon, J. Chem. Phys. 94, 8622 (1991)
S-P. Lu, S.M. Park, Y. Xie, and R.J. Gordon, J. Chem. Phys. 96, 6613 (1992).
N.F. Scherer, A.J. Ruggiero, M. Du, G.R. Fleming, J. Chem. Phys. 93, 856 (1990).
K.J. Boiler, A. Lmamoglu and S.E. Harris, Phys. Rev. Lett. 66, 2593 (1991).
B.A. Baranova, A.N. Chudinov, and B. Ya Zel’dovitch, Opt. Comm., 79, 116 (1990).
Y-Y. Yin, C. Chen, D.S. Elliott, and A.V. Smith, Phys. Rev. Lett. 69, 2353 (1992)
For a discussion of the basic principles of coherence, quantum interference, time dependence, which are fundamental to coherent control, see, e.g., J.D. Macomber, “The Dynamics of Spectroscopic Transitions”, (Wiley, N.Y., 1976).
This the asymptotic condition of scattering theory [see, J.R. Taylor, “Scattering Theory”, (J. Wiley, N.Y., 1972)].
M. Shapiro and R. Bersohn, J. Chem. Phys. 73, 3810 (1980).
M. Shapiro, J.Phys. Chem, 90, 3644 (1986).
M. Shapiro, J. Chem. Phys. 56 2582 (1972)
M. Shapiro and P. Brumer, in “Methods of Laser Spectroscopy”, ed. A. Prior, A. Ben-Reuven and M. Rosenbluh (Plenum, N.Y., 1986).
Z. Chen, M. Shapiro and P. Brumer, “Control of Photodissociation Branching Ratios via Two Color Frequency Tuning of Intense Laser Fields” Phys. Rev. Lett. - submitted.
M.S. Child, Mol. Phys. 32, 495 (1976).
Z. Chen, P. Brumer, and M. Shapiro, J. Chem. Phys. 98, 6843 (1993).
S. Chelkowski and A.D. Bandrauk, Chem. Phys. Lett. 186, 284 (1991)
A.D. Bandrauk, J.M. Gauthier, J.F. McCann, Chem. Phys. Lett. 200, 399 (1992)
S. Chelkowski, A.D. Bandrauk, and P.B. Corkum, Phys. Rev. Lett. 65, 2355 (1990).
A. Szöke, K.C. Kulander, and J.N. Bardsley, J. Phys. B 24, 3165 (1991)
R.M. Potvliege and P.H.G. Smith, J. Phys. B 25, 2501 (1992)
E. Charron, A. Guisti-Suzor and F.H. Mies, Phys. Rev. Lett. 71, 692 (1993).
Contrary to popular expectation, perturbation theory does not imply a small total photodissociation yield. Computational results (P. Brumer and M. Shapiro - to be published) indicate that perturbation theory is quantitatively correct for dissociation probabilities as large as 0.2.
M. Shapiro and P. Brumer, J. Chem. Phys. 98, 201 (1993).
N.E. Henriksen and B. Amstrup, Chem. Phys. Lett. 213, 65 (1993)
J. Chem. Phys. 97, 8285 (1993)
K.R. Wilson, private communication.
A.R. Edmonds, “Angular Momentum in Quantum Mechanics” (Princeton University Press, Princeton 2nd edition, 1960).
I. Levy and M. Shapiro, J. Chem. Phys. 89, 2900 (1988).
R. Bavli and H. Metiu, Phys. Rev. Lett., ().
M. Yu Ivanov, P.B. Corkum, and P. Dietrich, Laser Physics, 3, 375 (1993).
T. Nakajima and P. Lambropoulos, Phys. Rev. Lett. 70, 1081 (1993).
P.Bmmer and M.Shapiro, Adv. Chem. Phys. 60 371, K. P. Lawley, Ed., (Wiley- Interscience Pub., 1986).
M. Shapiro and H. Bony, J. Chem. Phys. 83, 1588 (1985)
G. G. Balint-Kurti and M.Shapiro, Adv. Chem. Phys. 60 403, K. P. Lawley, Ed., (Wiley-Interscience Pub., 1986).
A. D. Bandrauk and O. Atabek, Adv. Chem. Phys. 73, 823 (1989)
The potential curves and the relevant electronic dipole moments are taken from: I. Schmidt, Ph.D. Thesis, Kaiserslautern University, 1987.
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Shapiro, M., Brumer, P. (1995). Coherent and Incoherent Laser Control of Photochemical Events. In: Yurtsever, E. (eds) Frontiers of Chemical Dynamics. NATO ASI Series, vol 470. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0345-9_7
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DOI: https://doi.org/10.1007/978-94-011-0345-9_7
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