Skip to main content

Time—Dependent Nuclear Dynamics of Decaying States

  • Chapter
Frontiers of Chemical Dynamics

Part of the book series: NATO ASI Series ((ASIC,volume 470))

  • 183 Accesses

Abstract

The wavepacket dynamics accompanying the excitation to a decaying electronic state and the subsequent decay to final electronic states are discussed. The cross—sections for the excitation and for the production of final states are related to the corresponding wavepackets. The time—dependent formulation adds insight into the process and is amenable to semiclassical approximations and interpretations. It can also be used to compute the gross features of the observed spectra via a spectral moment expansion. An illustrative application demonstrates the usefulness of the expansion.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Lim, E.C.(1974) Excited States ,Academic Press, New York

    Google Scholar 

  2. Ma, Y., Sette, F., Meigs, G., Modesti, S. and Chen, C.T. (1989) Phys. Rev. Lett. 63, 2044

    Article  ADS  Google Scholar 

  3. Rabus, H. et al. (1990) Phys. Scr. T 31, 131

    Article  ADS  Google Scholar 

  4. Gadea, F.X. et al. (1991) Phys. Rev. Lett. 66, 883

    Article  ADS  Google Scholar 

  5. Hitchcok, A.P. and Brion, C.E. (1977) J. Electr. Spectr. 10, 317

    Article  Google Scholar 

  6. Tronc, M., King, G.C. and Read, F.H. (1979) J. Phys. B 12, 137

    Article  ADS  Google Scholar 

  7. Thompson, M., Baker, M.D., Christie, A. and Tyson, J.F. (1985) Auger Electron Spectroscopy ,Wiley, New York

    Google Scholar 

  8. Correira, N., Flores-Riveros, A., Ågren, H., Helenelund, K., Asplund, L. and Gelius, U. (1985) J. Chem. Phys. 83, 2035

    Article  ADS  Google Scholar 

  9. Svenson, S. and Karlsson, L. (1992) Phys. Scr. T 41, 132

    Article  ADS  Google Scholar 

  10. Plummer, E.W., Chen, C.T., Ford, W.K., Eberhardt, W., Messmer, R.P. and Freund, H.-J. (1985) Surf. Sci. 158, 58

    Article  ADS  Google Scholar 

  11. Nordgren, J., Selander. L., Pettersson, L., Nordling, C, Siegbahn, K. and Ågren, H. (1982) J. Chem. Phys. 76, 3928

    Article  ADS  Google Scholar 

  12. Deslattes, R.D. (1986) Aust. J. Phys. 39, 845

    ADS  Google Scholar 

  13. Southworth, S.H., Parr, A.C., Hardis, J.E. and Dehmer, J.L. (1987) J. Chem. Phys. 87, 5125

    Article  ADS  Google Scholar 

  14. Dehmer, J.L., Dill, D. and Parr, A.C. (1983) Photophysics and Photochemistry in the Vacuum Ultraviolet ,eds. S. McGlynn, G. Findley and R. Huebner, Reidel Publ., Dordrecht

    Google Scholar 

  15. Ferrett, T.A., Piancastelli, M.N., Lindle, D. W., Heimann, P.A., Medhurst, L.J., Liu, S.H. and Shirley, D.A. (1987) Chem. Phys. Lett. 134, 146

    Article  ADS  Google Scholar 

  16. Schulz, G.J. (1973) Rev. Mod. Phys. 45, 423

    Article  ADS  Google Scholar 

  17. Borrow, P.D., Michejda, J.A. and Jordan, K.D. (1987) J. Chem. Phys. 86, 9

    Article  ADS  Google Scholar 

  18. Domcke, W. (1991) Phys. Rep. 208, 97

    Article  ADS  Google Scholar 

  19. Morin, P. and Nenner, I. (1986) Phys. Rev. Lett. 56, 1913; Phys. Scr. T 17, 171

    Article  ADS  Google Scholar 

  20. Le Forestier, C, Bisseling, R., Verjan, C, Feit, M.D., Friesner, R., Guldberg, A., Hammerich, A., Jolicard, G., Karrlein, W., Meyer, H.-D., Lipkin, N., Roncero, O. and Kosloff, R. (1991) J. Comp. Phys. 94, 59

    Article  ADS  Google Scholar 

  21. Schinke, R. and Engel, V. (1990) J. Chem. Phys. 93, 3252

    Article  ADS  Google Scholar 

  22. Kulander, K.C., Cerjan, C. and Orel, A.E. (1991) ibid. 94, 2571

    ADS  Google Scholar 

  23. Manthe, U. and Köppel, H. (1991) Chem. Phys. Lett. 178, 36

    Article  ADS  Google Scholar 

  24. Cederbaum, L.S., Campos, P., Tarantelli, F. and Sgamellotti, A. (1991) J. Chem. Phys. 95, 6634

    Article  ADS  Google Scholar 

  25. Cederbaum, L.S. and Tarantelli, F. (1993) J. Chem. Phys. 98, 9691

    Article  ADS  Google Scholar 

  26. Cederbaum, L.S. and Tarantelli, F. (1993) J. Chem. Phys.99, 5871

    Article  ADS  Google Scholar 

  27. Kaspar, F., Domcke, W. and Cederbaum, L.S. (1979) Chem. Phys. 44, 33

    Article  Google Scholar 

  28. Domcke. W. and Cederbaum, L.S. (1981) J. Phys. B 14, 149

    Article  ADS  Google Scholar 

  29. Rohr, K. and Linder, F. (1975) J. Phys. B 8, L200

    Article  ADS  Google Scholar 

  30. Bienek, R.J. (1980) J. Phys. B 13, 4405

    Article  ADS  Google Scholar 

  31. Cederbaum, L.S. and Domcke, W. (1981) ibid. 14, 4665

    ADS  Google Scholar 

  32. Pahl, E., Meyer, H.-D. and Cederbaum, L.S. to be published

    Google Scholar 

  33. Gel’mukhanov, F.K., Mazalov, L.N. and Kondratenko, A.V. (1977) Chem. Phys. Lett. 46, 133

    Article  ADS  Google Scholar 

  34. Correira, N., Flores-Riveros, A., Ågren, H., Helenelund, K., Asplund, L. and Gelius, U. (1985) J. Chem. Phys. 83, 2035

    Article  ADS  Google Scholar 

  35. Cesar, A., Ågren, H. and Carravetta, V. (1989) Phys. A 40, 187

    ADS  Google Scholar 

  36. Domcke, W. and Cederbaum, L.S. (1977) Phys. Rev. A 16, 1465

    Article  ADS  Google Scholar 

  37. Cramer, H. (1946) Mathematical Methods of Statistics Princeton University Press, Princeton

    MATH  Google Scholar 

  38. Cederbaum, L.S. and Domcke, W. (1977) Adv. Chem. Phys. 36, 205

    Article  Google Scholar 

  39. Davydov, A.S., (1965) Quantum Mechanics ,Pergamon Press, New York

    Google Scholar 

  40. Dimensionless normal coordinates are obtained from the usual normal coordinates by dividing the latter by the square root of the corresponding frequency

    Google Scholar 

  41. Meyer, H.D. (1981) Chem. Phys. 61, 365

    Article  ADS  Google Scholar 

  42. Carrol, T.X. and Thomas, T.D. (1987) J. Chem. Phys. 86, 5221

    Article  ADS  Google Scholar 

  43. Kelber, J.A., Jennison, D.R. and Rye, R.R. (1981) ibid. 75, 652

    ADS  Google Scholar 

  44. Ungier, L. and Thomas, T.D. (1985) ibid. 82, 3146

    ADS  Google Scholar 

  45. Moddeman, W.E., Carlson, T.A., Krause, M.O., Pullen, B.P., Bull, W.E. and Schweizer, G.K. (1971) ibid. 55, 2317

    ADS  Google Scholar 

  46. Pahl, E. 1993 Diplom Theses, University of Heidelberg

    Google Scholar 

  47. Pahl, E. (1993) Diplom Theses, University of Heidelberg

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1995 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Cederbaum, L.S., Tarantelli, F. (1995). Time—Dependent Nuclear Dynamics of Decaying States. In: Yurtsever, E. (eds) Frontiers of Chemical Dynamics. NATO ASI Series, vol 470. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0345-9_13

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-0345-9_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4153-9

  • Online ISBN: 978-94-011-0345-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics