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NMR Characterization of Ceramic Materials Derived from Preceramic Polymers

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Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials

Part of the book series: NATO ASI Series ((NSSE,volume 297))

Abstract

A large number of ceramics can now be produced via the pyrolysis of polymers [1–3]. These new synthetic routes to ceramics are particularly suitable for the production of fibers [4], coatings [5] or reactive amorphous powders for sintering [6]. Two main routes are used to prepare the preceramic polymers, either the sol-gel process to get oxo-polymers, or organo-metallic chemistry to prepare essentially silicon-based polymers such as polysilanes, polycarbosilanes or polysilazanes. Depending on the pyrolysis atmosphere, oxo-polymers can be transformed into oxides, but also into oxycarbides or oxynitrides, while polysilanes, polycarbosilanes and polysilazanes can be converted into silicon carbide, silicon nitride or silicon carbonitride.

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Author information

Authors and Affiliations

  1. Chimie de la Matière Condensée, Université Pierre et Marie Curie - URA CNRS 1466, 4 place Jussieu, 75005, Paris, France

    Florence Babonneau

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  1. Florence Babonneau
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Editors and Affiliations

  1. Department of Chemistry, McGill University, Montreal, Quebec, Canada

    John F. Harrod

  2. Materials Science & Engineering, College of Engineering, Ann Arbor, Michigan, USA

    Richard M. Laine

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Babonneau, F. (1995). NMR Characterization of Ceramic Materials Derived from Preceramic Polymers. In: Harrod, J.F., Laine, R.M. (eds) Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials. NATO ASI Series, vol 297. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0337-4_6

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  • DOI: https://doi.org/10.1007/978-94-011-0337-4_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4149-2

  • Online ISBN: 978-94-011-0337-4

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