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Chemicals, Polymers and Ceramics from the Beach. II.

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Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials

Part of the book series: NATO ASI Series ((NSSE,volume 297))

Abstract

We recently discovered methods of dissolving silica in ethylene glycol in the pres- ence of alkali and alkaline base to form anionic pentacoordinated or dianionic hexacoordinated silicon complexes. We report here that the use of strong amine bases can be used in catalytic or stoichiometric quantities to form neutral tetracoordinate siloxanes containing only silicon and ethylene glycol or silicon, triethanolamine and ethy- lene glycol (silatrane glycol). We also find that aluminum hydroxide will dissolve under similar conditions to form alumatranes.

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Author information

Authors and Affiliations

  1. Contribution from the Departments of Materials Science & Engineering, and Chemistry, University of Michigan, Ann Arbor, MI, 48109-2136, USA

    Richard M. Laine

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  1. Richard M. Laine
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Editor information

Editors and Affiliations

  1. Department of Chemistry, McGill University, Montreal, Quebec, Canada

    John F. Harrod

  2. Materials Science & Engineering, College of Engineering, Ann Arbor, Michigan, USA

    Richard M. Laine

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Laine, R.M. (1995). Chemicals, Polymers and Ceramics from the Beach. II.. In: Harrod, J.F., Laine, R.M. (eds) Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials. NATO ASI Series, vol 297. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0337-4_4

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  • DOI: https://doi.org/10.1007/978-94-011-0337-4_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4149-2

  • Online ISBN: 978-94-011-0337-4

  • eBook Packages: Springer Book Archive

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