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Chemical Approaches to Nanoscale Magnetic Materials

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Part of the book series: NATO ASI Series ((NSSE,volume 297))

Abstract

Materials science in the last few years has become more and more interested at nanoscale phases, where the volume-to-surface area ratio of the bulk material rapidly decreases, conferring to the materials novel properties [1]. From the chemical point of view new synthetic techniques are being developed, aiming at obtaining new materials with varied structural, optical, and transport properties. This new branch of chemistry has also found a new name: nanochemistry. As in normal chemistry the object of interest is the molecule, in nanochemistry it is the nanocluster, intended as a large array of atoms kept together by chemical bonds, which is isolated from other identical or similar objects. Often the nanoclusters are incorporated into a processable matrix, and the combination of the two defines a nanocomposite.

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References

  1. Stucky, G.D. (1992), in Lippard, S.J. (ed), Progr. Inorg. Chem., 40, 99.

    Chapter  Google Scholar 

  2. Gatteschi, D., Caneschi, A., Pardi, L., Sessoli, R., (1994), Science, in press.

    Google Scholar 

  3. Gatteschi, D., (1994), Adv. Mater., in press.

    Google Scholar 

  4. McMichael, R.D., Shull, R.D., Swatzendruber, L.J., Bennett, L.H., (1992) J. Magn. Magn. Mater., 111, 29.

    Article  CAS  Google Scholar 

  5. Kemp., W. (1986) NMR in Chemistry - A Multinuclear Introduction, McMillan, London.

    Google Scholar 

  6. Xiao, J.R., Jang, J.S., Chien. C.L. (1992) Phys. Rev. Lett., 68, 3749.

    Article  CAS  Google Scholar 

  7. Anton, I. (1990) J. Magn. Mater., 85, 219.

    Article  CAS  Google Scholar 

  8. Molday, R.S., Yen, S.P.S., Rembaum, A. (1977) Nature, 268, 437.

    Article  CAS  Google Scholar 

  9. Leggett, A.J. (1984) Phys. Rev. B30, 1208.

    Google Scholar 

  10. Awstchalom, D.D.; Di Vincenzo, D.P., Smyth, J.F. (1992) Science, 258, 414.

    Article  Google Scholar 

  11. Tejada, J., Zhang, X.X., Baicelles, L. (1993) J. Appl. Phys., 73, 6709.

    Article  CAS  Google Scholar 

  12. Barbara, B., Sampaio, L.C., Wegrowe, J.E., Ratham, B.A., Marchand, A., Paulsen, C., Novak, M.A., Tholence, J.L., Uehara, M., Fruchart, D. (1993) J. Appl. Phys., 73, 6700.

    Article  Google Scholar 

  13. Neel, L. (1949)Ann. Geophys., 5, 99.

    Google Scholar 

  14. Ford, G.C. et al. (1984) Philos. Trans. R. Soc. London Ser. B., 304, 551.

    Article  CAS  Google Scholar 

  15. Chini, P. (1979) Gazz. Chim. It., 109, 229.

    Google Scholar 

  16. Schmid, G,, Klein, N. (1986) Angew. Chem. Int. Ed. Engl., 98, 910.

    Article  CAS  Google Scholar 

  17. Pronk, B.J., Brom, H.B., Longoni, G., Ceriotti, A. (1987) Solid State Commun., 64, 7.

    Article  CAS  Google Scholar 

  18. Van Staveren, M.P.J., Brom, H.B., de Jongh, L.J. (1991) Phy. Rep., 208, 1.

    Article  Google Scholar 

  19. Sapieszko, RS., Matijevic, E. (1980) Corrosion, 522.

    Google Scholar 

  20. Matijevic, E. (1991) Faraday Discuss., 92, 229.

    Article  CAS  Google Scholar 

  21. Gangopadhyay, S., Yiping, L., Hadjipanayis, G.C., Sorensen, C.M., Klabunde, K.J., Papaefthymiou, V., Kostikas, A. (1992) in Jena, P. (ed.) Physics and Chemistry of Finite Systems: From Clusters to Crystals, Kluwer Academic Publishers, Dordrecht, p. 743.

    Google Scholar 

  22. Arrighini, G.P., personal communication.

    Google Scholar 

  23. Mann, S., Frankel, R.B. (1989), in Mann, S., Webb, J., Williams, R.J.P. (eds.), Biomineralization Chemical and Biochemical Pespectives, VCH, Weinheim, 389.

    Google Scholar 

  24. Meldrum, F.C., Heywood, B.R., Mann, S. (1992) Science, 257, 522.

    Article  CAS  Google Scholar 

  25. Fendler, J.H. (1987) Chem. Rev., 87, 873.

    Article  Google Scholar 

  26. O’Reilly, A.M., Winefordner, J.D. (1988) Spectrochimica Acta, 44A, 1395.

    Google Scholar 

  27. Ziolo, R.F., Giannelis, E.P., Weinstein, BA., O’Horo, M.P., Ganguly, B.N., Mehrotra, V., Rüssel, M.W., Huffmann, D.R. (1992) Science, 257, 219.

    Article  CAS  Google Scholar 

  28. Miller, J.S. (1992) Adv. Mater., 4, 298.

    Article  CAS  Google Scholar 

  29. Palacio, F., Castro, C., Reyes, J., Sturgeon, G., Lazaro, F.J., Gonzales-Calbet, J., in come ref. 21,793.

    Google Scholar 

  30. Tang, Z.X., Sorensen, C.M., Klabunde, K.J., Hadjipanayis (1991) J. Colloid Interf. Science, 146, 38.

    Article  CAS  Google Scholar 

  31. Pope, M.T. (1983) Heteropoly and Isopoly Oxometalates, Springer, New York.

    Google Scholar 

  32. Müller, A., Krickenmeyer, E., Penk, M., Walberg, M.J., Bögge. H. (1987), Angew. Chem. Int. Ed. Engl., 26, 1045.

    Article  Google Scholar 

  33. Müller, A., Döring, J. (1988) Angew. Chem. Int. Ed. Engl., 27, 1721.

    Article  Google Scholar 

  34. Barra, A.-L., Gatteschi, D., Pardi, L., Müller, A., Döring, J. (1992) J. Am. Chem. Soc., 114, 8059.

    Google Scholar 

  35. Gatteschi, D., Pardi, L., Barra, A.-L., Müller, A. (1991) Nature, 354, 463.

    Article  CAS  Google Scholar 

  36. Gatteschi, D., Tsukerblatt, B., Barra, A.-L., Brunei, L.-C., Müller, A., Döring, J. (1993) Inorg. Chem., 32, 2114.

    Article  CAS  Google Scholar 

  37. Gatteschi, D., Pardi, L., Barra, A.-L., Müller, A. (1993) Mol. Eng., 3, 157.

    Article  CAS  Google Scholar 

  38. Müller, A., Plass, W., Krickenmeyer, E., Dillinger, S., Bögge, A., Armatage, A., Proust, A., Bengholt, C., Bergmann, V. (1994) Angew. Chem. Int. Ed. Engl., 33, 849.

    Article  Google Scholar 

  39. Cannon, R.D., White, R.P. (1988) in Lippard, S.J. (ed.), Progr. Inorg. Chem., 36, 195.

    Chapter  Google Scholar 

  40. Micklitz, W., Lippard, S.J. (1989) J. Am. Chem. Soc., 111, 6856.

    Article  CAS  Google Scholar 

  41. Papaefthymiou, G. (1992) Phys. Rev. B., 46, 10366.

    Article  CAS  Google Scholar 

  42. Heath, S.L., Powell, A.K. (1992) Angew. Chem. Int. Ed. Engl., 31, 191.

    Article  Google Scholar 

  43. Powell, A.K., Heath, S.L., Gatteschi, D., Pardi, L., Sessoli, R., Spina, G., Del Giallo, F., Pieralli, F., submitted for publication.

    Google Scholar 

  44. Hegetschweiler, K., Schmalle, H.W., Streit, H.M., Grämlich, V., Hund, H.U., Erni, I. (1992) Inorg. Chem., 31, 1299.

    Article  CAS  Google Scholar 

  45. Sessoli, R., Gatteschi, D., Caneschi, A., Novak, M.A. (1993) Nature, 365, 141.

    Article  CAS  Google Scholar 

  46. Lis, T. (1980) Acta Crystallogr. Sect. B., 36, 2042.

    Article  Google Scholar 

  47. Igonin, V.A., Shchegolikhina, O.I., Lindeman, S.V., Levitsky, M.M., Struchkov, Yu. T., Zhdanov, A.A. (1992) J. Organomet. Chem., 420, 351.

    Article  Google Scholar 

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Gatteschi, D. (1995). Chemical Approaches to Nanoscale Magnetic Materials. In: Harrod, J.F., Laine, R.M. (eds) Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials. NATO ASI Series, vol 297. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0337-4_18

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  • DOI: https://doi.org/10.1007/978-94-011-0337-4_18

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4149-2

  • Online ISBN: 978-94-011-0337-4

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