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Composition, Geochemistry and Conversion of Oil Shales pp 379–385Cite as

A Probe for the Rapid Analysis of Vanadium: An Electron Paramagnetic Resonance and Theoretical Perspective

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Part of the book series: NATO ASI Series ((ASIC,volume 455))

Abstract

The structure and bonding of several substituted benzenes (C6H5F, 1,4C6H4F2 and 1,3,5-(C6H3(CH3)3) with vanadium has been investigated by electron paramagnetic resonance (EPR) spectroscopy and semi-empirical quantum chemical ZINDO/1 calculations. As the arene electron withdrawing ability increases, the vanadium hyperfine splitting of the corresponding organometallic complex decreases. The calculated vanadium-ligand bond dissociation energies for these complexes increases with the increase of the π-electron density in their 2pz(C) orbitals. These observations indicate that EPR may be a rapid probe for the analysis of vanadium organometallic compounds.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of New Brunswick, Bag Service No. 45222, Fredericton, New Brunswick, Canada, E3B 6E2

    S. M. Mattar, R. Sammynaiken & I. Unger

Authors
  1. S. M. Mattar
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  2. R. Sammynaiken
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  3. I. Unger
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Editor information

Editors and Affiliations

  1. Department of Pure and Applied Chemistry, University of Stratchclyde, Glasgow, Scotland, UK

    Colin Snape

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© 1995 Springer Science+Business Media Dordrecht

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Mattar, S.M., Sammynaiken, R., Unger, I. (1995). A Probe for the Rapid Analysis of Vanadium: An Electron Paramagnetic Resonance and Theoretical Perspective. In: Snape, C. (eds) Composition, Geochemistry and Conversion of Oil Shales. NATO ASI Series, vol 455. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0317-6_23

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  • DOI: https://doi.org/10.1007/978-94-011-0317-6_23

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4140-9

  • Online ISBN: 978-94-011-0317-6

  • eBook Packages: Springer Book Archive

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