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Wide Band Gap Electronic Materials pp 271–283Cite as

Extended and Localized Electronic States in Tetrahedral Carbon Films

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Part of the book series: NATO ASI Series ((ASHT,volume 1))

Abstract

The disordered tetrahedral carbon films have been grown by ion beam deposition at ∼120 eV. An absorption maximum 6.15-5.80 eV (E B0 ) and a threshold 4.8-4.5 eV were resolved and tentatively attributed to Γ +5 - Γ -5 and Γ +5 - K2 transitions in lonsdaleite. The cubic sp3-carbon manifested as maxima at 5.45-5.50 eV (Γ′25 - Δx) and 7.0 eV (Γ′25 - Γ15). Urbach tails of different steepness were resolved. A 6.508 eV maximum of 0.52 eV half-width at 90K was resolved. The spectroscopic data on absorpsion and luminescence of sp3-bonded carbon films of different allotropies are discussed.

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Author information

Authors and Affiliations

  1. Institute of Steel and Alloys, Moscow, 117936, Russia

    V. E. Maschenko

  2. Institute of Single Crystals of the Ukrainian Academy of Sciences, Kharkov, 310141, Ukraine

    V. M. Puzikov

Authors
  1. V. E. Maschenko
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  2. V. M. Puzikov
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  3. A. V. Semenov
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Editor information

Editors and Affiliations

  1. University of Missouri-Columbia, Columbia, Missouri, USA

    Mark A. Prelas  & Tina Stacy  & 

  2. Florida A&M University/Florida State University, Tallahassee, Florida, USA

    Peter Gielisse

  3. Rockford Diamond Technology, Inc., Columbia, Missouri, USA

    Galina Popovici

  4. Russian Academy of Sciences, Moscow, Russia

    Boris V. Spitsyn

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© 1995 Springer Science+Business Media Dordrecht

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Maschenko, V.E., Puzikov, V.M., Semenov, A.V. (1995). Extended and Localized Electronic States in Tetrahedral Carbon Films. In: Prelas, M.A., Gielisse, P., Popovici, G., Spitsyn, B.V., Stacy, T. (eds) Wide Band Gap Electronic Materials. NATO ASI Series, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0173-8_28

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  • DOI: https://doi.org/10.1007/978-94-011-0173-8_28

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4078-5

  • Online ISBN: 978-94-011-0173-8

  • eBook Packages: Springer Book Archive

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