Mercury Concentrations In Two Great “Waters”

Abstract

Although many sources of Hg to surface waters have been identified including atmospheric deposition, resuspenseon of contaminated sediments, and direct discharges, there are very few recent data on ambient concentrations in the large lakes. Thus, an investigation of Hg concentrations in Lake Champlain and Lake Michigan was completed in the summer of 1993. Three depths of water including the microlayer, 30 cm below the surface, and 1 m below the thermocline were collected for each sampling event using ultra-clean techniques. All samples were processed in the field for dissolved and particulate fractions in a portable plastic enclosure equipped with a HEPA filter, and then analyzed by dual amalgamation and cold vapor atomic fluorescence spectroscopy in a Class 100 clean room at the University of Michigan. In addition, samples were analyzed for other trace metals by ICP-MS. Results from the two field investigations include the following: (1) On average, Lake Michigan water samples had higher concentrations of Hg than Lake Champlain; (2) There was no consistent pattern of Hg concentrations in the water column; (3) There was variability in the concentrations of Hg from the same depths over consecutive sampling periods. This paper discusses these results, and examines the relationship between the patterns in mercury concentrations and other physical and chemical data collected during the investigation.