Abstract
The development of metal carbonyl cluster chemistry in the last 30 years was stimulated by the perspective of using these derivatives as active and selective homogeneous catalysts; unfortunately this aspect was overestimated. The efficiency of clusters is severely limited by the low stability of the metal frame under the conditions required for some reactions, or by the difficulty of releasing the organic moieties without affecting the iratal core. Only a limited number of examples of intact cluster catalysis are known [1]. On the other hand, the difficulty of clusters in releasing organic moieties has been exploited for obtaining “models” of labile intermediates which could not be trapped in the reactions of mono- or binuclear catalysts [2].
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References and Notes
Süss-Fink, G. and Meister, G. (1993), Adv. Organomet. Chem. ,35, 41–134.
Boroni, E., Costa, M., Predieri, G., Sappa, E., Tiripicchio, A. (1992), J. Chem. Soc.Dalton Trans. ,2585–2590, and references therein.
Muetterties, EX., Rhodin, T.N., Band, E., Brucker, C.F. and Pretzer, W.R. (1979), Chem. Rev. ,79,91–137.
Gates, B.C., Gucz,i L. and Knözinger, H. (Eds), (1986), Metal Clusters in Catalysis ,Elsevier, Amsterdam
Whyman, R. in Basset, J. M., et al (Eds), Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis, Kluwer, Dordrecht, 1988, pp. 75–95.
Braunstein, P. and Rosé, J. (1989) in I. Bernal (Ed.) Stereochemistry of Organometallic and Inorganic Compounds ,Vol. 3, Elsevier, Amsterdam.
Fackler Jr, J.P. (Ed.) (1990) Metal-metal Bonds and Clusters in Chemistry and Catalysis ,Plenum, New York.
Psaro, R., Dossi, C., Sordelli, L., Ugo, R (1992), Chim. e. Ind ,74, 154–165.
Giordano, R. and Sappa, E. (1993), J. Organomet. Chem. ,448, 157–166, and references therein.
Castiglioni, M., Sappa, E., Valle, M., Lanfranchi, M. and Tiripicchio, A (1983), J.Organomet. Chem. ,241, 99–111.
Mays, M.J. and Simpson, R.N.F., (1968), J. Chem. Soc (A) ,1444–1447.
Castiglioni, M., Giordano, R., Sappa, E., Tiripicchio, A., Tiripicchio Camellini, M. (1986), J. Chem. Soc., Dalton Trans. ,23–30.
Castiglioni, M., Giordano, R. and Sappa, E. (1987), J. Organomet. Chem. ,319, 167–181.
Cauzzi, D., Giordano, R., Sappa, E., Tiripicchio, A., Tiripicchio Camellini, M. (1993) J. Cluster Sci. 4, 279–296.
Castiglioni, M., Gervasio, G., Sappa, E. (1981), Inorg. Chim. Acta. 49, 217–225.
Amadelli, R., Bartocci, C., Carassiti, V., Aime, S., Osella, D., Milone, L. (1985), Gazz. Chim. Ital. 115, 337–342.
Aime, S., Gobetto, R., Milone, L., Osella, D., Violano, L., Arce, A.J., and De Sanctis, Y. (1991) Organometallics ,10, 2854–2856.
Castiglioni, M., Giordano, R., Sappa, E., (1989), J. Organomet. Chem. ,369, 419–431.
Basu, A., Bhaduri, S., Sharma ,K., Jones, P.G., (1987), J. Chem. Soc. ,Chem. Commun. ,1126–1127.
Adams, R.D., Li, Z., Swepston, P., Wu,W., Yamamoto, Y., (1992), J. Am. Chem. Soc. ,114, 10657–10658.
Bianchi, M., Menchi, G., Matteoli, U., Piacenti, F. (1993), J. Organomet. Chem. ,451, 139–146 and references therein.
Castiglioni, M., Giordano, R., Sappa, E., manuscript in preparation.
Domingos, A.J.P., Johnson, B.F.G. and Lewis, J. (1972), J. Organomet. Chem. ,36C43–44.
Aime, S., Milone, L., Osella, D., Vaglio, G.A., Valle, M., Tiripicchio, A, and Tiripicchio Camellini ,M. (1979), Inorg. Chim. Acta. 34, 49–55.
Goudsmit, R.J., Johnson, B.F.G., Lewis, J., Raithby, P.R. and Rosales, M. (1983), J. Chem. Soc., Dalton Trans. ,2257–2261.
Johnson, B.F.G., Lewis, J., Martinelli, M., Wright, A.H., Braga, D. and Grepioni, F. (1990), J. Chem. Soc., Chem. Commun. 364–366.
Braga, D., Grepioni, F., Johnson, B.F.G., Lewis, J., Housecroft, C.E. and Martinelli, M. (1991), Organometallics ,10, 1260–1268.
Castiglioni, M., Giordano, R., Sappa, E., Predieri, G., Tiripicchio, A. (1984), J. Organomet. Chem. 270, C7–10.
Castiglioni, M., Giordano, R., Sappa, E. (1986), J. Mol. Cat. 37, 287–296.
Idem, ibidem (1987), 40, L65-69.
Castagno, F., Castiglion,i M., Sappa, E., Tiripicchio, A., Tiripicchio Camellini, M., Braunstein, P., Rose, J. (1989), J. Chem. Soc., Dalton Trans. ,1477–1482.
Moggi ,P., Albanesi, G., Predieri, G., Sappa, E. (1983), J. Organomet. Chem. ,252, C 89–92.
Albanesi, G., Bernardi, R., Moggi, P., Predieri, G., Sappa, E. (1986), Gazz. Chim. Ital. 116, 385–390.
Moggi, P., Predieri, G., Albanesi, G., Papadopoulos, S., Sappa, E. (1989), Appl. Cat. 53, L1–4.
Castiglioni, M., Giordano, R., Sappa, E. (1987), J. Mol. Cat. 42, 307–322.
Sakamoto, M., Shimizu, I and Yamamoto, A (1994), Organometallics 13, 407–409.
Predieri, G., Moggi, P., Papadopoulos, S., Armigliato, A., Bigi, S., Sappa, E. (1990) J. Chem. Soc., Chem. Commun. ,1736–1737.
Armigliato A., Bigi S., Moggi, P., Papadopoulos, S., Predieri, G., Salviati, G., Sappa, E. (1991), Materials Chem. and Phys. 29, 251–260.
Zecchina, A., Guglielminotti, E., Bossi, A. and Camia, M. (1982), J. Catal. 74, 225–239.
Guglielminotti, E., Zecchina, A., Bossi, A. and Camia, M. (1982), ibidem 74, 240–251.
Idem (1982), ibidem 74, 252–265.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Giordano, R., Sappa, E., Predieri, G. (1995). From Molecular Carbonyl Clusters to Supported Metal Particles Synthesis, Characterization, Catalysis . In: Farrugia, L.J. (eds) The Synergy Between Dynamics and Reactivity at Clusters and Surfaces. NATO ASI Series, vol 465. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0133-2_5
Download citation
DOI: https://doi.org/10.1007/978-94-011-0133-2_5
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4060-0
Online ISBN: 978-94-011-0133-2
eBook Packages: Springer Book Archive