Abstract
Our continuing interest in transformations of heteroatom-substituted alkynes on transition metal clusters [1,2] has prompted us to investigate reactions of silylalkynes with triruthenium and triosmium clusters.
It should be noted that reactions of silylalkynes with metal clusters have earlier been studied by several groups but these alkynes did not reveal any unusual reactivity. We observed, however, unusual transformations of silylalkynes on triruthenium and triosmium clusters, metal complexes bearing novel organic ligands, and novel rearrangements. These findings are the subject of the present report.
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Koridze, A.A. (1995). Reactions of Silylalkynes with Triosmium and Triruthenium Clusters. In: Farrugia, L.J. (eds) The Synergy Between Dynamics and Reactivity at Clusters and Surfaces. NATO ASI Series, vol 465. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0133-2_23
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DOI: https://doi.org/10.1007/978-94-011-0133-2_23
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