Skip to main content
SpringerLink
Log in

Silver and Gold Clusters Stabilized by Fe(CO)4 Ligands

  • Chapter
Book cover The Synergy Between Dynamics and Reactivity at Clusters and Surfaces

Part of the book series: NATO ASI Series ((ASIC,volume 465))

Summary

The reaction pathway of the oxidation of the [Fe(CO)4]2- dianion with Ag(I) and Au(I) salts to Fe(0) species, namely Fe(CO)5, Fe3(CO)12 and iron metal, involves the intermediate formation of several Ag-Fe and Au-Fe clusters, which may be selectively obtained by using substoichiometric molar ratios (comprised in the 0.33-1.75 range) between the reagents. On the basis of isolobal analogies, all the compounds which have been structurally characterized so far may be viewed as clusters of Group 11 elements stabilized by d8-Fe(CO)4 or bidentate Fe2(CO)8 ligands, in their several possible carbonyl stereochemistries. Rationalization of the miscellaneous steps of the above reactions enabled the synthesis of related heterometallic Cu-Ag and Au-Ag clusters. Their spectroscopic and structural behaviour are compared with those of previously reported Cu, Pd and Pt related compounds, as well as the corresponding Cu, Ag and Au cluster derivatives stabilized by d9-Co(CO)4 groups.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Shriver, D.F., Kaesz, H.D., and Adams, R.D. Eds. (1990) The Chemistry of Metal Cluster Complexes ,VCH Publishers, Inc, New York.

    Google Scholar 

  2. Salter, I.D. (1989) Heteronuclear Cluster Chemistry of Copper, Silver and Gold, Adv.Organomet.Chem. 29, 249–343.

    Article  CAS  Google Scholar 

  3. Hall, K.P. and Mingos, D.M.P., (1984) Homo-and Heteronuclear Cluster Compounds of Gold, Prog.Inorg.Chem. ,32, 237–325.

    Article  CAS  Google Scholar 

  4. Whitmire, K.H. (1988) The Interface of Main Group and Transition Metal Cluster Chemistry, J.Coord.Chem. 17, 95–203.

    Article  CAS  Google Scholar 

  5. Hermann, W.A., (1986) Angew. Chem.Int.Ed.Engl. ,25, 56–74

    Article  Google Scholar 

  6. Mingos, D.M.P., and Watson, M.J., (1992) Heteronuclear Gold Cluster Compounds, Adv.Inorg.Chem. ,39, 327–399.

    Article  CAS  Google Scholar 

  7. Canè, M., Iapalucci, M.C., Longoni, G., Demartin, F., and Grossi, L. (1991) Materials: Chemistry and Physics 29, 395404.

    Article  Google Scholar 

  8. Albano, V.G., Canè, M., Iapalucci, M.C., Longoni, G., and Monari, M. (1991) J.OrganometChem. 407, C9–C12.

    Article  CAS  Google Scholar 

  9. Albano, V.G., Azzaroni, F., Iapalucci, M.C., Longoni, G., Monari, M., and Mulley, S. (1992) Materials Research Society Symposium Proceedings 272, 115– 125.

    Article  CAS  Google Scholar 

  10. Albano, V.G., Grossi, L., Longoni, G., Monari, M., Mulley, S., and Sironi, A. (1992) J. Amer.Chem.Soc. 114, 5708–5713.

    Article  CAS  Google Scholar 

  11. Albano, V.G., Azzaroni, F., Iapalucci, M.C., Longoni, G., Monari, M., Mulley, S., Proserpio, D.M., and Sironi, A. (1994) Inorg.Chem. in press.

    Google Scholar 

  12. Albano, V.G., Calderoni, F., Iapalucci, M.C., Longoni, G., Monari, M., and Zanello, P. (1994) to be submitted.

    Google Scholar 

  13. Albano, V.G., Aureli, R., Iapalucci, M.C., Laschi, F., Longoni, G., and Zanello, P. (1993) J. Chem.Soc, Chem.Comm. ,1501–1502.

    Google Scholar 

  14. Albano, V.G., Calderoni, F., Iapalucci, M.C., Longoni, G., Monari, M., to be submitted.

    Google Scholar 

  15. Sosinsky, B.A., Shong, R.G., Fitzgerald, B.J., Noren, N., and O’Rourke, C. (1983) Inorg.Chem. 22, 3124–3129.

    Article  CAS  Google Scholar 

  16. Alvarez, S., Ferrer, M., Reina, R., Rossel, O., Seco, M., and Solans, X. (1989) J. Organomet.Chem. 377, 291–303.

    Article  CAS  Google Scholar 

  17. Cassidy, J.M. and Whitmire, K.H. (1989) Inorg. Chem. 28, 2494–2496.

    Article  CAS  Google Scholar 

  18. Cassidy, J.M., Whitmire, K.H., and Kook, A.M. (1993) J. Organomet.Chem. 456, 61–70.

    Article  CAS  Google Scholar 

  19. Luo, S. and Whitmire, K.H. (1989) Inorg.Chem. 28, 1424–1431.

    Article  CAS  Google Scholar 

  20. Churchill, M.R., Fettinger, J.C. ,Whitmire, K.H., and Lagrone C.B. (1986) J. Organomet.Chem. 303, 99–109.

    Article  CAS  Google Scholar 

  21. Ferrer, M., Rossel, O., Seco, M., Solans, X., and Gòmez, M. (1990) J.Organomet.Chem. 381, 183–189.

    Article  CAS  Google Scholar 

  22. Shieh, M., Liou, Y., Peng, S.-M., and Lee, G.-H. (1993) Inorg.Chem. 32, 2212– 2214.

    Article  CAS  Google Scholar 

  23. Bachman, R.E., Miller, S.K., and Whitmire, K.H. (1994) Inorg.Chem. 33 2075–2076.

    Article  CAS  Google Scholar 

  24. Albano, V.G., Ciani, G., Bruce, M.I., Shaw, G., and Stone, F.G.A., (1972) J.Organomet.Chem. ,42, C99–C101.

    Article  CAS  Google Scholar 

  25. Albano, V.G., Monari, M., Iapalucci, M.C., and Longoni, G. (1993) Inorg.Chim. Acta 213, 183–190.

    Article  CAS  Google Scholar 

  26. Briant, C.E., Hall, K.P., and Mingos, D.M.P. (1983) J.Chem.Soc.,Chem.Comm. ,843–845.

    Google Scholar 

  27. Calderoni, F., Demartin, F., Iapalucci, M.C., Longoni, G., and Soverini, M., to be submitted.

    Google Scholar 

  28. Longoni, G., Manassero, M., and Sansoni, M. (1980) J. Amer.Chem.Soc. 102, 7973–7974.

    Article  CAS  Google Scholar 

  29. Della Pergola, R., Garlaschelli, L., Mealli, C., Proserpio, D.M., and Zanello, P. (1990) J. Cluster Science 1, 93–106.

    Article  Google Scholar 

  30. Adams, R. D., Chen, G., and Wang, J.-G. (1989) Polyhedron 8, 2521–2530.

    Article  CAS  Google Scholar 

  31. Doyle, G., Eriksen, K.A., and Van Engen, D. (1986) J. Amer.Chem.Soc. 108,445– 451.

    Article  CAS  Google Scholar 

  32. Ernst, R.D., Marks, T.J., and Ibers, J.A. (1977) J. Amer.Chem.Soc. 99, 2090– 2098.

    Article  CAS  Google Scholar 

  33. Doyle, G., Eriksen, K.A., and Van Engen, D. (1985) J. Amer.Chem.Soc. 107, 7914–7920.

    Article  CAS  Google Scholar 

  34. Briant, C.E., Smith, R.G., and Mingos, D.M.P. (1984) J.Chem.Soc.,Chem. Comm. ,586–588.

    Google Scholar 

  35. Longoni, G., Manassero, M., and Sansoni, M. (1980) J. Amer.Chem.Soc. 102, 3242–3244.

    Article  CAS  Google Scholar 

  36. Fuchs, R., and Klüfers, P., (1991) Z.Naturforsch. ,46b, 507–518

    Google Scholar 

  37. Usòn, R., Laguna, A., Laguna, M., Jones, P.G., and Sheldrick, G. (1981) J. Chem.Soc. Dalton Trans., 366–370.

    Google Scholar 

  38. Albright, T.A., Burdett, J.K., and Whangbo, M-H. (1985) Orbital Interactions in Chemistry ,J.Wiley and Sons, New York.

    Google Scholar 

  39. Hoffmann, R. (1982) Angew.Chem.Int.Ed.Engi ,21, 711–726

    Article  Google Scholar 

  40. Klüfers, P. (1984) Angew.Chem.Int.Ed.Engl. ,23, 307–308

    Article  Google Scholar 

  41. Klüfers, P. (1985) Angew.Chem.Int.Ed.Engl. 24, 70–71.

    Article  Google Scholar 

  42. Merz, K.M., and Hoffmann, R. (1988) Inorg.Chem. ,27, 2120–2127

    Article  CAS  Google Scholar 

  43. Buhl, M.L., Long, G., and Doyle, G. (1993) J.Organomet.Chem. ,461, 187–199

    Article  CAS  Google Scholar 

  44. Pitzer, K.S. (1979) Ace.Chem,Res. ,12, 271–276

    Article  CAS  Google Scholar 

  45. Pyykko, P. and Desclaux, J-P. (1979) Acc.Chem.Res. ,12, 276–281

    Article  CAS  Google Scholar 

  46. Lindley, P.F. and Woodward, P. (1967) J.Chem,Soc. A ,382–392.

    Google Scholar 

  47. Whitmire, K.H., Lagrone, C.B., Churchill, M.R., Fettinger, J.C., and Robinson, B.H. (1987) Inorg.Chem. 26, 3491–3499.

    Article  CAS  Google Scholar 

  48. Di Cori, C. (1992) Thesis, University of Bologna

    Google Scholar 

  49. Rossell, O., Seco, M., and Jones, P. (1990) Inorg.Chem. ,29, 348–350

    Article  CAS  Google Scholar 

  50. Huang, S-P., and Kanatzidis, M.G. (1992) Angew.Chem.Int.Ed.Engl ,31,787–789

    Article  Google Scholar 

  51. Basolo, F. and Pearson, R.G. (1967) Mechanisms of Inorganic Reactions ,J.Wiley and Sons, New York

    Google Scholar 

  52. Chini, P., Longoni, G., and Albano, V.G. (1976) Adv. Organomet. Chem. ,14, 285– 344

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Chimica Fisica ed Inorganica, University of Bologna, Viale del Risorgimento 4, 40136, Bologna, Italy

    Francesca Calderoni, Maria Carmela Iapalucci, Giuliano Longoni & Umberto Testoni

Authors
  1. Francesca Calderoni
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Maria Carmela Iapalucci
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Giuliano Longoni
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Umberto Testoni
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry, University of Glasgow, Glasgow, Scotland

    Louis J. Farrugia

Rights and permissions

Reprints and permissions

Copyright information

© 1995 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Calderoni, F., Iapalucci, M.C., Longoni, G., Testoni, U. (1995). Silver and Gold Clusters Stabilized by Fe(CO)4 Ligands. In: Farrugia, L.J. (eds) The Synergy Between Dynamics and Reactivity at Clusters and Surfaces. NATO ASI Series, vol 465. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0133-2_22

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-0133-2_22

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4060-0

  • Online ISBN: 978-94-011-0133-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation