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Can we Put the Cluster-Surface Analogy on a Sound Structural Basis?

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The Synergy Between Dynamics and Reactivity at Clusters and Surfaces

Part of the book series: NATO ASI Series ((ASIC,volume 465))

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Abstract

A thorough examination of the analogy between the adsorption complexes formed by molecules and molecular fragments adsorbed on metal surfaces and the corresponding co-ordination compounds has hitherto not been possible because of a lack of accurate structural information on surface systems. X-ray diffraction, which gives bondlengths and bond angles to very high accuracy in inorganic and organometallic systems, is not readily applicable to problems of molecular chemisorption. Nevertheless, some progress is now being made using techniques based on electron scattering phenomena. The few data so far available indicate that there are strong similarities between the two situations, at least as far as ligand structure and metal-ligand bondlengths are concerned.

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References

  1. Muetterties, E. L. (1975) Bull. Soc. Chim. Belg. 84, 959

    Article  CAS  Google Scholar 

  2. Muetterties, E. L. (1976) Bull. Soc. Chem. Belg. 85, 451

    Article  CAS  Google Scholar 

  3. Muetterties, E. L. and Wexler, R. M. (1983) Surv. Prog. Chem. 10, 61.

    Google Scholar 

  4. Eischens, R. P. and Pliskin, W. A. (1958) Adv. Catalysis 10, 1.

    Article  CAS  Google Scholar 

  5. Blyholder, G. (1964) J. Phys. Chem. 68, 2772.

    Article  CAS  Google Scholar 

  6. E.g. Thomas, G. E. and Weinberg, W. H. (1978) Phys. Rev. Lett. 41, 1181.

    Article  CAS  Google Scholar 

  7. Bond, G. C. (1966) Disc. Far. Soc. 41, 200.

    Article  Google Scholar 

  8. Morrow, B. A. and Sheppard, N. (1969) Proc. Roy. Soc. A 311, 391.

    Google Scholar 

  9. Ibach, H. and Mills, D. L. (1982) Electron Energy Loss Spectroscopy and Surface Vibrations ,Academic Press, New York.

    Google Scholar 

  10. Albert, M. R. and Yates, J. T. Jr. (1987) The Surface Scientist’s Guide to Organometallic Chemistry ,American Chemical Society, Washington DC.

    Google Scholar 

  11. Kordesch, M. E., Stenzel, W. and Conrad, H. (1986) J. Electron Spectrosc. Relat. Phenom. 39, 89

    Article  CAS  Google Scholar 

  12. Kordesch, M. E., Stenzel, W. and Conrad, H. (1986) Surface Sci. 175, L687.

    Article  CAS  Google Scholar 

  13. Somers, J., Kordesch, M. E., Lindner, Th., Conrad, H., Bradshaw, A. M. and Williams, G. P. (1987) Surface Sci. 188, 693

    Article  Google Scholar 

  14. Kordesch, M. E., Lindner, Th., Somers, J., Stenzel, W., Conrad, H., Bradshaw, A. M., Williams, G. P. (1987) Spectrochimica Acta 43A, 1561.

    CAS  Google Scholar 

  15. Aminpirooz, S., Schmalz, A. and Haase, J. (1992) Phys. Rev. B 45, 6337

    Article  CAS  Google Scholar 

  16. Schindler, K.-M., Hofmann, Ph., Weiß, K.-U., Dippel, R., Gardner, P., Fritzsche, V., Bradshaw, A. M., Woodruff, D. P., Davila, M. E., Asensio, M. C, Conesa, J. C. and González-Elipe, A. R. (1993) J. Electron Spectrosc. Relat. Phenom. 65/65, 75.

    Article  Google Scholar 

  17. Wander, A., Hu, P. and King, D. A. (1993) Chem. Phys. Lett. 201, 393. A more recent photoelectron diffraction study (A. Locatelli et al (1994), Phys. Rev. Lett. 73, 90) suggests, however, that for the system Pd(110) (2xl)-CO bridge sites are occupied after all.

    Article  CAS  Google Scholar 

  18. Woodruff, D. P. and Delchar, T. A. (1994) Modern Techniques of Surface Science ,2nd edition, CUP, Cambridge.

    Book  Google Scholar 

  19. Liang, S. and Trenary, M. (1988) J. Chem. Phys. 89, 3320.

    Article  Google Scholar 

  20. Bradshaw, A. M. (1990) in V. Bortolani, N. March and M. Tosi (eds), Interaction of Atoms and Molecules with Solid Surfaces ,Plenum London, p. 477.

    Google Scholar 

  21. Ricken, D. E., Somers, J., Robinson, A. and Bradshaw, A. M. (1990) Far. Disc. Chem. Soc. 89, 291.

    Article  CAS  Google Scholar 

  22. Stöhr, J. (1992) NEXAFS Spectroscopy ,Springer-Verlag, Berlin.

    Google Scholar 

  23. Aminpirooz, S., Becker, L., Hillert, B. and Haase, J. (1991) Surface Sci. 244, L152.

    Article  CAS  Google Scholar 

  24. Somers, J., Robinson, A. W., Lindner, Th., Ricken, D. and Bradshaw, A. M. (1989) Phys. Rev. B 40, 2053.

    Article  CAS  Google Scholar 

  25. Ramsier, R. D. and Yates, J. T, Jr. (1991) Surface Sci. Rep. 12, 243

    Article  CAS  Google Scholar 

  26. Madey, T. E. (1987) Vacuum 37, 31.

    Article  CAS  Google Scholar 

  27. Alvey, M. D. and Yates, J. T. (1988) J. Am. Chem. Soc. 110, 1782.

    Article  CAS  Google Scholar 

  28. Weiss, P. S. and Eigler, D. M. (1993) Phys. Rev. Lett. 71, 3139.

    Article  CAS  Google Scholar 

  29. Feidenhans’l, L. L. (1989) Surface Sci. Rep. 10, 105.

    Article  Google Scholar 

  30. Woodruff, D. P., Seymour, D. L., McConville, C. F., Riley, C. E., Crapper, M. D., Prince, N. P. and Jones, R. G. (1987) Phys. Rev. Lett. 58, 1460.

    Article  CAS  Google Scholar 

  31. Heinz, K., Starke, U. and Bothe, F. (1991) Surface Sci. 243, L70.

    Article  CAS  Google Scholar 

  32. Woodruff, D. P. and Bradshaw, A. M. (1994) Rep. Progr. Phys. ,in press.

    Google Scholar 

  33. Weiss, K.-U., Dippel, R., Schindler, K.-M., Gardner, P., Fritzsche, V., Bradshaw, A. M., Kilcoyne, A. L. D. and Woodruff, D. P. (1992) Phys. Rev. Lett. 69, 3196.

    Article  CAS  Google Scholar 

  34. Haase, J. and Bradshaw, A. M. (1992) in R. Z. Bachrach (ed), Synchrotrotron Radiation Research: Advances in Surface and Interface Science ,Plenum, New York, p. 55.

    Chapter  Google Scholar 

  35. Pangher, N., Schmalz, A. and Haase, J. (1994) Chem. Phys. Lett. 221, 189.

    Article  CAS  Google Scholar 

  36. Surnev, L., Xu, Z. and Yates, J. T. (1988) Surface Sci. 202, 1, 14.

    Article  Google Scholar 

  37. Chen, J. G., Erley, W. and Ibach, H. (1989) Surface Sci. 223, L891. 29.

    Google Scholar 

  38. Sheppard, N. and Nguyen, N. T. (1978) Adv. IR Raman Spect. 5, 67.

    CAS  Google Scholar 

  39. Bradshaw, A. M. and Hoffmann, F. (1978) Surface Sci. 72, 513.

    Article  CAS  Google Scholar 

  40. E.g. Bradshaw, A. M. and Schweizer, E. (1988) Adv. Spect. 23, 413.

    Google Scholar 

  41. Gmelin Handbuch der Anorganischen Chemie, Bd. 17 Nickel-Organische Verbindungen, Teil 2 (1974) Springer-Verlag, Berlin, S. 381.

    Google Scholar 

  42. De la Cruz, C. and Sheppard, N. (1990) J. Molec. Structure 224, 141.

    Article  Google Scholar 

  43. Corey, E. R., Dahl, L. F. and Beck, W. (1963) J. Am. Chem. Soc. 85, 1202.

    Article  CAS  Google Scholar 

  44. Farrugia, L. J., Jeffery, J. C., Marsden, C. and Stone, F. G. A. (1985) J. Chem. Soc., Dalton Trans. ,645.

    Google Scholar 

  45. Alvey, M. D., Yates, J. T. Jr. and Uram, K. J. (1987) J. Chem. Phys. 87, 7221.

    Article  CAS  Google Scholar 

  46. Dippel, R., Weiss, K.-U., Schindler, K.-M., Gardner, P., Fritzsche, V., Bradshaw, A. M, Asensio, M. C, Hu, X. M, Woodruff, D. P. and González-Elipe (1992) Chem. Phys. Lett. 199, 625.

    Article  CAS  Google Scholar 

  47. Kerkar, M., Woodruff, D. P., Avila, J., Asensio, M. C, Fernández-Garcia, M. and Conesa, J. C. (1992) J. Phys. Cond. Matter 4, 6509.

    Article  CAS  Google Scholar 

  48. Almenningen, A., Andersen, B. A. and Astrup, E. E. (1970) Acta Chem. Scand. 24, 1579.

    Article  CAS  Google Scholar 

  49. Nitschké, F., Ertl, G. and Küppers, J. (1981) J. Chem. Phys. 74, 5911.

    Article  Google Scholar 

  50. Hayden, B. E., Prince, K. C, Woodruff, D. P. and Bradshaw, A. M. (1983) Surface Sci. 133, 589.

    Article  CAS  Google Scholar 

  51. Sexton, B. A. (1979) Chem. Phys. Lett. 65, 469

    Article  CAS  Google Scholar 

  52. Sexton, B. A. (1979) Surface Sci. 88, 319.

    Article  CAS  Google Scholar 

  53. Woodruff, D. P., McConville, C. F., Kilcoyne, A. L. D., Lindner, Th., Somers, J., Surman, M., Paolucci, G. and Bradshaw, A. M. (1988) Surface Sci. 201, 228.

    Article  CAS  Google Scholar 

  54. Weiss, K.-U., Dippel, R., Schindler, K.-M., Gardner, P., Fritzsche, V., Bradshaw, A. M., Woodruff, D. P., Asensio, M. C. and González-Elipe, A. R. (1993) Phys. Rev. Lett. 71, 581.

    Article  CAS  Google Scholar 

  55. Goodgame, D. M. L., Hill, N. J., Marsham, D. F., Skapski, A. C, Smart, M. L. and Troughton, P. G. H. (1969) J. Chem. Soc. Chem. Comm. 629.

    Google Scholar 

  56. Sheppard, N. (1988) Ann. Rev. Phys. Chem. 39, 589.

    Article  CAS  Google Scholar 

  57. Motyl, K. M., Norton, J. R., Schauer, C. K. and Anderson, O. P. (1982) J. Am. Chem. Soc. 104, 7325.

    Article  CAS  Google Scholar 

  58. Anson, C. E., Johnson, B. F. G., Lewis, J., Powell, D. B., Sheppard, N., Bhattacharyya, A. K., Bender, B. R., Bullock, R. M., Hembre, R. T. and Norton, J. R. (1989) J. Chem. Soc., Chem. Commun. 703.

    Google Scholar 

  59. Anderson, O. P., Bender, B. R., Norton, J. R., Larson, A. C. and Vergamini, P. J. (1991) Organometallics 10, 3145.

    Article  CAS  Google Scholar 

  60. Love, R., Koetzle, T. F., Williams, G. J. B., Andrews, L. C. and Bau, R. (1975) Inorg. Chem. 14, 2653.

    Article  CAS  Google Scholar 

  61. Anson, C. E., Sheppard, N., Powell, D. B., Bender, B. R. and Norton, J. R. (1994) J. Chem. Soc. Faraday Trans. 90, 1449.

    Article  CAS  Google Scholar 

  62. Bao, S., Hofmann, Ph., Schindler, K.-M., Fritzsche, V., Bradshaw, A. M., Woodruff, D. P., Casado, C. and Asensio, M. C. (1994) J. Phys.: Cond. Matter 6, L93.

    Article  CAS  Google Scholar 

  63. Schaff, O., Hofmann, Ph., Schindler, K.-M., Bradshaw, A. M., Davis, R. and Woodruff, D. P., to be published.

    Google Scholar 

  64. Netzer, F. P., Graen, H. H., Kuhlenbeck, H. and Neumann, M. (1987) Chem. Phys. Lett. 133, 49, and references therein.

    Article  CAS  Google Scholar 

  65. Huber, W., Zebisch, P., Bornemann, T. and Steinrück, H.-P. (1991) Surface Sci. 258, 16.

    Article  CAS  Google Scholar 

  66. Lin, R. F., Blackman, G. S., Van Hove, M. A. and Somorjai, G. A. (1987) Acta Crystallogr. B 43, 368.

    Article  Google Scholar 

  67. Wander, A., Held, G., Hwang, R. Q., Blackman, G. S., Lu, M. L., de Andres, P., Hove, M. A. and Somorjai, G. A. (1991) Surface Sci. 249, 21.

    Article  CAS  Google Scholar 

  68. Wadepohl, H. (1992) Angew. Chem. 104, 253.

    Article  CAS  Google Scholar 

  69. Müller, J., Escarpa Gaede, P. and Qiao, K. (1993) Angew. Chem. 105, 1809.

    Article  Google Scholar 

  70. Blake. A. J., Dyson, P. J., Johnson, B. F. G. and Matin, C. M. (1994) J. Chem. Soc., Chem. Commun. 1471.

    Google Scholar 

  71. Ogletree, D. F., Van Hove, M. A. and Somorjai, G. A. (1987) Surface Sci. 183, 1.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4 - 6, D-14195, Berlin, Germany

    A. M. Bradshaw

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  1. A. M. Bradshaw
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  1. Department of Chemistry, University of Glasgow, Glasgow, Scotland

    Louis J. Farrugia

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Bradshaw, A.M. (1995). Can we Put the Cluster-Surface Analogy on a Sound Structural Basis?. In: Farrugia, L.J. (eds) The Synergy Between Dynamics and Reactivity at Clusters and Surfaces. NATO ASI Series, vol 465. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0133-2_1

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  • DOI: https://doi.org/10.1007/978-94-011-0133-2_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4060-0

  • Online ISBN: 978-94-011-0133-2

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