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Zeolite Guest-Host Interactions: Implications in Formation, Catalysis, and Photochemistry

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Inclusion Chemistry with Zeolites: Nanoscale Materials by Design

Part of the book series: Topics in Inclusion Science ((TISC,volume 6))

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Abstract

Zeolites are crystalline aluminosilicates with the composition Mx/n•(A1O2)x•(SiO2)y•wH2O [1]. The framework is formed by -Si-O-Al(Si)- bonds and about 75 different topologies comprising of cages and channels with varying molecular dimensions are known [2]. The intracrystalline zeolitic space is occupied by H2O molecules which can be removed upon heating. The Mn+ cations, which neutralize the charge carried by the tetrahedral framework aluminum, are readily exchangeable. The close match in size between reactant molecules and the zeolite interior has been extensively exploited in hydrocarbon transformations, leading to many novel processes[3]. Reactions showing selectivity towards specific reactants, formation of specific products, as well as novel control of the transition state and molecular traffic control due to different intrazeolitic diffusivities of reactants and products, have all been observed [4]

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Authors
  1. Prabir K. Dutta
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Editors and Affiliations

  1. Central Research and Development Experimental Station, DuPont Company, Wilmington, DE, USA

    Norman Herron  & David R. Corbin  & 

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Dutta, P.K. (1995). Zeolite Guest-Host Interactions: Implications in Formation, Catalysis, and Photochemistry. In: Herron, N., Corbin, D.R. (eds) Inclusion Chemistry with Zeolites: Nanoscale Materials by Design. Topics in Inclusion Science, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0119-6_8

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  • DOI: https://doi.org/10.1007/978-94-011-0119-6_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4057-0

  • Online ISBN: 978-94-011-0119-6

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