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Part of the book series: Topics in Inclusion Science ((TISC,volume 6))

Abstract

Zeolites and molecular sieves are important industrial materials that have a broad range of applications. Many zeolites with different structures and compositions are commercially available and used in refining and chemical processing as catalysts, absorption materials, and drying agents, as well as in ion-exchange operations [1, 2]. Zeolites and molecular sieves show a strikingly close relationship between their microscopic structure and macroscopic properties. This relationship is particularly clear in their ability to sieve organic and inorganic molecules based on size. Also, the rigorous steric control that zeolite frameworks offer over the chemical reactions occurring inside their pores is directly related to their microscopic structure.

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References

  1. M. E. Davis, Ind. Eng. Chem. Res., 30, 1675 (1991).

    Article  CAS  Google Scholar 

  2. J. M. Newsam, in Solid State Chemistry: Compounds, A. K. Cheetham and P. Day (Eds), Oxford University Press, New York (1992).

    Google Scholar 

  3. W. M. Meier and D. H. Olson, Atlas of Zeolite Structure Types, ButterworthsHeineman, Stoneham, MA (1992).

    Google Scholar 

  4. J. V. Smith, Chem. Rev., 88, 149 (1988).

    Article  CAS  Google Scholar 

  5. J. Higgins, Catal. Today, in press.

    Google Scholar 

  6. L. B. McCusker, C. Baerlocher, E. Jahn, and M. Bulow, Zeolites, 11, 308 (1991)

    Article  CAS  Google Scholar 

  7. M. E. Davis, C. Montes, P. E. Hathaway, and J. P. Arhancet, J. Am. Chem. Soc., 111, 3919 (1989).

    Article  CAS  Google Scholar 

  8. G. V. Gibbs and E. P. Meagher, in Structure and Bonding in Crystals, H. O’Keeffe and A. Navrotsky (Eds), Academic Press, New York, Vol 1, pp 195–223 (1980).

    Google Scholar 

  9. M. D. Newton and G. V. Gibbs, Phys. Chem. Miner., 6, 221 (1980).

    Article  CAS  Google Scholar 

  10. M. E. Davis and R. F. Lobo, Chem. Mater., 4, 756 (1992).

    Article  CAS  Google Scholar 

  11. B. M. Lok, T. R. Cannon, and C. A. Messina, Zeolites, 3, 282 (1983).

    Article  CAS  Google Scholar 

  12. J. C. Jansen, in Introduction to Zeolite Science and Practice, H. van Bekkum, E. M. Flanigen, and J. C. Jansen (Eds), Elsevier, Amsterdam, pp 77–135 (1991).

    Chapter  Google Scholar 

  13. R. Szostak, Handbook of Molecular Sieves, Van Nostrand-Reinhold, New York, (1992).

    Google Scholar 

  14. H. Gies, in Inclusion compounds, Academic Press, London, Vol. 5, pp 1–35 (1991).

    CAS  Google Scholar 

  15. H. Gies and B. Marler, Zeolites, 12, 42 (1992).

    Article  CAS  Google Scholar 

  16. F. Liebau, in Silicon Chemistry, E. R. Corey, J. Y. Corey, and P. P. Gaspar (Eds) Ellis Horwood Limited, England, pp 308–323 (1988).

    Google Scholar 

  17. D. M. Bibby and M. P. Dale, Nature, 317, 157 (1985).

    Article  CAS  Google Scholar 

  18. J. Keisper, C. J. J. den Ouden, and M. F. M. Post, Stud. Surf. Sci. Catal., 49, 237–248 (1989)

    Article  Google Scholar 

  19. C. Y. Chen, personal communication (1994).

    Google Scholar 

  20. J. J. Pluth and J. V. Smith, Stud. Surf. Sci. Catal., 49, 835–844 (1989).

    Article  Google Scholar 

  21. F. Liebau, Structural Chemistry of Silicates, Springer-Verlag, Berlin (1985).

    Book  Google Scholar 

  22. S. B. Hong, H. M. Cho and M. E. Davis, J. Phys. Chem., 97, 1622 (1993).

    Article  CAS  Google Scholar 

  23. S. B. Hong, H. M. Cho and M. E. Davis, J. Phys. Chem., 97, 1629 (1993).

    Article  CAS  Google Scholar 

  24. S. Burkett and M. E. Davis, Microporous Mater., 1, 265 (1993).

    Article  CAS  Google Scholar 

  25. H. Gies, Z. Kristal., 164, 247 (1983).

    Article  CAS  Google Scholar 

  26. H. Gerke and H. Gies, Z. Kristal., 166, 11 (1984).

    CAS  Google Scholar 

  27. G. Miehe, T. Vogt, H. Fuess, and U. Muller, Acta Cryst., Sect. B, 49, 745 (1993).

    Article  Google Scholar 

  28. H. Gies, Z. Kristal., 167, 73 (1984).

    Article  CAS  Google Scholar 

  29. H. Gies, Z. Kristal., 175, 93 (1986).

    Article  CAS  Google Scholar 

  30. L. B. McCusker, Acta. Cryst., Sect. A, 47, 297 (1991).

    Article  Google Scholar 

  31. L. B. McCusker, J. AppL Crystallography, 21, 305 (1988).

    Article  CAS  Google Scholar 

  32. R. F. Lobo and M. E. Davis, Microporous Mater., accepted.

    Google Scholar 

  33. R. M. Dessau, K. D. Smith, G. T. Kerr, G. L. Woolery and L. B. Alemany, J. Catal., 104, 484 (1987).

    Article  CAS  Google Scholar 

  34. C. A. Fyfe, H. Gies, G. T. Kokotailo, B. Marler, and D. E. Cox, J. Phys. Chem., 94, 3718 (1990).

    Article  CAS  Google Scholar 

  35. C. A. Fyfe, H. Gies, G. T. Kokotailo, C. Pasztor, H. Strobl, and D. E. Cox, J. Am. Chem. Soc., 111, 2470 (1990).

    Article  Google Scholar 

  36. F. Liebau, Structural Chemistry of Silicates, Springer-Verlag, Berlin, p 242 (1985).

    Book  Google Scholar 

  37. Y. Nakagawa and S. I. Zones, in Synthesis of Microporous Materials, M. L. Occelli and H. Robson (Eds), Vol 1, Van Nostrand Reinhold, New York, pp 222–239 (1992)

    Google Scholar 

  38. C. D. Chang and A. T. Bell, Catal. Lett., 8, 305 (1991).

    Article  CAS  Google Scholar 

  39. R. M. Barrer, Hydrothermal Synthesis of Zeolites, Academic Press, London, p 359 (1982).

    Google Scholar 

  40. I. Petrovic, A. Natvrotsky, S. I. Zones, and M. E. Davis, Chem. Mater., 5, 1805 (1993).

    Article  CAS  Google Scholar 

  41. N. J. Henson, A. K. Cheetham, and J. D. Gale, Chem. Mater., submitted (1994).

    Google Scholar 

  42. X. Hu and W. Depmeier, Z. Kristal., 201, 99 (1992).

    Article  CAS  Google Scholar 

  43. A. Shimizu and Y. Taniguchi, Bull. Chem. Soc. Jpn., 63, 1572 (1990).

    Article  CAS  Google Scholar 

  44. A. Shimizu and Y. Taniguchi, Bull. Chem. Soc. Jpn., 63, 3295 (1990).

    Google Scholar 

  45. D. T. Griffen, Silicate Crystal Chemistry, Oxford University Press, Oxford, p 15 (1992).

    Google Scholar 

  46. C. B. Khouw, H. X. Li, C. B. Dartt, and M. E. Davis, ACS Symp. Ser., 523, 293 (1993).

    Google Scholar 

  47. M. Goepper, H. X. Li, and M. E. Davis, J. Chem. Soc., Chem. Commun., 1665 (1992).

    Google Scholar 

  48. P. Brady and J. V. Walther, Chem. Geol., 8, 253 (1990).

    Article  Google Scholar 

  49. P. M. Dove and D. A. Crerar, Geochim. Cosmochim. Acta, 54, 955 (1990).

    Article  CAS  Google Scholar 

  50. S. I. Zones, Microporous Mater., in press.

    Google Scholar 

  51. S. I. Zones and Y. Nakagawa, Microporous Mater., in press (1994).

    Google Scholar 

  52. S. I. Zones Y. Nakagawa, G. Yuen and T. Harris, J. Am. Chem. Soc., submitted.

    Google Scholar 

  53. T. V. Harris and S. I. Zones, in Proceedings of the 10th International Zeolites Conference., Garmisch-Partenkirchen, Germany, Elsevier, Amsterdam, Vol A, pp 29–36 (1994).

    Google Scholar 

  54. R. M. Kerchner and N. K. McGuire, in Extended Abstracts and Program, 9th International Zeolite Conference, J. B. Higgins, R. von Ballmoos and M. M. J. Treacy (Eds), Butterworth-Heinemann, Stoneham, MA (1992).

    Google Scholar 

  55. S. I. Zones, L. T. Yuen, Y. Nakagawa, R. A. Van Nordstrand and S. D. Toto, in Proceedings of the 9th International Zeolites Conference, R. von Ballmoos, J. B. Higgins and M. M. Treacy (Eds) Butterworth-Heinemann, Stoneham, MA, Vol.1, pp 163–170 (1993).

    Google Scholar 

  56. R. Kumar, K. Ramesh Reddy, A. Raj and P. Ratnasamy, in Proceedings of the 9th International Zeolites Conference, R. von Ballmoos, J. B. Higgins and M. M. Treacy (Eds), Butterworth-Heinemann, Stoneham, MA, Vol.1, pp 189–196 (1993).

    Google Scholar 

  57. R. F. Lobo, M. Pan, I. Chan, H. X. Li, R. C. Medrud, S. I. Zones, P. A. Crozier, and M. E. Davis, Science, 262, 1543 (1993).

    Article  CAS  Google Scholar 

  58. R. F. Lobo, S. I. Zones, and M. E. Davis, in Proceedings of the 10th International Zeolites Conference., Garmisch-Partenkirchen, Germany, Elsevier, Amsterdam, Vol A, pp 461–468 (1994).

    Google Scholar 

  59. Y. Nakagawa, U.S. Patent 5,254,514 (1993).

    Google Scholar 

  60. Y. Nakagawa, in Proceedings of the 10th International Zeolites Conference., Garmisch-Partenkirchen, Germany, Elsevier, Amsterdam, Vol A, pp 323–330 (1994).

    Google Scholar 

  61. M. J. Annen, Ph.D. Thesis, Virgina Polytechnic Institute, Blacksburg, VA (1992).

    Google Scholar 

  62. M. J. Annen and M.E. Davis, Microporous Mater., 1, 57 (1993)

    Article  CAS  Google Scholar 

  63. M. A. Camblor, S. I. Zones and M. E. Davis, in preparation.

    Google Scholar 

  64. J. M. Newsam, M. M. J. Treacy, W. T. Koetsier and C. B. de Gruyter, Proc. R. Soc. Lond., Ser. A, 420375 (1988).

    Article  CAS  Google Scholar 

  65. S. I. Zones, M. M. Olmstead, and D. S. Santilli, J. Am. Chem. Soc., 114, 4195 (1992).

    Article  CAS  Google Scholar 

  66. S. I. Zones and D. S. Santilli, in Proceedings of the 9th International Zeolites Conference, R. von Ballmoos, J. B. Higgins, and M. M. Treacy (Eds), Butterworth-Heinemann, Stoneham, MA, Vol.1, pp 171–179 (1993).

    Google Scholar 

  67. R. F. Lobo, M. Pan, I. Chan, S. I. Zones, P. A. Crozier and M. E. Davis, J. Phys. Chem., in press.

    Google Scholar 

  68. S. L. Lawton, and W. J. Rohrbaugh, Science, 247, 1319 (1990).

    Article  CAS  Google Scholar 

  69. L. B. McCusker, Microporous Mater., in press.

    Google Scholar 

  70. J. P. Arhancet and M. E. Davis, Chem. Mater., 3, 567 (1991).

    Article  CAS  Google Scholar 

  71. Y. Nakagawa, U.S. Patent 5,271,921 (1993).

    Google Scholar 

  72. J. C. van der Waal, M. S. Rigutto, and H. van Bekkum, J. Chem. Soc., Chem. Commun., 1241 (1994).

    Google Scholar 

  73. K. D. Schmith and G. J. Kennedy, Zeolites, in press.

    Google Scholar 

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Lobo, R.F., Zones, S.I., Davis, M.E. (1995). Structure-Direction in Zeolite Synthesis. In: Herron, N., Corbin, D.R. (eds) Inclusion Chemistry with Zeolites: Nanoscale Materials by Design. Topics in Inclusion Science, vol 6. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0119-6_2

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  • DOI: https://doi.org/10.1007/978-94-011-0119-6_2

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