Abstract
This chapter provides an introduction to and overview of the important scientific and practical aspects of hydrogen interactions with metals. In particular, it concentrates on the controlled absorption and desorption of hydrogen into and out of metals, especially the area of rechargeable metal hydrides. The subject of the hydrogen degradation of structural materials is also briefly discussed.
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References
G. Sandrock: “Applications of Hydrides”, this volume
T. Graham: Phil. Trans. Royal Soc., 156 (1866) 415
T. Graham: Proc. Royal Soc., 16 (1868) 422
D.P. Smith: Hydrogen in Metals, U. of Chicago Press, Chicago, 1948
L Schlapbach: “Introduction”, in Ref.27, Vol.I, p.1
G. Taubes: Bad Science: The Short Life and Wierd Times of Cold Fusion, Random House, New York, 1993
J.J.G. Willems: Philips J. Research, 39 (Sup.1) (1984)
F.A. Lewis: Platinum Metals Review, 12 (1968)
F.A. Lewis: Platinum Metals Review, 14 (1970)
A.S. Darling: Platinum Metals Review, 15 (1971)
G. Alefeld, H. Browdowsky, J. Völkl, E. Wicke: Hydrogen in Metals, Rep. Jül Conf-6, KFA Jülich, 1972 (2 Volumes); see also Ber. Bunsengesellschaft Phys. Chem., 76 (No.8)(1972)
I.R. Harris, J.P.G. Farr, Eds.: J. Less-Common Met., 49 (1976)
E. Wicke, H. Züchner, Eds.: Z. Phys. Chem. NF, 111–116 (1979)
B. Baranowski, Ed.: J. Less-Common Met., 101 (1984)
F. Lewis, E. Wicke, Eds.: Z. Phys. Chem., 143, 145–147 (1985–86)
A.F. Andresen, A.J. Maeland, Eds.: Hydrides for Energy Storage, Pergamon, Oxford, 1978
G.G. Libowitz, G.D. Sandrock, Eds.: J. Less-Common Met., 73 & 74 (1980)
W.E. Wallace, T. Schober, S. Suda, Eds.: J. Less-Common Met., 88 (1982) & 89 (1983)
ML Ron, Y. Josephy, I. Jacob, D. Shaltiel, Eds.: J. Less-Common Met., 103 & 104 (1984)
A. Percheron-Guegan, M. Gupta, Eds.: J. Less-Common Met., 129–131 (1987)
R. Kirchheim, E. Fromm, E. Wicke, Eds.: Z. Phy. Chem. NF, 163 & 164 (1989)
F.D. Manchester, Ed.: J. Less-Common Met., 172–174 (1991)
D. Noréus, S. Rundqvist, E. Wicke, Eds.: Z. Phy. Chem., 179, 181, 183 (1983)
Proc. Miami International Symposium on Metal-Hydrogen Systems, Pergamon, Oxford, 1982
Proc. 2nd International Congress on Hydrogen in Metals, Pergamon, Oxford, 1978
G. Alefeld, J. Vötkl, eds.: Hydrogen in Matals I & II, Topics in Appl. Phys., 28 -29 (1978)
L. Schiapbach, Ed.: Hydrogen in Intermetallic Compounds I & II, Topics in Appl. Phys., 63 & 67 (1988 & 1992)
G.G. Libowitz: The Solid State Chemistry of Binary Metal Hydrides, W.A. Benjamin, New York, 1965
H. Buchner: Energiespeicherung in Metallhydriden, Springer, Vienna, 1982
W.M. Mueller, J.P. Blackledge, G.G. Libowitz, Eds.: Metal Hydrides, Academic, New York, 1968
D.T. Hurd: An Introduction to the Chemistry of the Hydrides, John Wiley, New York, 1952
K.M. Mackay: Hydrogen Compounds of the Metallic Elements, E & F.N. Spon, London, 1966
B.L. Shaw: Inorganic Hydrides, Pergamon, Oxford, 1967
Y. Fukai: The Metal-Hydrogen System, Springer, Berlin, 1993
G. Bambakidis, Ed.: Metal Hydrides, NATO ASI Series B: Physics, Vol. 76, Plenum, New York, 1981
P. Jena, C.B. Satterthwaite, Eds.: Electronic Structure and Properties of Hydrogen in Metals, NATO Conf. Series VI, Plenum, New York, 1983
G. Bambakidis, R.C. Bowman: Hydrogen in Disordered and Amorphous Solids, NATO ASI Series B: Physics, Vol. 126, Plenum, New York, 1986
R. Gibala, R.F. Hehemann, Eds.: Hydrogen Embrittlement and Stress Corrosion Cracking, ASM International, Materials Park, OH, 1984
A.W. Thompson, I.M. Bernstein, Eds.: Effect of Hydrogen on Behavior of Materials (1976) and Hydrogen Effects in Metals (1981)
N.R. Moody, A.W. Thompson, Eds.: Hydrogen Effects on Material Behavior (1990), The Minerals, Metals and Materials Society, Warrendale, PA
R.A. Oriani, J.P. Hirth, M Smialowski, Eds.: Hydrogen Degradation in Ferrous Alloys, Noyes Publications, Park ridge, NJ, 1985
H. Bruning, A. Sieverts: Z. Phys. Chem., 163A (1933) 409
F.A. Lewis: The Palladium Hydrogen System, Academic, New York, 1967
E. Wicke, H. Brodowsky: “Hydrogen in Palladium and Palladium Alloys”, in Ref.26, Vol.2, p.73
R. Speiser. “The Thermodynamics of Metal-Hydrogen Systems” and “Statistical Mechanics of Metal-Hydrogen Systems”, in Ref.30, p.51
T.B. Flanagan, W.A. Oates: “Thermodynamics of Intermetallic Compound-Hydrogen Systems”, in Ref.27, Vol.I, p.49
D.M. Gruen, M. Mendelsohn: J. Less-Common Met., 55 (1977) 149
E.A. Sullivan, R.C. Wade: “Hydrides”, Kirk-Othmer Encyclopedia of Chemical Technology, V.12, John Wiley, New york, 1980, p.772
R. Griessen, T. Riesterer: “Heat of Formation Models”, in Ref.27, p.219
C.S. Barrett, T.B. Massalski: Structure of Metals, 3rd Ed., Pergamon, Oxford, 1980
A.C. Switendick: Z. Phys. Chem., 117 (1979) 89; “The Change in Electronic Properties on Hydrogen Alloying and Hydride Formation”, in Ref.26, Vol.I, p.101
K.C. Hoffman, J.J. Reilly, F.J. Salzano, C.H. Waide, R.N. Wiswall, W.E. Winsche: Int. J. Hydrogen Energy, 1 (1976) 133
J.J. Reilly, R.H. Wiswall, Jr.: “The Effect of Minor Constituents on the Properties of Vanadium and Niobium Hydrides”, Rept. BNL-16546, Brookhaven National Lab, Upton, NY 11973, 1972
W.M. Mueller: “Titanium Hydrides”, in Ref.30, p. 336
B. Baranowski: “Metal Hydrogen Systems at High Hydrogen Pressures”, in Ref. 26, Vol.II, p.157
G.G. Libowitz, A.J. Maeland: Matl. Sci. Forum, 31 (1988) 177
A.F. Maeland G.G. Libowitz, G. Rak: U.S. Pat. 4,440,736, Apr.3, 1984
J.H. Westbrook, Ed.: Intermetallic Compounds, Jojhn Wiley, New York, 1967
G.G. Libowitz, H.F. Hayes, T.R.P. Gibb: J. Phys. Chem., 62 (1958) 76
K.H.J. Buschow, P.C.B. Bouten, A.R. Miedema: Rep. Prog. Phys, 45 (1982) 937
J.H.N. van Vucht, F.A. Kuijpers, H.C.A.M. Bruning: Plilips Res. Repts., 25 (1970) 133
T.B. Massalski, Ed.: Binary Alloy Phase Diagrams, 2nd Edition, ASM International, Materials Park, OH, 1990
C. Lartigue, A. Percheron-Guegan, J.C. Achard, J.L. Soubeyroux: J. Less-Common Met., 113 (1985) 127
J.F. Lakner, F.S. Uribe, S.A. Steward: J. Less-Common Met., 72 (1980) 87
G.D. Sandrock: “Hydrogen Storage”, in Hydrogen Energy, Rept. 199, Royal Swedish Acad. Eng. Sci., Stockholm, 1981
W.M. Mueller: “The Rare Earth Hydrides”, in Ref. 30, p. 384
H.H. van Mal: “Stability of Ternary Hydrides and Some Applications”, Doctor’s Dissertation, Technische Hogeschool Delft, 1976
P.D. Goodell, G.D. Sandrock, E.L. Huston: “Microstructure and Hydriding Studies AB5 Hydrogen Storage Alloys”, Rept. SAND79-7095, Sandia National Lab., 1980
G.D. Sandrock: “Development of Low Cost Nickel — Rare Earth Hydrides for Hydrogen Storage”, in Proc. 2nd World Hydrogen Energy Conf., V.3 (Pergamon Press, Oxford, 1978), p.1625
Y. Osumi, H. Suzuki, A. Kato, K. Oguro, N. Nakane: J. Less-Common Met., 74 (1980) 271
A. Pebler and E.A. Gulbransen: Trans. Met. Soc. AIME, 239 (1967) 1593
D. Shaltiei, I. Jacob, D. Davidov: J. Less-Common Met., 53 (1977) 117
Y. Gamo, Y. Moriwaki, T. Yamashita, M. Fukuda: U.S. Pat. 4,144,103, Mar. 13, 1979
D.G. Ivey, D.O. Northwood: Z. Phys. Chem., 147 (1986) 191
R.M. van Essen, K.H.J. Buschow: Mat. Res. Bull., 15 (1980) 1149
F. Pourarian, H. Fuji, W.E. Wallace, V.K. Sinha, H.K. Smith: J. Phys. Chem., 85 (1981) 3105
S.R. Ovshinsky, M.A. Fetcenko, J. Ross: Science, 260 (9 April 1993) 176
J.J. Reilly, R.H. Wiswall: Inorg. Chem., 13 (1974) 218
J.J. Reilly, J.R. Johnson: “Titanium Alloy Hydrides and Their Applications”, Proc. First World Hydrogen Energy Conf., V.II, Int. Assoc. Hydrogen Energy, 1976, p.8B–6
G.D. Sandrock, P.D. Goodell: J. Less-Common Met, 104 (1984) 159
H. Buchner, MA. Gutjahr, K.-D. Beccu, H. Säuferer: Z. Metall., 63 (1972) 497
J.J. Reilly, R.H. Wiswall: Inorg. Chem., 7 (1968) 2254
E.L. Huston, G.D. Sandrock: J. Less-Common Met., 74 (1980) 435
G. Sandrock, S. Suda, L. Schlapbach: in Ref.27, V.II, p.197
G.D. Sandrock, P.D. Goodell, E.L. Huston, P.M. Golben: Z. Phy. Chem. NF, 164 (1989) 1285
A. Kadir: “Studies of New Ternary Hydrides with Different d-Electron Content”, Doctoral Dissertation, Stockholm Univ., 1994 (Chem. Commun., 1994, No.2); K. Kadir, D. Noréus: Z. Phys. Chem., 129 (1993) 249
A.F. Maeland, W.D. Lahar: Z. Phys. Chem., 179 (1993) 181
D. Noréus: Z. Phys. Chem., 163 (1989) 575
J.J. Didisheim, P. Zolliker, K. Yvon, P. Fischer, J. Schefer, M. Gubelmann, A.F. Williams: Inorg. Chem., 23 (1984) 1953
P. Zolliker, K. Yvon, J.D. Jorgensen, F. Rotella: Inorg. Chem., 25 (1986) 3590
N.T. Stetson, K. Yvon, P. Fischer: “On the Structure of the Complex Metal Hydride BaReH9”, Inorg. Chem, 1994, in press
D.W. Slocum, W.R. Moser: Catalytic Transition Metal Hydrides, Anals N.Y. Acad. Sciences, 415, New York, 1983
M. Mediati, G.N. Tachibana, C.M. Jensen: Inorg. Chem., 31 (1992) 1827
A.J. Maeland, L.E. Tanner, G.G. Libowitz: J. Less-Common Met., 74 (1980) 279
S.R. Ovshinky, K. Sapru, K. Dec, K. Hong: U.S. Pat. 4,431,561, Feb.14, 1984
K.C. Hong, K. Sapru: Int. J. Hydrogen Energy, 12 (1987) 411
F.H.M. Spit: “The Thermodynamics and Kinetics of Hydrogen Solution in some Metallic Glasses”, Doctoral Dissertation, U. of Utrect, Jan., 1982
D.H. Ryan, F. Dumais, B. Patel, J. Kycia, J.O. Ström-Olsen: J. Less-Common Met., 172–174 (1991) 1246
K. Sapru, K. Hong, M.A. Fetcenko, S. Venkatesan: U.S. Pat. 4,551,400, Nov.5, 1985
M.Y. Song, E. Ivanov, B. Darriet, M. Pezat: J. Less-Common Met., 131 (1987) 71
A. Stepanov, E. Ivanov, I. Konstanchuk, V. Boldyrev: J. Less-Common Met., 131 (1987) 89
A. Kr. Singh, A.K. Singh, O.N. Srivastava: Int. J. Hydrogen Energy, 18 (1993) 567
I.G. Konstanchuk, E.Y. Ivanov, M. Pezat, B. Darriet, V.V. Boldyrev, P. Hagenmuller: J. Less-Common Met., 131 (1987) 189
B. Bogdanovic, B. Spliethoff: Int. J. Hydrogen Energy, 12 (1987) 863
B. Bogdanovic, T.H. Hartwig, B. Spliethoff: Int. J. Hydrogen Energy, 18 (1993) 575
R. Zidan, D.K. Slattery, J. Burns: Int. J. Hydrogen Energy, 16 (1991) 821
H. Imamura, M. Kawahigashi, S. Tsuchiya: J. Less-Common Met., 95 (1983) 157
S. Suda: “Mechanism of Hydrogen Uptake on the F-Treated Surface of the LaNi4.7Al0.3-alloy”, Research Reports of Kogakuin University, 74 (Apr. 1993) 29
F.-J. Liu, G. Sandrock, S. Suda: J. Alloys and Compounds, 190 (1992) 57
F.-J. Liu, G. Sandrock, S. Suda: Z. Phys. Chem., 183 (1994) 163
D.A. Mathis: Hydrogen Technology for Energy, Noyes Data, Park ridge, NJ, 1976
C.D. Beachem, Ed.: Hydrogen Damage, ASM, Metals Park, OH, 1977
A.R. Troiano: Trans. ASM, 52 (1960) (reprinted in [110])
H.K. Birnbaum: “Mechanisms of Hydrogen Related Fracture of Metals”, in Ref.39 (1990), p.639
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Sandrock, G. (1995). Hydrogen-Metal Systems. In: Yürüm, Y. (eds) Hydrogen Energy System. NATO ASI Series, vol 295. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0111-0_10
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