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Polymer Composite Materials — Interface Phenomena & Processes pp 107–135Cite as

Formation of Polymer Composite Materials in the Presence of Solid Acids and Bases

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Part of the book series: Solid Mechanics and Its Applications ((SMIA,volume 90))

Abstract

As noted in the previous chapters, the formation of polymers in the presence of acidic and basic fillers is determined by the adsorption character of the acid-base interaction within the compositions. When a filler — a solid acid or base, is introduced into a ready prepared polymer (basic or acidic, respectively), the polymer structure and properties may vary as a result of the adsorption interaction. These fillers affect the polymer more significantly when they are introduced during the stage of polymer formation, i.e. before the accomplishment of polymerization or polycondensation. Thus, they modify not only polymer structure and properties but also kinetics, thermodynamics and polymerization mechanism. The numerous published data show that solid acids and bases behave as effective catalysts of polymerization and polycondensation.

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Authors and Affiliations

  1. Central Laboratory of Physico-Chemical Mechanics, Bulgarian Academy of Sciences, Sofia, Bulgaria

    Yatchko Ivanov, Valerii Cheshkov & Margarita Natova

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  1. Yatchko Ivanov
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  2. Valerii Cheshkov
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  3. Margarita Natova
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© 2001 Kluwer Academic Publishers

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Ivanov, Y., Cheshkov, V., Natova, M. (2001). Formation of Polymer Composite Materials in the Presence of Solid Acids and Bases. In: Polymer Composite Materials — Interface Phenomena & Processes. Solid Mechanics and Its Applications, vol 90. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-9664-5_4

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  • DOI: https://doi.org/10.1007/978-94-010-9664-5_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0386-8

  • Online ISBN: 978-94-010-9664-5

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