Abstract
The formation of HCN, ammonium cyanide, alkylnitriles, aminoacetonitrile and its C- and N- methyl homologs was demonstrated earlier in a simulated Jovian atmosphere. The polymeric material resulting in these experiments was shown to give glycine, alanine, sarcosine, aspartic acid and some imino dibasic acids on acid hydrolysis suggesting thereby the participation of the monomeric nitriles into the formation of the polymeric product(s). Further examination of products resulting from semi-corona and arc discharge through a mixture of methane and ammonia has provided evidence for the formation of alkylaminopropionitriles as a complex mixture and also some pyridyl and pyrimidyl type heterocyclic compounds. A GC-MS examination of the heterocyclics showed resemblance with those found in some carbonaceous chondrites. The significance of these findings in relation to chemical evolution will be discussed.
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References
Akabori, S.: 1955, Kagaku, Tokyo 25, 54.
Buc, S. R.: 1955, Organic Syntheses, Collective vol. III, J. Wiley and Sons, p. 93.
Chadha, M. S. and Ponnamperuma, C.: 1970, unpublished work.
Chadha, M. S., Flores, J. J., Lawless, J. G., and Ponnamperuma, C.: 1971a, Icarus 15, 39.
Chadha, M. S., Lawless, J. G., Flores, J. J., and Ponnamperuma, C.: 1971b, in R. Buvet and C. Ponnamperuma (eds.), Molecular Evolution I — Chemical Evolution and the Origin of Life, North-Holland Publ. Co., p. 143.
Chadha, M. S., Replogle, L., Flores, J., and Ponnamperuma, C.: 1971c, Bio-Organic Chemistry 1, 269.
Cook, A. H. and Reed, K. J.: 1945, J. Chem. Soc., London, 399.
Folsome, C. E., Lawless, J., Romiez, M., and Ponnamperuma, C.: 1971, Nature 232, 108.
Folsome, C. E., Lawless, J. G., Romiez, M., and Ponnamperuma, C.: 1973, Geochim. Cosmochim. Acta 37, 455.
Hanafusa, H. and Akabori, S.: 1959, Bull. Chem. Soc., Japan 32, 626.
Lemmon, R. M.: 1970, Chemical Rev. 70, 95 and references therein.
Loew, G. H. and Chang, S.: 1971, Tetrahedron 27, 3669.
Loew, G. H., Chadha, M. S., and Chang, S.: 1972, J. Theor. Biol. 35, 359.
Miller, S. L.: 1957, Biochim. Biophys. Acta 23, 480.
Molton, P. M. and Ponnamperuma, C.: 1973, Paper presented at the Middle Atlantic Regional ACS Meeting, Washington, D.C., Jan. 17.
Morimoto, S. and Ponnamperuma, C.: 1970, Paper presented at the 160th ACS meeting, Chicago, Sept. 13–18.
Moser, R. E. and Matthews, C. M.: 1968, Experimentia 24, 658.
Noda, H. and Ponnamperuma, C.: 1971, in R. Buvet and C. Ponnamperuma (eds.), Molecular Evolution I — Chemical Evolution and the Origin of Life, North-Holland Publ. Co., p. 236.
Ponnamperuma, C. and Gabel, N. W.: 1968, Space Life Sci. 1, 64 and references therein.
Ponnamperuma, C. and Woeller, F.: 1967, Curr. Mod. Biol. 1, 156.
Snyder, L. E. and Buhl, D.: 1971, Astrophys. J. 163, L 47.
Woeller, F. and Ponnamperuma, C.: 1969, Icarus 10, 386.
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© 1974 D. Reidel Publishing Company, Dordrecht, Holland
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Chadha, M.S., Molton, P.M., Ponnamperuma, C. (1974). Aminonitriles: Possible Role in Chemical Evolution. In: Oró, J., Miller, S.L., Ponnamperuma, C., Young, R.S. (eds) Cosmochemical Evolution and the Origins of Life. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-2282-8_14
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DOI: https://doi.org/10.1007/978-94-010-2282-8_14
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