Abstract
During the last two decades the thermodynamic properties of numerous polyelectrolytes in aqueous solution have been investigated. Some research workers were more interested in natural, others again in synthetic polyelectrolytes with a variety of counter-ions. The thermodynamic behaviour of pure polyelectrolyte solutions and of their mixtures with simple electrolytes, was studied. It is impossible to give in one lecture a full account of the efforts in this direction. I shall, therefore, confine myself mainly to the work which has been done at this Department.
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References
Strauss, U. P. and Leung, Y. P.: J. Am. Chem. Soc. 87, 1476 (1965).
Kotin, L. and Nagasawa, M.: J. Am. Chem. Soc. 83, 1026 (1961).
Lapanje, L. and Rice, S. A.: J. Am. Chem. Soc. 83, 496 (1961).
Fuoss, R. M., Katchalsky, A., and Lifson, S.: Proc. Natl. Acad. Sci. U.S. 37, 579 (1951).
Alfrey, T., Berg, P. W., and Morawetz, H.: J. Polymer Sci. 7, 543 (1951).
Katchalsky, A., Alexandrowicz, Z., and Kedem, O.: in B. E. Conway and R. G. Barradas (eds.), Chemical Physics of Ionic Solutions, John Wiley & Sons, Inc., New York, 1966. p. 295.
Katchalsky, A.: Pure Appl. Chem. 26, 327 (1971).
Lifson, S. and Katchalsky, A.: J. Polymer Sci. 13, 43 (1954).
Verwey, E. J. W. and Overbeek, J. Th. G.: Theory of the Stability of Lyophobic Colloids, Elsevier, Amsterdam, 1948, p. 56.
Philip, J. R.: J. Chem. Phys. 52, 1387 (1970).
Onsager, L.: Ann. N.Y. Acad. Sci. 51, 627 (1949).
Oman, S. and Dolar, D.: Z. Physik. Chem., Frankfurt 56, 1 (1967).
Oman, S. and Dolar, D.: Z. Physik. Chem., Frankfurt 56, 13 (1967).
Armstrong, R. W. and Strauss, U. P.: in H. F. Mark and N. G. Gaylord (eds.), Encyclopedia of Polymer Science and Technology, vol. 10, Interscience, New York, 1969, p. 781.
Kozak, D., Kristan, J., and Dolar, D.: Z. Physik. Chem., Frankfurt 16, 85 (1971).
Chu, P. and Marinsky, J. A.: J. Phys. Chem. 71, 4352 (1967).
Kozak, D. and Dolar, D.: Z. Physik. Chem., Frankfurt 76, 93 (1971).
Kagawa, I. and Gregor, H. P.: Polymer Sci. 23, 477 (1957).
Manning, G. S.: J. Chem. Phys. 51, 924 (1969).
Ise, N. and Okubo, T.: J. Phys. Chem. 69, 4102 (1965).
Ise, N.: Adv. Polymer Sci. 7, 536 (1971).
Dolar, D. and Leskovšek, H.: Makromol. Chem. 118, 60 (1968).
Vesnaver, G. and Dolar, D.: in press.
Dolar, D., Špan, J., and Pretnar, A.: J. Polymer Sci., Part C 16, 3557 (1968).
Dolar, D.: Z. Physik. Chem., Frankfurt 58, 170 (1968).
Škerjanc, J., Dolar, D., and Leskovšek, D.: Z. Physik. Chem., Frankfurt 56, 207 (1967).
Škerjanc, J., Dolar, D. and Leskovšek, D.: Z. Physik. Chem., Frankfurt 70, 31 (1970).
Škerjanc, J.: J. Phys. Chem. 77, 2225 (1973).
Dolar, D. and Peterlin, A.: J. Chem. Phys. 50, 3011 (1969).
Dolar, D. and Kozak, D.: IUPAC Symposium on Macromolecules, Leiden, 1970, Book of Abstracts, Vol. 1, p. 363.
Dolar, D. and Škerjanc, J.: in preparation for press.
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© 1974 D. Reidel Publishing Company, Dordrecht-Holland
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Dolar, D. (1974). Thermodynamic Properties of Polyelectrolyte Solutions. In: Sélégny, E., Mandel, M., Strauss, U.P. (eds) Polyelectrolytes. Charged and Reactive Polymers, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-2185-2_7
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DOI: https://doi.org/10.1007/978-94-010-2185-2_7
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