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Short-Range Interactions Between Polyions and Small Ions

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Polyelectrolytes

Part of the book series: Charged and Reactive Polymers ((CHRP,volume 1))

Abstract

Specific short-range interactions between polyions and small ions are gradually becoming recognized for their significant and universal role in the behavior of aqueous polyelectrolyte solutions. These interactions, which are observable even with strong polyelectrolytes, — such as the alkali metal salts of polyacids — characteristically involve changes in the solvation states of the participating species and lead to deviations of the net interionic forces from Coulomb’s law. Besides being of intrinsic theoretical interest specific interactions are frequently crucial to the functioning of polyelectrolytes in technological and natural processes [1].

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© 1974 D. Reidel Publishing Company, Dordrecht-Holland

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Strauss, U.P. (1974). Short-Range Interactions Between Polyions and Small Ions. In: Sélégny, E., Mandel, M., Strauss, U.P. (eds) Polyelectrolytes. Charged and Reactive Polymers, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-2185-2_5

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  • DOI: https://doi.org/10.1007/978-94-010-2185-2_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-2187-6

  • Online ISBN: 978-94-010-2185-2

  • eBook Packages: Springer Book Archive

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