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Ion-Binding Phenomena of Polyelectrolytes

  • Chapter
Polyelectrolytes

Part of the book series: Charged and Reactive Polymers ((CHRP,volume 1))

Abstract

The alkali ion salts of carboxylic or sulplionic acid are in general completely dissociated in aqueous solutions if those salts are ordinary simple electrolytes. Even though those groups are fixed on a linear polymer skeleton such as polyacrylate or polystyrene sulphonate, it is reasonable to believe that those salts are completely dissociated in aqueous solutions. Nevertheless, it has often been pointed out that the physical properties of polyelectrolyte solutions can be well explained if we assume that the effective charge density is much lower than the analytical charge density. That is, the counter-ions appear to be bound on fixed charges to decrease the charge density. Such an idea of ion-binding (fixation, condensation etc.) has long been employed by various authors to explain the physical properties of linear polyelectrolyte solutions.

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Author information

Authors and Affiliations

  1. Dept. of Synthetic Chemistry, Nagoya University, Chikusa-Ku, Nagoya, Japan

    Mitsuru Nagasawa

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  1. Mitsuru Nagasawa
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Editor information

Editors and Affiliations

  1. Université de Rouen, France

    Eric Sélégny

  2. University of Leyden, The Netherlands

    Michael Mandel

  3. Rutgers University, USA

    Ulrich P. Strauss

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© 1974 D. Reidel Publishing Company, Dordrecht-Holland

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Nagasawa, M. (1974). Ion-Binding Phenomena of Polyelectrolytes. In: Sélégny, E., Mandel, M., Strauss, U.P. (eds) Polyelectrolytes. Charged and Reactive Polymers, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-2185-2_4

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  • DOI: https://doi.org/10.1007/978-94-010-2185-2_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-2187-6

  • Online ISBN: 978-94-010-2185-2

  • eBook Packages: Springer Book Archive

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