Abstract
Inspection of the alkene-metal hydride complex (1) in which the ligand X(SML) is asymmetrically substituted, indicates that steric or polar interaction between the groups S, M and L and the alkene substituents a, b, c, d should discriminate between alternative modes of co-ordination of the alkene i.e. between adducts (1) and (2).
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© 1976 D. Reidel Publishing Company, Dordrecht, Holland
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McQuillin, F.J. (1976). Asymmetric Hydrogenation. In: Homogeneous Hydrogenation in Organic Chemistry. Homogeneous Catalysis in Organic and Inorganic Chemistry, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1878-4_9
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DOI: https://doi.org/10.1007/978-94-010-1878-4_9
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