Abstract
Transition metal hydrides which are active in hydrogen transfer and catalysis, e.g. (1)–(9), very generally carry stabilising ligands such as
a phosphine, carbonyl, cyanide or π-cyclopentadienyl, capable of retrodative π-bonding. Ligands of this type are, however, not altogether essential. The pent amine hydridorhodium derivative (10) for example, is known as stable salts [1], and the hydride reacts readily with ethylene, propene or but-1-ene to give adducts (11), (R = Et, Pr, Bu), which have been characterised [1].
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
K. Thomas, J. A. Osborn, A. R. Powell, and G. Wilkinson: J. Chem. Soc. (A), 1801 (1968).
A. R. Powell: Platinum Metals Rev. 11, 58 (1967).
R. D. Cramer, E. L. Jenner, R. V. Lindsey, and U. G. Stolberg: J. Amer. Chem. Soc. 85, 1691 (1963).
R. D. Cramer and R. V. Lindsey: J. Amer. Chem. Soc. 88, 3534 (1966).
G. C. Bond and M. Hellier: Chem. and Intl., 35 (1965).
G. C. Bond and M. Hellier: J. Catal. 7, 217 (1967).
J. H. Flynn and H. M. Hulbert: J. Amer. Chem. Soc. 76, 3393 (1954).
J. A. Osborn, F. H. Jardine, J. F. Young, and G. Wilkinson: J. Chem. Soc. (A), 1711 (1966).
G. C. Bond and R. A. Hillyard: Discuss. Faraday Soc. 46, 20 (1968).
F. H. Jardine, J. A. Osborn, and G. Wilkinson: J. Chem. Soc. (A), 1574 (1967).
W. Strohmeier and R. Endres: Z. Naturforsch., 2613, 362 (1971).
L. Vaska and M. F. Werneke: Trans. New York Acad. Sci. 31, 70 (1971).
D. Rose, J. D. Gilbert, R. P. Richardson, and G. Wilkinson: J. Chem. Soc. (A), 2610 (1969).
C. O’Connor and G. Wilkinson: Tetrahedron Letters, 1375 (1969).
S. Montelatici, A. van der Ent, J. A. Osborn, and G. Wilkinson: J. Chem. Soc. (A), 1054 (1968).
R. Stern, Y. Chevallier, and L. Sajus: Compt. rend. 264, 1740 (1967).
C. Masters, W. S. McDonald, G. Raper, and B. L. Shaw: J. Chem. Soc. Chem. Comm., 210 (1971).
C. Masters and B. L. Shaw: J. Chem. Soc. (A), 3679 (1971).
D. E. Budd, D. G. Holah, A. N. Hughes, and B. C. Hui: Canad. J. Chem. 52, 775 (1974).
D. G. Holah, I. M. Hoodless, A. N. Hughes, B. C. Hui, and D. Martin: Canad. J. Chem. 52, 3758 (1974).
Y. Chevallier, R. Stern, and L. Sajus: Tetrahedron Letts., 1197 (1969).
W. Voelter and C. Djerassi: Chem. Ber. 101, 58 (1968).
R. L. Augustine and J. van Peppen: J. Chem. Soc. Chem. Comm., 495 (1970).
W. Voelter and C. Djerassi: Chem. Ber. 101, 1154 (1968).
A. S. Hussey and Y. Takencho: J. Org. Chem. 35, 643 (1970).
J. P. Candlin and A. R. Oldham: Discussion Faraday Soc. 46, 60 (1968).
J. R. Shapley, R. R. Schrock, and J. A. Osborn: J. Amer. Chem. Soc. 91, 2816 (1969).
R. R. Schrock and J. A. Osborn: J. Amer. Chem. Soc. 93, 2397 (1971).
R. R. Schrock and J. A. Osborn: J. Chem. Soc. Chem. Comm., 567 (1970).
B. Hui and B. R. James: J. Chem. Soc. Chem. Comm., 198 (1969).
B. Hui and B. R. James: Can. J. Chem. 52, 3760 (1974).
I. Ogata, R. Owata, and Y. Ikeda: Tetrahedron Letters, 3011 (1970).
B. R. James and G. L. Rempel: Discussion Faraday Soc. 46, 48 (1968).
B. R. James and G. L. Rempel: Canad. J. Chem. 44, 233 (1966).
P. Abley, I. Jardine, and F. J. McQuillin: J. Chem. Soc. (C), 840 (1971).
P. Abley and F. J. McQuillin: J. Catal. 24, 536 (1972).
A. G. Hinze and D. J. Frost: J. Catal. 24, 540 (1972).
W. Strohmeier: Fortschritte der Chemischen Forschung 25, 71 (1972).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1976 D. Reidel Publishing Company, Dordrecht, Holland
About this chapter
Cite this chapter
McQuillin, F.J. (1976). Liganos and Solvents. In: Homogeneous Hydrogenation in Organic Chemistry. Homogeneous Catalysis in Organic and Inorganic Chemistry, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1878-4_8
Download citation
DOI: https://doi.org/10.1007/978-94-010-1878-4_8
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-1880-7
Online ISBN: 978-94-010-1878-4
eBook Packages: Springer Book Archive