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Isomerisation and Specific Deuteriation

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Book cover Homogeneous Hydrogenation in Organic Chemistry

Part of the book series: Homogeneous Catalysis in Organic and Inorganic Chemistry ((CMCO,volume 1))

Abstract

It was noted in Chapter I that in hydrogenation the process of addition of a metal hydride across an alkene bond is fundamentally reversible, i.e.:

Thus the mechanism of hydrogenation contains the possibility of alkene isomerisation since it is also evident that the reverse process of elimination of L n MH from the metal alkyl (2) may involve either hydrogen H(a), leading back to the parent alkene (1), or H(b) yielding an isomerised alkene.

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Authors and Affiliations

  1. University of Newcastle upon Tyne, England

    F. J. McQuillin

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  1. F. J. McQuillin
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© 1976 D. Reidel Publishing Company, Dordrecht, Holland

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McQuillin, F.J. (1976). Isomerisation and Specific Deuteriation. In: Homogeneous Hydrogenation in Organic Chemistry. Homogeneous Catalysis in Organic and Inorganic Chemistry, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1878-4_7

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  • DOI: https://doi.org/10.1007/978-94-010-1878-4_7

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-1880-7

  • Online ISBN: 978-94-010-1878-4

  • eBook Packages: Springer Book Archive

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