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Structural and Magnetic Properties of Layered Chalcogenides of the Transition Elements

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Optical and Electrical Properties

Part of the book series: Physics and Chemistry of Materials with Layered Structures ((PCMA,volume 4))

Abstract

The physical properties of layered materials have been a field of intensive study for many years. Particularly, attention has focused on the transition-metal dichalcogenides which form typical layer structures. They are built from layers of metal atoms M, sandwiched between two sheets of chalcogens X, which are bonded by van der Waals energy. The early work on transition-metal dichalcogenides has been reviewed by Wilson and Yoffe [1]. Also, their structural properties were briefly reviewed in a chapter on transition-metal chalcogenides by Jellinek [2]. More recently a review article on inclusion compounds, by Gamble and Geballe [3], discussed the chemistry and physical properties of chalcogenide intercalation compounds. Optics, transparent and anisotropic physical properties were measured in order to study their band structure [4, 5, 6, 6a]. However, it appears that among transition-metal chalcogenides the typical layer materials do not show the most interesting magnetic properties. With a few exceptions they are either Pauli-paramagnetic metals or diamagnetic semiconductors.

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References

  1. J. A. Wilson and A. D. Yoffe: Adv. Phys. 18 (1969), 193.

    Article  CAS  Google Scholar 

  2. F. Jellinek: Sulphides, Selenides and Tellurides of the Transition Elements, MTP Int. Rev. Sci., Inorg. Chem. Ser. One, Vol. 5, 1972, p. 355.

    Google Scholar 

  3. F. R. Gamble and T. H. Geballe, Treatise on Solid State Chemistry, (N. B. Hannay, Ed.), Plenum Publishing Corp., Vol. 3, Chapter 2 (to be published).

    Google Scholar 

  4. R. A. Bromley and R. B. Murray: J. Phys. C. Solid State Phys. 5 (1972), 738.

    Article  CAS  Google Scholar 

  5. R. B. Murray, R. A. Bromley, and A. D. Yoffe: J. Phys. C. Solid State Phys. 5 (1972), 746 and 759.

    Google Scholar 

  6. R. B. Murray and A. D. Yoffe: J. Phys. C. Solid State Phys. 5 (1972), 3038.

    Article  CAS  Google Scholar 

  7. R. M. White and G. Lucovsky: Solid State Comm. 11 (1972), 1369.

    Article  CAS  Google Scholar 

  8. K. Anzenhofer, J. M. Vandenberg, P. Cossee, and J. N. Helle: J. Phys. Chem. Solids 31 (1970), 1057.

    Article  CAS  Google Scholar 

  9. R. J. H. Voorhoeve and J. C. M. Stuiver: J. Catal. 23 (1971), 243.

    Article  CAS  Google Scholar 

  10. R. Huisman, R. De Jonge, C. Haas, and F. Jellinek: J. Solid State Chem. 3 (1971), 56.

    Article  CAS  Google Scholar 

  11. L. F. Mattheiss: Phys. Rev. B8 (1973), 3719.

    Article  CAS  Google Scholar 

  12. R. S. Title and M. W. Shafer: Phys. Rev. Letters 28 (1972), 808.

    Article  CAS  Google Scholar 

  13. R. S. Title, M. W. Shafer, and F. Mehran: ONR Conf. Phys. Chem. Layered Compounds, 1972.

    Google Scholar 

  14. B. E. Brown: Acta Cryst. 20 (1966), 268.

    Article  CAS  Google Scholar 

  15. R. De Jonge: Thesis, Groningen, 1970.

    Google Scholar 

  16. A. A. Opalovskii and V. E. Fedorov: Russ. Chem. Rev. 35 (1966), 186.

    Article  Google Scholar 

  17. L. H. Brixner: J. Electrochem. Soc. 110 (1963), 289.

    Article  Google Scholar 

  18. W. T. Hicks : J. Electrochem. Soc. 111 (1964), 1058.

    Article  CAS  Google Scholar 

  19. L. C. Upadhyayula, J. J. Loferiski, A. Wold, W. Giriat, and R. Kershaw: J. Appl. Phys. 39 (1968), 4736.

    Article  CAS  Google Scholar 

  20. T. J. Wieting: J. Phys. Chem. Solids 31 (1970), 2148.

    Google Scholar 

  21. R. S. Title and M. W. Shafer: Phys. Rev. Letters 28 (1972), 808.

    Article  CAS  Google Scholar 

  22. V. L. Kalikhman and L. L. Pravoverova: Izv. Akad. Nauk SSSR, Neorgan. Mat. 7 (1971), 2162.

    CAS  Google Scholar 

  23. V. L. Kalikhman, T. A. Lobova, and L. L. Pravoverova: Inorg. Mater. 9 (1973), 826.

    Google Scholar 

  24. V. L. Kalikhman, T. A. Lobova, and L. L. Pravoverova: Inorg. Mater. 9 (1973), 826.

    Google Scholar 

  25. W. Geertsma and C. Haas: Proc. 4th Int. Conf. on Transition Metal Compounds, Geneva, April 9–13, 1973, p. 135.

    Google Scholar 

  26. W. P. F. A. M. Omloo and F. Jellinek: J. Less-Common Metals 20 (1970), 121.

    Article  CAS  Google Scholar 

  27. W. Rüdorff: Chimia 19 (1965), 489.

    Google Scholar 

  28. R. B. Somoano and A. Rembaum: Phys. Rev. Letters 27 (1971), 402.

    Article  CAS  Google Scholar 

  29. A. M. Herman: Solid State Comm. 13 (1973), 1065.

    Article  Google Scholar 

  30. J. V. Acrivos, W. Y. Liang, J. A. Wilson, and A. D. Yoffe: J. Phys. C. Proc. Phys. Soc., London 4 (1971), L18.

    CAS  Google Scholar 

  31. R. B. Somoano, V. Hadek, and A. Rembaum: J. Chem. Phys. 58 (1973), 697.

    Article  CAS  Google Scholar 

  32. . R. B. Somoano, V. Hadek, and A. Rembaum: ONR Conf. Phys. Chem. Layered Compounds, 1972.

    Google Scholar 

  33. A. D. Yoffe: Annual Review of Materials Science, Annual Reviews Inc., California, 1973, p. 147.

    Google Scholar 

  34. A. D. Yoffe: Festkorperprobleme, XIII (1973), 1.

    Google Scholar 

  35. G. V. Subba Rao, M. W. Shafer, S. Kawarazaki, and A. M. Toxen: J. Solid State Chem. 9 (1974), 323.

    Article  Google Scholar 

  36. C. B. Carter and P. M. Williams: Phil. Mag. 26 (1972), 393.

    Article  CAS  Google Scholar 

  37. J. F. Di Salvo, G. W. Hull, Jr., L. H. Schwartz, J. M. Voorhoeve, and J. V. Waszczak: J. Chem. Phys. 59 (1973), 1922.

    Google Scholar 

  38. F. R. Gamble: J. Solid State Chem. 9 (1974), 358.

    Article  CAS  Google Scholar 

  39. N. W. Alcock and A. Kjekshus: Acta Chem. Scand. 19 (1965), 79.

    Article  CAS  Google Scholar 

  40. J. C. Wildervanck and F. Jellinek: J. Less-Common Metals 24 (1971), 73.

    Article  CAS  Google Scholar 

  41. J. C. Wildervanck: Thesis, Groningen, Netherlands, 1970.

    Google Scholar 

  42. F. Kadijk and F. Jellinek: J. Less-Common Metals 19 (1969), 421.

    Article  CAS  Google Scholar 

  43. F. Kadijk and F. Jellinek: J. Less-Common Metals 23 (1971), 437.

    Article  CAS  Google Scholar 

  44. R. Huisman and F. Jellinek: J. Less-Common Metals 17 (1969), 111.

    Article  CAS  Google Scholar 

  45. J. F. Revelli and W. A. Phillips: J. Solid State Chem. 9 (1974), 176.

    Article  CAS  Google Scholar 

  46. K. Selte and A. Kjekshus: Acta Chem. Scand. 19 (1965), 259.

    Google Scholar 

  47. R. K. Quinn, R. Simmons, and J. J. Banewicz: J. Phys. Chem. 70 (1966), 230.

    Article  CAS  Google Scholar 

  48. E. Bjerkelund and A. Kjekshus: Acta Chem. Scand. 21 (1967), 513.

    Article  CAS  Google Scholar 

  49. F. Kadijk: Thesis, Groningen, Netherlands, 1969.

    Google Scholar 

  50. R. Huisman: Thesis, Groningen, Netherlands, 1969.

    Google Scholar 

  51. J. Edwards and R. F. Frindt: J. Phys. Chem. Solids 32 (1971), 2217.

    Article  CAS  Google Scholar 

  52. R. F. Frindt, R. B. Murray, G. P. Pitt, and A. D. Yoffe: J. Phys. C. Solid State Phys. 5 (1972), L154.

    Article  CAS  Google Scholar 

  53. D. Jerome, A. J. Grant, and A. D. Yoffe: Solid State Comm. 9 (1971), 2183.

    Article  CAS  Google Scholar 

  54. . R. F. Frindt: ONR Conf. Phys. Chem. Layered Compounds, 1972.

    Google Scholar 

  55. T. F. Smith, L. E. Delong, A. R. Moodenbaugh, T. H. Geballe, and R. E. Schwall: J. Phys. C. Solid State Phys. 5 (1972), L230.

    Article  CAS  Google Scholar 

  56. F. J. Di Salvo, B. G. Bagley, J. M. Voorhoeve, and J. V. Waszczak: J. Phys. Chem. Solids 34 (1973), 1357.

    Article  Google Scholar 

  57. R. Huisman, F. Kadijk, and F. Jellinek: J. Less-Common Metals 21 (1970), 187.

    Article  CAS  Google Scholar 

  58. H. N. S. Lee, M. Garcia, H. McKinzie, and A. Wold: J. Solid State Chem. 1 (1970), 190.

    Article  CAS  Google Scholar 

  59. R. Kershaw, M. Vlasse, and A. Wold: Inorg. Chem. 6 (1967), 1599.

    Article  CAS  Google Scholar 

  60. H. N. S. Lee, H. McKinzie, D. S. Tannhauser, and A. Wold: J. Appl. Phys. 40 (1969), 602.

    Article  CAS  Google Scholar 

  61. L. E. Conroy and K. R. Pisharody: J. Solid State Chem. 4 (1972), 345.

    Article  CAS  Google Scholar 

  62. E. Ehrenfreund, A. C. Gossard, F. R. Gamble, and T. H. Geballe: J. Appl. Phys. 42 (1971), 1491.

    Article  CAS  Google Scholar 

  63. M. Marezio, P. D. Dernier, A. Menth, and G. W. Hull: J. Solid State Chem. 4 (1972), 425.

    Article  CAS  Google Scholar 

  64. J. A. Wilson, F. J. Di Salvo, and S. Mahajan: Phys. Rev. Letters 32 (1974), 882.

    Article  CAS  Google Scholar 

  65. R. Brouwer and F. Jellinek: Mat. Res. Bull. 9 (1974), 827.

    Article  CAS  Google Scholar 

  66. A. H. Thompson, F. R. Gamble, and J. F. Revelli: Solid State Comm. 9 (1971), 981.

    Article  CAS  Google Scholar 

  67. G. K. Wertheim, F. J. Di Salvo, and D. N. E. Buchanan: Solid State Comm. 13 (1973), 1225.

    Article  CAS  Google Scholar 

  68. F. J. Di Salvo, R. G. Maines, J. V. Waszczak, and R. E. Schwall: Solid State Comm. 14 (1974), 497.

    Article  Google Scholar 

  69. A. H. Thompson, K. R. Pisharody, and R. F. Koehler: Phys. Rev. Letters 29 (1972), 163.

    Article  CAS  Google Scholar 

  70. F. J. Di Salvo: private communication.

    Google Scholar 

  71. B. E. Brown: Acta Cryst. 20 (1966), 264.

    Article  CAS  Google Scholar 

  72. K. Selte, E. Bjerkelund, and A. Kjekshus: J. Less-Common Metals 11 (1966), 14.

    Article  CAS  Google Scholar 

  73. J. M. Vandenberg and P. Cossee: Inorg. Chim. Acta 2 (1968), 143.

    Article  CAS  Google Scholar 

  74. A. E. van Arkel and C. Crevecoeur: J. Less-Common Metals 5 (1963), 177.

    Article  CAS  Google Scholar 

  75. K. Koerts: Acta Cryst. 16 (1963), 432.

    Article  CAS  Google Scholar 

  76. J. M. Vandenberg: J. Less-Common Metals 13 (1967), 363.

    Article  Google Scholar 

  77. J. M. Voorhoeve-Vandenberg: J. Less-Common Metals 26 (1972), 399.

    Article  CAS  Google Scholar 

  78. K. Anzenhofer, J. M. Vandenberg, P. Gossee, and J. N. Helle: J. Phys. Chem. Solids 31 (1970), 1057.

    Article  CAS  Google Scholar 

  79. K. Anzenhofer and J. J. de Boer: Recueil. 90 (1971), 56.

    CAS  Google Scholar 

  80. B. van Laar, H. M. Rietveld, and D. J. W. Ydo: J. Solid State Chem. 3 (1971), 154.

    Article  Google Scholar 

  81. F. Hulliger and E. Pobitschka: J. Solid State Chem. 1 (1970), 117.

    Article  CAS  Google Scholar 

  82. A. Le Blanc and J. Rouxel: Compt. Rend. Acad. Sci. Paris 276C (1970), 1976.

    Google Scholar 

  83. J. Rouxel, A. Le Blanc, and A. Royer: Bull. Soc. Chim. Fr. (1971), 2019.

    Google Scholar 

  84. A. Royer, A. Le Blanc, and J. Rouxel: Compt. Rend. Acad. Sci. Paris 276C (1973), 1021.

    CAS  Google Scholar 

  85. J. M. Voorhoeve-Vandenberg and M. Robbins: J. Solid State Chem. 1 (1970), 134.

    Article  Google Scholar 

  86. A. Meerschaut and J. Rouxel: Compt. Rend. Acad. Sci. Paris 277C (1973), 163.

    CAS  Google Scholar 

  87. J. J. Hauser, M. Robbins, and F. J. Di Salvo: Phys. Rev. B8 (1973), 1038.

    Article  CAS  Google Scholar 

  88. A. Menth: Program of the 1971 March meeting of the American Physical Society, p. 403.

    Google Scholar 

  89. K. Verhoeven: Intercalation Compounds of First-Row Transition Metal Atoms with Structures of the 2s—NbS2 Type, Thesis, Leiden, Netherlands, 1971.

    Google Scholar 

  90. J. M. Voorhoeve-Vandenberg and R. C. Sherwood: J. Phys. Chem. Solids 32 (1971), 167.

    Article  CAS  Google Scholar 

  91. F. Jellinek: Mat. Res. Bull. 6 (1971), 169.

    Article  CAS  Google Scholar 

  92. G. V. Subba Rao, M. W. Shafer, and L. J. Tao: Mat. Res. Bull. 8 (1973), 1231.

    Article  Google Scholar 

  93. R. A. Bromley and R. B. Murray: J. Phys. C. Solid State Phys. 5 (1972), 738.

    Article  CAS  Google Scholar 

  94. A. B. de Vries and C. Haas: J. Phys. Chem. Solids 34 (1973), 651.

    Article  Google Scholar 

  95. J. B. Goodenough: Magnetism and the Chemical Bond, Interscience Publishers, 1963, p. 168.

    Google Scholar 

  96. W. P. F. A. M. Omloo and F. Jellinek: J. Less-Common Metals 20 (1970), 121.

    Article  CAS  Google Scholar 

  97. F. J. Di Salvo, G. W. Hull, Jr., L. H. Schwartz, J. M. Voorhoeve, and J. V. Waszczak: J. Chem. Phys. 59 (1973), 1922.

    Google Scholar 

  98. J. M. Voorhoeve-Vandenberg: J. Less-Common Metals 26 (1972), 399.

    Article  CAS  Google Scholar 

  99. A. C. Gossard, F. J. Di Salvo, and H. Yasuoka: Phys. Rev. B9 (1974), 3965.

    Article  CAS  Google Scholar 

  100. D. W. Murphy, F. J. Di Salvo et al: J. Chem. Phys. 62 (1975) 967.

    Article  CAS  Google Scholar 

  101. R. B. Murray, R. A. Bromley, and A. D. Yoffe: J. Phys. C. Solid State Phys. 5 (1972), 746.

    Article  CAS  Google Scholar 

  102. M. Danot, A. Le Blanc, and J. Rouxel: Bull Soc. Chim. Fr. (1969), 2670.

    Google Scholar 

  103. J. Rouxel, M. Danot, and J. Bichon: Bull Soc. Chim. Fr. (1969), 3930.

    Google Scholar 

  104. J. Bichon, M. Danot, and J. Rouxel: Compt. Rend. Acad. Sci. Paris 276C (1973), 1283.

    CAS  Google Scholar 

  105. J. Rouxel, J. Cousfceau, and L. Trichet: Compt. Rend. Acad. Sci. Paris 273C (1971), 243.

    CAS  Google Scholar 

  106. J. Cousseau, L. Trichet, and J. Rouxel: Bull Soc. Chim. Fr. (1973), 872.

    Google Scholar 

  107. A. Le Blanc, M. Danot, L. Trichet, and J. Rouxel: Mat. Res. Bull. 9 (1974), 191.

    Article  Google Scholar 

  108. L. Trichet and J. Rouxel: Compt. Rend. Acad. Sci. Paris 269C (1969), 1040.

    CAS  Google Scholar 

  109. L. Trichet, J. Cousseau, and J. Rouxel: Compt. Rend. Acad. Sci. Paris 274C (1972), 394.

    CAS  Google Scholar 

  110. M. Danot, J. Bichon, and J. Rouxel: Bull Soc. Chim. Fr. (1972), 3063.

    Google Scholar 

  111. M. Danot and J. Rouxel: Compt. Rend. Acad. Sci. Paris 271C (1970), 998.

    CAS  Google Scholar 

  112. T. Takahashi and O. Yamada: J. Solid State Chem. 7 (1973), 25.

    Article  CAS  Google Scholar 

  113. J. W. Boon and C. H. MacGillavry: Rec. Trav. Chim. Pays-Bas Belg. 61 (1942), 910.

    Article  CAS  Google Scholar 

  114. W. Rüdorff and K. Stegemann: Z. Anorg. Allg. Chem. 251 (1943), 376.

    Article  Google Scholar 

  115. W. Rudorff, W. R. Ruston, and A. Scherhaufer: Acta Cryst. 1 (1948), 196.

    Article  Google Scholar 

  116. B. van Laar and D. J. W. Ydo: J. Solid State Chem. 3 (1971), 590.

    Article  Google Scholar 

  117. P. F. Bongers, C. F. van Bruggen, J. Koopstra, W. P. Omloo, G. A. Wiegers, and F. Jellinek: J. Phys. Chem. Solids 29 (1968), 977.

    Article  CAS  Google Scholar 

  118. W. P. F. A. M. Omloo: Thesis, Groningen, Netherlands, 1969.

    Google Scholar 

  119. F. M. R. Engelsman, G. A. Wiegers, F. Jellinek, and B. van Laar: J. Solid State Chem. 6 (1973), 574.

    Article  CAS  Google Scholar 

  120. S. L. Carr, Paul Erdös, W. G. Moulton, and J. Robinson: Solid State Commun. 7 (1969), 1673.

    Google Scholar 

  121. B. van Laar and F. M. R. Engelsman: J. Solid State Chem. 6 (1973), 384.

    Article  Google Scholar 

  122. J. B. Goodenough: Magnetism and the Chemical Bond, Interscience, New York, London, 1963, p. 165.

    Google Scholar 

  123. F. Hulliger: Structure and Bonding, Vol. 4, Springer-Verlag, New York, 1968, p. 195.

    Google Scholar 

  124. W. Bronger, J. Eyck, W. Rüdorff, and A. Stossel: Z. Anorg. Allg. Chem. 375 (1970), 1.

    Article  CAS  Google Scholar 

  125. W. Bronger and J. Hustler: J. Less-Common Metals 23 (1971), 67.

    Article  CAS  Google Scholar 

  126. W. Rüdorff, A. Stossel, and V. Schmidt: Z. Anorg. Allg. Chem. 357 (1968), 264.

    Article  Google Scholar 

  127. O. Gunther and W. Bronger: J. Less-Common Metals 31 (1973), 255.

    Article  Google Scholar 

  128. A. Okazaki and K. Hirakawa: J. Phys. Soc. Japan 11 (1956), 930.

    Article  CAS  Google Scholar 

  129. F. Jellinek: Acta Cryst. 10 (1957), 620.

    Article  CAS  Google Scholar 

  130. A. Kjekshus and W. B. Pearson: Progress in Solid State Chemistry, Vol. I, 1964, p. 83.

    Google Scholar 

  131. F. Hulliger : Structure and Bonding, Springer-Verlag, New York, Inc., Vol. 4, 1968, p. 157.

    Google Scholar 

  132. J. M. Vandenberg: Inorg. Chim. Acta. 2 (1968), 216.

    Article  Google Scholar 

  133. R. Chevrel, M. Sergent, and J. Prigent: Compt. Rend. Acad. Sci. Paris 267C (1968), 1135.

    CAS  Google Scholar 

  134. R. Cfievrel, J. Guillevic, and M. Sergent: Compt. Rend. Acad. Sci. Paris 271C (1970), 1240.

    CAS  Google Scholar 

  135. J. Guillevic, R. Chevrel, and M. Sergent: Bull Soc. Fr. Mineral Cristallogr. 93 (1970), 495.

    CAS  Google Scholar 

  136. K. Anzenhofer and J. J. de Boer: Acta Cryst. B25 (1969), 1419.

    Google Scholar 

  137. A. Meerschaut and J. Rouxel: Compt. Rend. Acad. Sci. Paris 277C (1973), 163.

    CAS  Google Scholar 

  138. K. Verhoeven: Intercalation Compounds of First-Row Transition Metal Atoms with Structures of the 2s—NbS2 Type, Thesis, Leiden, Netherlands, 1971.

    Google Scholar 

  139. W. P. F. A. M. Omloo and F. Jellinek: J. Less-Common Metals 20 (1970), 121.

    Article  CAS  Google Scholar 

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    J. M. Vandenberg-Voorhoeve

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    Peter A. Lee

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Vandenberg-Voorhoeve, J.M. (1976). Structural and Magnetic Properties of Layered Chalcogenides of the Transition Elements. In: Lee, P.A. (eds) Optical and Electrical Properties. Physics and Chemistry of Materials with Layered Structures, vol 4. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1478-6_8

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