Skip to main content
SpringerLink
Log in

Measurement of Fluxes and Forces at the Surface of Cation-Exchange Membranes under Conditions of Controlled Polarization

II: Application of Measurement — Use of Phenomenological Coefficients

  • Chapter
Charged Gels and Membranes

Part of the book series: Charged and Reactive Polymers ((CHRP,volume 3))

  • 111 Accesses

Abstract

The nine differential phenomenological coefficients of a non-commercial cation-exchange membrane were measured in 0.1 M sodium chloride and the Onsager reciprocal relations verified. Since these results were obtained from measurements of fluxes and forces at the membrane interface without the intervention of a hydrostatic pressure, the technical difficulties connected with the compression of the membrane were thus overcome. Hydrodynamic influences at these interfaces upon volumetric and ionic transport numbers could readily be simulated thereby, and it was shown that the existence of a transport number independent of current density does not constitute full proof of complete depolarization.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Meares, P.: this volume, p. 123.

    Google Scholar 

  2. Foley, T., Klinowski, J., and Meares, P.: Proc. Roy. Soc. A 336, 327 (1974).

    Article  CAS  Google Scholar 

  3. Staverman, A. J.: Trans Faraday Soc. 48, 176 (1952).

    Article  CAS  Google Scholar 

  4. Kedem, O. and Katchalsky, A.: (1963).

    Google Scholar 

  5. Spiegler, K. S.: Trans Faraday Soc. 54, 1408 (1958).

    Article  CAS  Google Scholar 

  6. Ramer, H. K. and Meares, P.: Biophys. J. 9, 1006 (1969).

    Article  Google Scholar 

  7. Demarty, M. and Sélégny, E.: C.R. Acad. Sci. C 276, 1549 (1973).

    Google Scholar 

  8. Dorst, W. and Staverman, A. J.: Rec. Tray. Chim. 86, 61 (1967).

    Article  CAS  Google Scholar 

  9. Meares, P., Thain, J. F., and Danson, D. G.: in G. Eisenman (ed.) Membranes, Marcel Dekker, New York, 1972.

    Google Scholar 

  10. Paterson, R. and Gardner, C. R.: J. Chem. Soc. A, 2254 (1971).

    Google Scholar 

  11. Thau, G., Block, R., and Kedem, O.: Desalination 1, 129 (1966).

    Article  CAS  Google Scholar 

  12. Sélégny, E. and Bourdillon, C.: this volume, p. 183.

    Google Scholar 

  13. Katchalsky, A. and Curran, P.: Non-Equilibrium Thermodynamics in Biophysics, Harvard Univ. Press, Boston, 1965.

    Google Scholar 

  14. Kirkwood, J. G.: Ion Transport Across Membranes, Academic Press, New York, 1954.

    Google Scholar 

  15. Kindly furnished by Dr. E. Korngold (Negev Institute).

    Google Scholar 

  16. Snell, F. M. and Stein, B.: J. Theoret. Biol. 10, 177 (1966).

    Article  CAS  Google Scholar 

  17. Oda, Y. and Yawataya, T.: Bull. Chem. Soc. Japan 29, 673 (1956).

    Article  CAS  Google Scholar 

  18. Block, M. and Kitchener, J. A.: J. Electrochem. Soc. 113, 947 (1966).

    Article  CAS  Google Scholar 

  19. Gregor, H. P. and Peterson, M. A.: J. Phys. Chem. 68, 2201 (1964).

    Article  CAS  Google Scholar 

  20. Oda, Y. and Yawataya, T.: Desalination 5, 129 (1968).

    Article  CAS  Google Scholar 

  21. Ripoll, C., Demarty, M. and Sélégny, E.: J. de Chim. Phys. 71, 828 (1974).

    CAS  Google Scholar 

  22. Bourdillon, C., Metayer, M., and Sélégny, E.: J. de Chim. Phys. 3, 91 (1973).

    Google Scholar 

  23. Cooke, B. A. and Van der Valt S. J.: Electrochim. Acta. 5, 216 (1961).

    Article  CAS  Google Scholar 

  24. Bourdillon, C., Metayer, M., and Sélégny, E.: J. de Chim. Phys. 5, 788 (1974).

    Google Scholar 

  25. Brun, T. S. and Vaula, D.: Ber Bunsenges Physik, Chem 71, 824 (1967).

    Google Scholar 

  26. Kabatake, Y. and Kamo, N.: 4th International Symposium on Fresh Water from the Sea (ed. by E. and A. Delyannis), Athens, Vol. 3, 91 (1973).

    Google Scholar 

  27. Madkay, D. and Ivreares, P.: Trans Faraday’ Soc. 55, 1221 (1959).

    Article  Google Scholar 

  28. Meares, P. and Sutton, A. H.: J. Colloid Interface Science 28, 118 (1968).

    Article  CAS  Google Scholar 

  29. McHardy, W. J., Meares, P., Sutton, A. H., and Thain, J. F.: J. Colloid Interface Science 29, 116 (1969).

    Article  CAS  Google Scholar 

  30. Lorimer, J. W., Boterenbrood, E. I., and Hermans, J. V.: Disc. Faraday Soc. 21, 141 (1956).

    Article  Google Scholar 

  31. Scatergood, E. M. and Lightfoot, E. N.: Trans Faraday Soc. 64, 1135 (1968).

    Article  Google Scholar 

  32. Levich, V. G.: Physicochemical Hydrodynamics, Prentice Hall, New York 1962.

    Google Scholar 

  33. George, J. H. B. and Courant, R. A.: J. Phys. Chem. 71, 246 (1967).

    Article  CAS  Google Scholar 

  34. Lakshminarayanaiah, N.: Transport Phenomena in Membranes, Academic Press, New York 1969.

    Google Scholar 

Download references

Author information

Author notes

  1. Christian Bourdillon

    Present address: Lab. Technologie Enzymatique, Université Technologique de Compiègne, Compiègne, France

Authors and Affiliations

  1. Laboratory of Macromolecular Chemistry, ERA 471, Faculty of Sciences and Technology of the University of Rouen, 76130, Mont Saint Aignan, France

    Christian Bourdillon & Eric Sélégny

Authors
  1. Christian Bourdillon
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Eric Sélégny
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Université de Rouen, France

    Eric Sélégny (Director of the Institute) (Director of the Institute)

  2. University of Georgia, USA

    George Boyd

  3. Columbia University, USA

    Harry P. Gregor

Rights and permissions

Reprints and permissions

Copyright information

© 1976 D. Reidel Publishing Company, Dordrecht-Holland

About this chapter

Cite this chapter

Bourdillon, C., Sélégny, E. (1976). Measurement of Fluxes and Forces at the Surface of Cation-Exchange Membranes under Conditions of Controlled Polarization. In: Sélégny, E., Boyd, G., Gregor, H.P. (eds) Charged Gels and Membranes. Charged and Reactive Polymers, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1464-9_9

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-1464-9_9

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-1466-3

  • Online ISBN: 978-94-010-1464-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation