Abstract
The triplet mechanism of electron spin polarization is described first qualitatively, and then with full dynamical freedom allowing for rotation chemical quenching, and initiation with polarized light. The contents are (1) the underlying physical model, including an estimate of the magnitudes and an argument based on a simple kinetic scheme, (2) the full dynamical problem, treating relaxation, rotation, and reaction consistently.
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P.W. Atkins and K.A. McLauchlan, in Chemically Induced Magnetic Polarization, ed. by A.R. Lepley and G.L. Closs, Wiley, New York, 1973.
S.K. Wong, D.A. Hutchinson, and J.K.S. Wan, J. Chem. Phys., 58, 985 (1973).
P.W. Atkins and G.T. Evans, Mol. Phys., 27, 1633 (1974).
P.W. Atkins and G.T. Evans, Adv. Chem. Phys., 35, 1 (1976).
J.H. Freed and J.B. Pedersen, Adv. Mag. Reson., 8, 1 (1976).
P.W. Atkins, A.J. Dobbs, and K.A. McLauchlan, Chem. Phys. Letts. 29, 616 (1974).
C.P. Slichter, Principles of Magnetic Resonance, Harper and Row, New York, 1963.
L.T. Muus and P.W. Atkins, eds, Electron Spin Relaxation in Liquids, Plenum, New York, 1972.
F.J. Adrian, J. Chem. Phys., 61, 4875 (1974).
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© 1977 D. Reidel Publishing Company, Dordrecht, Holland
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Atkins, P.W. (1977). The Triplet Mechanism. In: Muus, L.T., Atkins, P.W., McLauchlan, K.A., Pedersen, J.B. (eds) Chemically Induced Magnetic Polarization. Nato Advanced Study Institutes Series, vol 34. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1265-2_11
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DOI: https://doi.org/10.1007/978-94-010-1265-2_11
Publisher Name: Springer, Dordrecht
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