Abstract
The use of porous carbons, especially activated carbons, for gas separation is wellestablished in chemical engineering processes. Their use for storage of fuel gases has also been studied over the years. However, environmental pressures for cleaner fuels, especially for motor vehicles, have prompted a resurgence of interest in the potential of porous carbons as storage media for natural gas and for hydrogen. In this Chapter some applications of porous carbons for gas separation and storage are reviewed. The focus is on the design of the porous carbons for different duties. The processes selected for review include the separation of oxygen and nitrogen from air, methane and carbon dioxide from landfill gas, and hydrogen from hydrocarbons using molecular sieve carbons and membranes. Recently, novel forms of porous carbon, including carbon nanotubes and vapour grown carbon nanofibres have been considered as substrates for gas storage and the potential of these materials for natural gas and hydrogen storage will also be assessed.
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References
Sing, K.S. W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierro M, R.A., Rouquerol, J., and Siemieniewska, T. (1985) Reporting physisoiption data for gas/solid systems, Pure Appl Chem. 57,603–619.
Rodriguez-Reinoso, F., and Linares-Solano, A. (1988) Microporous structure of activated carbons as revealed by adsorption methods, in P.A. Thrower (ed) Chemistry and Physics cf Carbon, Vol. 21, Marcel Dekker, New York, pp. 1–146.
Carrott, P.J.M., Ribeiro Caixott, M.M.L., and Mays, T.J. (1998) Comparison of methods for estimating micropore sizes in active carbons from adsorption isothems, in F. Meunier (ed) Fundamentals of Adsorption 6, Elsevier, Paris, pp. 677–682.
Gregg, S.J., and Sing, K.S.W. (1982) Adsorption Surface Area and Porosity, 2nd. Edn., Academic Press, London.
Dubinin, M.M. (1989) Fundamentals of the theory of adsorption in micropores of carbon adsorbents, Carbon 27,457–467.
Stoeckli, F. (1998) Recent developments in Dubinin’s theory, Carbon 36,363–368.
Reference 4, pp. 132–152.
Alain, E., McEnaney, B., Mays, T.J., Strelko, V., and Kozynchenko, O. (1999) Synthetic carbons derived from lignosulphonate waste as new materils for gas storage. Ektended Abstracts,’ Carbon’ 99’, American Carbon Society, Charleston, SC., USA, pp. 630–631.
Reference 4, pp. 173–190.
McEnaney, B., and Mays, T. J. (1995) Characterisation of macroporosity in carbons, in J.W Patrick (ed) Porosity in Carbons, Edward Arnold, London, pp. 93–130.
McEnmey, B., Mays, T.J., Yin, Y.F., and Rodriguez-Reinoso, F. (1997) Estimating the dimensions of ultramicropores using molecule proles, In B. McEnaney et al (eds) Characterisation of Porous Solids-IV, Royal Society of Chemistry, Cambridge, pp. 125–132.
Dubinin M.M., and Stoeckli, F. (1980) Homogeneous and heterogeneom micropore sfructures in carbonaceous adsorbents, J. Colloid Interface Sci 75,34–42.
Horvath, G. and Kawazoe, K. (1983) Method for calculation of effective pore size distribution in molecular sieve carbon, J. Chem. Eng, Japan 16,470–475.
Stoeckli, F., Rebstein, P., and Ballerini, L. (1990) On fee assessmmt of microporosity in active carbons: a comparison of theoretical and experimental data, Carbon 28,907–909.
McEnaney, B., Mays, T.J., Chen, X. (1998) Computer simulations of adsorption processes in carbonaceous adsorbents, Fuel 77,557–562.
Seaton, N.A., Wdton, J.P.R.B., and Quirke, N. (1989) A new analysis method for the deteimination of the pore size distribution of porous carbons from nifrogen adsorption measurements, Carbon 27,853–861.
McEnaney, B., Mays, TJ., and Causton, P.D. (1987) Heterogeneous adsorption in microporous carbons, Langmuir 3,695–699.
Olivier, J.P., Conklin, W.B., and Szombathely M.v. (1994) Determination of pore size distribution from density functional theory: a comparison of nifrogen and argon results, In J. Rouquerol et al (eds) Characterisatim cf Poroms Solids III, Elsevier Science, Amsterdam, pp. 81–89.
Endo, M., Furate, T., Minoura. F., Kim, C., Oshida, K., Dresselhaus, G., and Dresselhaus, M.S. (1998) Visualized observation of pores in activated carbon fibers by HRTEM and combined image processor, Suprcmolecular Sci 5,261–266.
Valenzuela D.P. and Myers, A.L. (1989) Adsorption Equilibrium Data Handbook, Prentice Hall, New York.
Stoeckli, F., Wintgens, D., Lavmchy, A., and Stoeckli, M. (1997) Binary adsorption of vapours in airtive carbons described by the combined theories of Myers-Praunitz and Dubinin, Adsorption Sci. Tech. 15,677–683.
Burchell, T.D., Judkms, E.R., Rogers, M.R., and Willimis, A.M. (1997) A novel process for separation of carbon dioxide and hydrogm sulfide gas mixtures, Carbon 35,1279–1294.
Morgm, N. (1998) Cool chemistiy in a can, Chemustry in Britain, December, p. 17.
Juntgen, H. (1977) New applications for carbonaceous adsorbents, Carbon 15, 273–283.
Amor, J.N. and Farris, T.S. (1994) Mild crushing of carbon molecular sieves alters perfomance at the Angstrom level, Extended Abstracts ‘Carbon’ 94’, Spanish Carbon Group, Grana Spain, pp 324–325.
Chagger, H.K., Ndaji, F.E., Sykes, M.L., and Thomas, M.K. (1995) Kinetics of adsorption and diflftisional characteristics of carbon molecule sieves, Carbon 33, 1405–1411.
Koresh J.E. and Sofifer A. (1983) Molecular sieve carbon permselectivity membrane. Part 1. Presentation of a new device for gas mixture separation, Sep. Sci. Tech. 18, 723–734.
Rao M.B. and Sircar S. (1996) Performance and pore characterization of nanoporous carbon membranes for gas separation, J. Membrane Sci. 110 109–118.
Bromhead, J., Clint, J.H., Lear, A.M., Oliver, L.F., and Tennison, S.R. (1992) Membranes, European Patent 474 424 A2.
Hatori, H., Yamada, Y., Shiraishi, M., Nakata, H., Yoshitomo, S. (1992) Carbon molecular sieves from polyimide. Carbon 30,719.
Fuertes, A.B. and Centeno, T.A. (1998) Preparation of supported asymmetric carbon molecular sieve membrmes, J. Membrane Sci. 144,105–111.
Parkyns, N.D. and Quinn, D.F. (1995) Natural gas adsorbed on carbon, in J.W Patrick (ed) Porosity in Carbons, Edward Arnold, London, pp. 291–325.
Cook, T.L., Komodromos, C., Quinn, D.F., and Ragm, S. (1999) Adsorbent storage for natural gas vehicles, in T.D. Burchell (ed.), Carbon Materials for Advanced Technologies, Elsevier Science, Oxford, pp. 269–302.
Atimta Gas & Light Adsorbent Research Group (AGLARG) (1995) Final report on adsorbed natural gas research, GRI-95/0068, Gas Research Institute, USA
Matrmga, K.R., Myers, A.L., and Glandt, E.D. (1992) Storage of natural gas by adsorption on activated carbons, Chem. Eng. Sci. 47, 1569–1579.
Komodromos, C, Pearson, S., and Grint, A. (1992) The potential for adsorbed natural gas for advanced on-board storage in natural gas fuelled vehicles, International Gas Research Conference, Florida, USA.
Baker, F.S. (1995) Production of a highly microporous activated carbon product US Patent 5416056
Quinn, D.F. and MacDonald J.A. (1992) Natural gas storage. Carbon 30, 1097–1103.
Bose T., Chahine R., and St. Amaud, J.M. (1991) High density adsorbent and metiiod of producing same, US Patent 4999330.
Chen X.S., McEnmey, B., Mays, T.J., Alcmiz-Monge, J., Cazorla-Amoros, D., and Linares-Solano, A. (1997) Theoretical and experimental studies of methme adsorption on microporous carbons. Carbon 35,1251–1258
Burchell, T.D., Juikins, R.R., Rogers, M.R., and Shaw, W. (1998) The staidm-e and properties of carbon fiber based adsorbent monoliths, Proc International Symposium on Carbon, Japanese carbon Society, Tokyo, pp. 506–507.
Alcaniz-Monge, J., de la Casa Lillo, M.A., Cazorla-Amorós, D., and Linares-Solano, A. (1997) Methane storage in activated carbon fibres, Carbon 35,291–297.
Manzi S., Valladares, D., Marchese J., and Zgrablich, G. (1997) Characterization of Maxsorb acrtivated carbons and their evaluation for gas storage, Adsorption, Sci. Tech. 15,301–309.
Loano-Castelló, D., de la Casa Lillo, M.A., Cazorla-Anaorós, D., and Linares Solano, A. (1999) Methane storage at commercially attractive levels in superactivated carbons and commercial activated carbon fibers, (1999) Extended Abstracts ‘Carbon’ 99’, Americm Carbon Society, Charleston, SC, USA, 626–627.
Lipmm, T.E. and DeLucchi, M.A. (1996) Hydrogen-fuelled vehicles, Int. J. Vehicle Design 17,562–589.
Chahine R. and Bose, T.K. (1994) Low-pressure adsorption storage of hydrogen. Int, J. Hydrogen Energy 19,161–164.
Noh, J.S., Agarwal, R.K., and Schwarz, J.A. (1987) Hydrogen storage-systems using activated carbon. Int. J. Hydrogen Energy 12,693–700.
Dillon, A.C., Jones, K.M., Bekkedahl, T.A., Kimg, C.H., BeAune, D.S., and Heben, M.J. (1997) Storage of hydrogen in single-wdled carbon nanotubes. Nature 386,377–379.
Liu, C., Fm, Y.T., Liu, M., Cong, H.T., Cheng, H.M., and Dresselhaus, M.S. (1999) Hydrogen storage m single-walled cabon nanotubes at room temperature, Scieme 286,1127–1129.
Yin, Y.F., Mays, T., McEnmey, B. (1999) Hydrogen storage in carbon namnotube arrays, Ektended Abstracts ‘Carbon’ 99’, Americm Carbon Society, Charleston, SC, USA, pp. 784–785.
Chambers, A., Pat, C., Baker, R.T.K., and Rodriguez, N.M. (1998) Hydrogen storage in graphite nanofibers, J. Phys, Chem, B, 102,4253–4256.
Ahn, C.C., Ye, Y., Ratnakumar, B.V., Witham, C., Bowman Jr., R.C., and Fultz B. (1998) Hydrogen desoqition and adsorption measurements on graphite nanofibers, Appl. FAyi. Lett. 73,3378–3380.
Klyamkin, S.N., Metenier K., Sklovsky, D.E., Bonnamy, S., and Béguin, F. (1999) Carbon nanofilamrate under high hydrogen pressure, Extended Abstracts ‚Carbon’ 99‘, American Carbon Society, Charleston, SC, USA, pp. 628–629.
Fan, Y.Y., Liao, B., Liu, M., Wei, Y.L., Lu, M.Q., and Cheng, H.M. (1999) Hydrogen uptale in vapor-grown carbon nanofibers. Carbon 37,1649–1652.
Wang, Q. and Johnson, K.J. (1999) Computer simulations of hydrogen adsorption on graphite nanofibers, J.Phys. Chem. B, 103,277–281.
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McEnaney, B., Alain, E., Yin, YF., Mays, T.J. (2001). Porous Carbons for Gas Storage and Separation. In: Rand, B., Appleyard, S.P., Yardim, M.F. (eds) Design and Control of Structure of Advanced Carbon Materials for Enhanced Performance. NATO Science Series, vol 374. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1013-9_17
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DOI: https://doi.org/10.1007/978-94-010-1013-9_17
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