Abstract
Infrared luminescence spectra of Fe2+ in II-VI zinc-blende structures show more than 4 unequally spaced lines. To explain such experimental features, we introduce a Jahn-Teller coupling to acoustical phonons of E symmetry. We apply and compare two independent methods: Born-Oppenheimer’s and Lanczos’. Additionally we investigate the role of higher-order corrections such as spin-spin and third-order spin-orbit contributions to accurate calculation of energy levels. Details of the emission spectra of ZnS : Fe 2+, ZnSe : Fe 2+, ZnTe : Fe 2+, and CdTe : Fe 2+ are explained as due to a weak Jahn-Teller coupling which is enhanced when the energy of the coupling phonon is close to the spacing between electronic levels of appropriate symmetry.
Author deceased on May 27, 2000
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. Rivera-Iratchet, M.A. de Orúe, and E.E. Vogel, Phys. Rev. B 34, 3992 (1986).
L. Martinelli, G. Bevilacqua, J. Rivera-Iratchet, M.A. de Orúe, 0. Mualin, E.E. Vogel, and J. Cartes, Phys. Rev. B, scheduled for October 15, 2000.
C. Lanczos, J. Res. Ntl. Bur. Stand.45, 255 (1950)
C. Lanczos, J. Res. Ntl. Bur. Stand.49, 33 (1952)
C. Lanczos,Applied Analysis (Prentice-Hall, Englewood Cliffs, NJ, 1956).
R. Haydock, V. Heine, and M. J. Kelly, J. Phys. C 5, 2845 (1972)
R. Haydock, V. Heine, and M. J. Kelly, J. Phys. C8, 2591 (1975)
D. W. Bullet, R. Haydock, and M. J. Kelly, in Solid State Physics, edited by H. Erhenreich,, F. Seitz, and D. Turnbull (Academic, New York 1980), Vol. 35.
L. Martinelli, M. Passaro, and G. Pastori Parravicini, Phys. Rev. B 43, 8395 (1991)
L. Martinelli, M. Passaro, and G. Pastori Parravicini,Phys. Rev. B 39, 13343 (1989)
G. Grosso, L. Martinelli, and G. Pastori Parravicini, Phys. Rev. B 51, 13033 (1995).
F.S. Ham and G.A. Slack, Phys. Rev.B 4, 777 (1971).
G. Roussos, H.-J. Schulz, and M. Thiede, J. Lumin. 3l&32, 409 (1984).
E.E. Vogel, O. Mualin, H.-J. Schulz, and M. Thiede, Z. Phys. Ch. 201, 373 (1997).
E.E. Vogel, O. Mualin, M.A. de Orùe, J. Rivera-Iratchet, M.L. Flores, U.W. Pohl, H.-J. Schulz, and M. Thiede, Phys. Rev. B 50, 5231 (1994).
H.-J. Schulz, M. Thiede, U.W. Pohl, J. Rivera-Iratchet, M.A. de Orùe, M.L. Flores, O. Mualin, and E.E. Vogel, Z. Phys. B, 98, 215 (1995).
G.A. Slack, S. Roberts, and F.S. Ham, Phys. Rev. 155, 170 (1967).
A. Twardowski, X.C. Liu, D. Heiman, Y. Shapira, R. Kershaw, K. Dwight, and A. Wold, Solid State Commun. 89, 245 (1994).
C. Testelin, C. Rigaux, A. Mauger, A. Mycielski, and C. Julien, Phys. Rev. B 46, 2183 (1992).
G.A. Slack, S. Roberts, and J.T. Vallin, Phys. Rev. 187, 511 (1969).
J.T. Vallin, Phys. Rev. B 2, 2390 (1970).
C.E. Moore, Atomic Energy Levels, Nat. Bur. Stand. (U.S.) Circ. No. 467 (U.S. GPO, Washington, D.C., 1949); Vol. II (U.S. GPO, Washington, D.C., 1952).
I.B. Bersuker and V.Z. Polinger, Vibronic Interactions in Molecules and Crystals (Wiley, New York,1989).
M. Villeret, S. Rodriguez, and E. Karthauser, Physica B 162, 91 (1990).
E.E. Vogel and J. Rivera-Iratchet, Phys. Rev. B 22, 4511 (1980);
E.E. Vogel, 0. Mualin, M.A. de Orùe, and J. Rivera-Iratchet, Phys. Rev. B 44 1579 (1991).
V. Savona, F. Bassani, and S. Rodriguez, Phys. Rev. B 49, 2408 (1994).
L. Martinelli, M. Passaro, and G. Pastori Parravicini, Phys. Rev. B 40, 10443 (1989).
G. Bevilacqua, L. Martinelli, M.A. de Orùe, J. Rivera-Iratchet, and E.E. Vogel, proceedings of the “XIV International Symposium on Electron-Phonon Dynamics and Jahn-Teller Effect”, Erice-Italy, 7–13 July 1998, edited by G. Bevilacqua, L. Martinelli, and N. Terzi (World Scientific, Singapore 1999), pag.178.
G. Russo, Thesis (1998), University of Pisa.
R.E. Watson and M. Blume, Phys. Rev. 139, A1209 (1965).
B. Hennion, F. Moussa, G. Pepy, and K. Kunc, Phys. Lett. 36A, 376 (1971).
N. Vagelatos, D. Wehe, and J. King, J. Chem. Phys. 60, 3613 (1974).
J.M. Rowe, R.M. Nicklow, D.L. Price, and K. Zanio, Phys. Rev. B 10, 671 (1974).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2001 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Bevilacqua, G. et al. (2001). Fine Interactions and the Jahn-Teller Effect in Luminescence of FE 2+ in II-VI Compounds. In: Kaplan, M.D., Zimmerman, G.O. (eds) Vibronic Interactions: Jahn-Teller Effect in Crystals and Molecules. NATO Science Series, vol 39. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0985-0_48
Download citation
DOI: https://doi.org/10.1007/978-94-010-0985-0_48
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-0045-4
Online ISBN: 978-94-010-0985-0
eBook Packages: Springer Book Archive