Abstract
The excitons, localized states in crystalline and glassy silicon dioxide, germanium dioxide were studied by photoluminescent and photoelectric experimental methods. Results were compared with analogous investigations of related crystals, such as aluminum and gallium orthophosphates, and of related glasses, such as silica, sodium silicates, germanates, lead and phosphates glasses. Special attention was made to the influence of oxygen deficiency on localized states of glasses, in general, and to the nature of the 7.6 eV band in reduced silica, in particular.
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References
Knox, R. (1963) Theory of Excitons, New-York, Academic Press
Agranovich, V.M. (1968) Theory of Excitons, Moskwa, Nauka.
Lushchik, Ch.B. (1982) Excitons In Solids, Sturge, North Holland.
Song, K.S. Williams, R.T. (1992) Self-trapped excitons. Springer-Verlag.
Trukhin, A.N. (1992) Excitons in SiO2: a review, J.Non-Crystalline Solids 149, 32–35.
Sumi, A. (1977) Phase diagram of an exciton in the phonon field, J.Phys.Soc. Japan, 43,1286.
Toyozawa, Y.A. (1964) The Urbach rule and the exciton-lattice interaction, Techn. Report. ISSP, Al, 119–168.
Philipp, H.R.(1966) Optical transitions in crystalline and fused quartz, Solid State Commun. 4, 73–75.
Pajasova, L. (1969) Optical properties of GeO2 in the ultraviolet region, Czech. J. Phys., B19, 1265–1270.
Zallen, R. (1983). Physics of Amorphous Solids, New York, John Willey&sons.
Kink, R.A. Lohmus, A.E. (1976) Exciton states in crystalline Xe, Fizika nizkikh temperatur, 2, 277–280.
Trukhin, A.N. Silin, A.R. and Zakis, J.R. (1988) Comparison of electronic excitations and of luminescence in glassy and crystalline silicon dioxide, Izvestia Akademii Nauk SSSR (Report of Sov.Academy of Science) 52, 697–702.
Weinberg Z., Rubloff., G.W. Bassous, E. (1979) Transmission, photoconductivity, and experimental band gap of thermally grown SiO2 film, Phys.Rev. 19, 3107–3117.
Trukhin, A.N. (1982) Model of excitons in SiO2, Fiz.Tverdogo Tela (Sov.Sol.St.Phys.) 24, 993–997.
Trukhin, A.N. (1980) Study of exciton in SiO2. Luminescent centers as exciton detector Phys.Stat.Solidi, b, 98, 541–550.
Godmanis, I.T. Trukhin, A.N. and Hubner, K. (1983) Exciton-phonon interaction in crystalline and vitreous SiO2, Phys.Stat.Sol b, 116, 279–287.
Itoh, C. Tanimura, K. Itoh, N. Itoh, M. (1989) Threshold energy for photogeneration of self-trapped excitons in SiO2, Phys. Rev. B 39, 11183–11186.
Reily, M. (1970) Remperature dependence of the short wavelength transmittance limit of vacuum ultravioler window materials, J.Phys.Chem. Sol, 31 1041–1056.
Pantelides, S.T. (1978) the optical absorption spectrum of SiO2, The Physics of SiO2 and its Interfaces, ed.S.T. Pantelides, Pergamon Press
Trukhin, A.N. (1993) Luminescence of a self-trapped exciton in GeO2 crystal, Solid State Communication 85, 723–728.
Trukhin, A.N. (1994) Evidences of the self-trapped excitons in GaPO4 and A1PO4 crystals, Solid State Communication 90, 795–80.
V. Puchin, (1994). Ab intio calculations of AIPO4 crystals band straucture, privat communications.
Griscom, D.L. (1979) Point defests and radistion damage pricesses in a—quartz, 32nd Freq.Control Symp. Electr. Indust Assn., W-DC, p.98–108.
Hayes, W. Kane, M.J. Salminen, O. Wood, R.L. Doherty, S.P. (1984) ODMR of recombination centers in crystalline quartz, J.Phys.C, 17,2943–2951.
Trukhin, A.N. (1986) A host and an impurity luminescence of crystalline quartz, Fizika Tverdogo Tela (Sov.Sol St.Phys.) 28, 1460–1464.
Hayes, W., Jenkin, T.J.L (1985) Paramagnetic hole centers produced in germanium-doped crystalline quartz by x-irradiation at 4 K, J.Phys.C: Sol.St.Phys., 21, 2391–2399.
Griscom, D.L. (1992) Electron spin resonance characterization of self-trapped holes in amorphous silicon dioxide, J..Non-Crystalline Solids 149, 137–160.
Trukhin, A.N. Rogulis, U. Spriniis, M. (1997) Self-trapped excitons in Li2GeO3, Journal of Luminescence, 72-74, 890–892.
Trukhin, A.N., (1991) Luminescence kinetics in crystalline and glassy silicon dioxide, J. of Applied Spectroscopy (in Russian), 55, 800–805.
Higashi, G.S. Kastner, M. (1979) Charged defect-pair luminescence in a-As2S3, J.Phys.C 12 L821–L826.
Trukhin, A.N. (1987) Temperature dependence of luminescence decay kinetics of self-trapped excitons, germanium and aluminum centers in quartz Phys. Stat.Solidi (b), 142, K83–K88.
Shluger, A.L. and Stefanovich, E. (1990) Models of the self-trapped exciton and nearest-neighbor defect pair in SiO2. Phys. Rev., B42, 9664–9673.
Fisher, A.J. Hayes, W. and Stoneham, A.M., (1990) Structure of the self-trapped exciton in quartz, Phys. Rev.Letters, 64, 2667–2670.
Itoh, C. Tanimura, K. Itoh, N. (1998) Optical studies of self-trapped excitons in SiO2, J. Phys. C: Solid State Phys. 21, 4693–4702.
Trukhin, A.N. (1991) Luminescence of the self-trapped exciton in crystalline and glassy silicon dioxide, Soviet Solid State Physics, 33, 2888–2895.
Trukhin, A.N. (1994) Self-trapped exciton luminescence in α-quartz, Nuclear Instruments am Methods in physics research, B 91, 334–337.
Anderson, P.W. (1958) Absence of diffusion in certain random lattices, Phys.Rev. 109, 1492–1503.
Mott, N.F. Davis, E.A. (1971) Electronic processes in non-crystalline materials, Oxford.
Glebov, L.B. Popova, L.B. Tolstoi, M.N. Rusan, V.V. (1976) Preparation of high purity sodium-silicate glasses, Sov. Phys. Chem. Glasses, 2, 569–571.
Gelmont, B.L. Perel, V.I. Jassievich, I.N. (1983) About Urbach rule, Sov.Sol.State Phys. 25 727–733.
Mackey, Y.H. Smith, H.L. Halperin, A. (1966) Optical studies in X-radiated high purity sodium-silicate glasses, J.Phys.Chem. Sol. 17, 1759–1772.
Trukhin, A.N. Rudenko, V.S. (1987) Investigation of the spectral kinetic properties of luminescence centers created by non-bridging oxygen and one valent metal ion, Sov. Phys.Chem.Glasses, 13, 236–241.
Skuja, L.N. Silin, A.R. Boganov, A.G. (1984) On the nature of the 1.9 eV luminescence centers in amorphous SiO2 J.Non-Crystalline Solids, 63, 431–436.
Trukhin, A.N. L.B. Glebov, O.S. Schavelev, A.G. Golovin, (1991) Investigation of Fluorescence and Phosphorescence of Glasses under X-ray Excitation, (Annual Report, Riga, University of Latvia,) p. 10–43.
Glebov, L.B. Plukhin, A.G. Raaben, E.L. Tolstoi, M.N. Trukhin, A.N. (1990) Luminescence of lead in silicate glasses, Phys.Chem. Glass.(Sov.) 16, 245–252.
Trukhin, A.N. (1990) Localized states of silicon dioxide, sodium and leadsilicate glasses J.Non-Cryst.Sol. 123, 250–257.
Grabovskis, V.J. Dzenis, J.J. Kovaleva, N.S. Tolstoi, M.N. (1990) Intrinsic absorption and luminescence of phosphate glasses, Solid State Physics (Sov), 32, 2953–2959.
Trukhin, A.N. Kûlis, P.A. (1995) Localized states in germanate glasses. Ultraviolet absorption tail of crystalline and glassy germanium dioxide and alkali germanate. Journal of Non-Crystalline Solids, 188, 125–129.
Stapelbroek, M. Evans, B.D. (1978) Exciton structure in the UV. Absorption edge of tetragonal GeO2. Sol. St. Commun. 25 959–962.
Trukhin, A.N. (1995) Localized states in germanate glasses. Study of luminescence, Journal of Non-Crystalline Solids, 189, 291–296.
Skuja, L.N. (1989) Photoluminescence of intrinsic defects in glassy GeO2. Twofold coordinated Ge and Non-bridging oxygen, Phys.Stat.Sol. (a), 114, 731–737.
Bohm, H. (1970) On the thermoluminescence of vitreous GeO2, Phys.Chem.Glass. 11, 177.
Nelson, C.M. and Weeks, R.A. (1961) Vacuum-ultraviolet absorption studies of irradiated silica and quartz, J.Appl.Phys. 32, 883–886.
Zakis, J.R. and Trukhin, A.N. (1973) Photoluminescence of quartz excited by vacuum-ultraviolet radiation, Scientific Reports of the Latvian University, 182, 50–54.
Trukhin, A.N. Boganov, A.G. Praulinsh, A.M. (1979) On the nature of the 395 and 280 nm luminescence centers in glassy SiO2, Phys.Chem. Glass.(Sov.) 6, 346–353.
Skuja, L.N. Streletsky, A.N. Pakovich, A.B. (1984) A new intrinsic defect in amorphous SiO2, Solid State Commun. 50, 1069–1072.
Skuja, L.N. Trukhin, A.N. Plaudis, A.E. (1984) Luminescence in germanium-doped glassy SiO2, Phys.Stat.Sol.(a) 84, K153–K157.
Gee, CM. Kastner, M. (1979) Intrinsic-defect photoluminescence in amorphous SiO2, Phys.Rev.Lett. 42,1765–1769.
Tohmon, R. Mizuno, H. Ohki, Y. Sagane, K. Nagasawa, K. Hama, Y. (1989) Correlation of the 5.0-and 7.6 absorption bands in SiO2 with oxygen vacancy, Phys.Rev. 39, 1337–1344.
Boganov, A.G. Dianov, E.M. Kornienko, L.S. Nikitin, E.P. Rudenko, V.S. Rybaltovsky, A.O. Chernov, P.V. (1977) Water-free silica glass for optical fibers and radiation and optical properties, Quantum Electronics (Sov.) 4, 996–1003.
Skuja, L. (1998) Optically active oxygen-deficiency-related centers in amorphous silicon dioxide, J.Non-Crystalline Solids, 239 16–48.
Griscom, D. L. (1997) Visible/Infra-red absorption study in fiber geometry of metastable defect states in high-purity fused silicas, Material Science Forum Volumes, 239-241, 19–24.
Trukhin, A.N. (1995) Localized states in wide gap glasses. Comparison with relevant crystals, J.Non-Crystalline Solids, 189, 1–15.
Xu, Y. Ching, W. Y. (1991) Electronic and optical propertiex of all polymorphic forms of silicon dioxide, Phys. Rev. 44, 11048–11059.
Trukhin, A.N. Fitting, H.-J. (1997) Investigation of optical and radiation properties of oxyged deficient silica glasses, Bragg Gratings, Photosensitivity, and Poling in Glass fibers and Waveguides: Applications and Fundamentals, Topical Meeting of the Optical Society of America OSA, Williamsburg USA, Oct., technical digest series volum 17, p.89–91.
Trukhin, A.N. Fitting, H.-J. (1999) Investigation of optical and radiation properties of oxygen deficient silica glasses, J.Non-Crystalline Solids, 248, 49–64.
Trukhin, A.N. Skuja, L.N. Boganov, A.G. Rudenko, V.S. (1992) The correlation of the 7.6 eV optical absorption band in pure fused silicon dioxide with twofold-coordinated silicon, J.Non-Crystalline Solids, 149, 96–101.
Imai, H. Arai, K. Imagawa, H. Hosono, H. Abe. Y. (1988) Experimental evidence for Si-Si bond model of the 7.6-eV band in SiO2 glass, Phys. Rev. B 38, 12772–12775.
Trukhin, A.N. Fitting, H.-J. Barfels, T. von Czarnovski, A. (1999) Cathodoluminescence and IR absorption of oxygen deficient silica—influence of hydrogen treatment, Journal of Non-Crystalline Solids, 260, 132–140.
Shelby J.E., (1994) Protonic species in vitreous silica, in R.A. Weeks Symposium volume of J.Non-Crystalline Solids, 179, 138–147.
Imai, H. Arai, K. Hosono, H. Abe, Y. Arai, T. Imagawa, H. (1991) Dependence of defects induced by excimer laser on intrinsic structural defects in synthetic silica glasses, Phys. Rev. B 44, 4812–4818.
Silin, A.R. Trukhin, A.N. (1985) Elementary Electronic Excitations and Point Defects in Crystalline and Glassy SiO2, Zinatne Press, Riga.
Goldberg, M. Trukhin, A.N. Fitting, H.-J. (1996) Dose effects of cathodoluminescence in SiO2 layers on Si, Material Science&Engineering B 42, 293–296.
Goldberg, M. Fitting, H.-J. Trukhin, A.N. (1997) Cathodoluminescence and cathodoelectroluminescence of amorphous SiO2, J.Non-Crystalline Solids, 220, 69–77.
Trukhin, A.N. Goldberg, M. Jansons, J. Fitting, H.-J. Tale, I.A. (1998) Silicon dioxide thin film luminescence in comparison with bulk silica, J.Non-Crystalline Solids, 223, 114–122.
Miller, A.J. Leisure, R.G. Austin, W.R. (1999) X-ray induced luminescence of high-purity, amorphous silicon dioxide, Journal of Applied Physics, 86, 2042–2050.
Skuja, L. (1994) The origin of the intrinsic 1.9 eV luminescence band in glassy SiO2, J.Non-Crystalline Solids, 179, 51–69.
A.N. Trukhin, H.-J. Fitting, T. Barfels, A. Veispals, (1999) Defect luminescence study in tetragonal GeO2 crystals, Defects and surface induced effects in advanced provskites., Ed.G. Borsel, A. Krumins, D. Miller, Kluwer Academic Publisher, 379–386.
Garino-Canino, V. (1956) La band d’absorption à 242 nm de la silice vitreuse, Compte Rendue, 242, 1982–1984.
Trukhin, A.N. Poumellec, B. Garapon, J. (1999) Luminescence decay kinetics of Ge related center in silica, Radiation Effects and Defects in Solids, 149, 89–95.
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Trukhin, A.N. (2000). EXCITONS, LOCALIZED STATES IN SILICON DIOXIDE AND RELATED CRYSTALS AND GLASSES. In: Pacchioni, G., Skuja, L., Griscom, D.L. (eds) Defects in SiO2 and Related Dielectrics: Science and Technology. NATO Science Series, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0944-7_8
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