Abstract
Non-crystalline materials, which include some inorganic and organic glasses, are characterized by lack of long range order. This fact is responsible for lots of physical and chemical properties, which opens broad possibility for technical applications. Glasses show glass transition, relaxation effects and crystallization under heat treatment with very similar phenomenological peculiarities. Attention has been paid to effects called physical aging. The study of molecular reorganization during aging has not only fundamental scientific importance but it can have an impact on possible technological advances in material science and engineering.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Cortés, P., Montserrat, S. (1989) Effect of previous thermal history on physical aging of poly(ethylenterephtalate), Makromol.Chem.Macromol Symp. 27, 279–287.
Ichikawa, K., (1992) The effect of annealing on the structure of Ge20Te80 glass: atomic-scale imaging using a scanning tunneling microscope, J.Non-Ctyst Solids 150,435-439.
Malek, J. (1998) Dilatometric study of structural relaxation in arsenic sulfide glass, Thermochim. Acta 311, 183–198.
Ribelles, J.L.G, Garayo, A.V., Cowie, J.M.G., Ferguson, R., Harris, S., McEwen, I.J. (1998) The length of cooperativity at the glass transition in poly(vinyl acetate) from the modeling of the structural relaxation process, Polymer 40, 183–192.
Brophy, J.H., Rose, M.R., Wulff, J. (1967) Structure and Properties of Materials: Volume II Thermodynamic of Structure, John Wiley & Sons, New York.
Henderson, D.W., Ast, D.G. (1984) Viscosity and crystallization kinetics of As2Se3, J. Non-Cryst. Solids 64, 43–70.
Brophy, J.H., Rose, R.M., Wulff, J. in: Structure and Properties of Materials, vol. II, Thermodynamics of Structure, John Wiley & Sons, New York (1967), 106.
Mora, M.T. Chalcogenide glasses in: M.F. Thorpe, M.I. Mitkova, (eds.), Amorphous Insulators and Semiconductors NATO ASI Series, vol 23, Kluwer Academic Publishers, London (1997), pp. 45–69.
Málek, J. (1995) The applicability of Johnson-Mehl-Avrami model in the thermal analysis of the crystallization kinetics of glasses, Thermochim. Acta 267 61–73.
Wagner, C, Vázques, J., Dominguez, M., Villares, P., Jiménez-Garay, R. (1996) Analysis of the crystallization kinetics in the semiconducting glassy alloy Cuo.2oAso.35Teo 45, Materials Chemistry and Physics 43, 227–232.
Christian, J.W. (1975) The Theory of Transformation in Metals and Alloys, 2nd Edition, Pergamon Press, London.
Henderson, D.W. (1979) Experimental analysis of non-isothermal transformations involving nucleation and growth, J. Therm Anal. 15, 325–331.
Yinnon, H.S., Uhlmann, D.R. (1983) Applications of thermoanalytical techniques to the study of crystallization kinetics in glass-forming liquids. Parti: Theory, J.Non.-CrystSolids 54, 253–275.
Avrami, M. (1939) Kinetics of phase change L, J.Phys.Chem. 7, 1103–112.
Avrami, M. (1939) Kinetics of phase change H, J.Phys.Chem. 8, 212–224.
Sestak, J., Berggren, G. (1971) Study of kinetics of mechanism of solid state reactions at increasing temperature, Thermochim. Acta 3, 1–7.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2001 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Černošková, E., Černošek, Z., Holubová, J. (2001). Thermal Properties Studied on As2Se3 Model Glass. In: Thorpe, M.F., Tichý, L. (eds) Properties and Applications of Amorphous Materials. NATO Science Series, vol 9. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0914-0_5
Download citation
DOI: https://doi.org/10.1007/978-94-010-0914-0_5
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-6811-3
Online ISBN: 978-94-010-0914-0
eBook Packages: Springer Book Archive