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Towards a better understanding and terminology of the Oxide / Transition Metal Complex interactions

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Catalysis by Unique Metal Ion Structures in Solid Matrices

Part of the book series: NATO Science Series ((NAII,volume 13))

Abstract

The present review aims at clarifying some points of terminology regarding the interactions of transition metal ion complexes (TMCs) and transition metal ion ions (TMIs) with oxide matrices, with special emphasis on their relevance to the preparation of supported metal catalysts. As we will show, the current use of vocabulary is sometimes confused or misleading and would benefit from some systematisation. In particular, a sound reasoning on TMC/oxide systems should carefully distinguish between operations carried out at the macroscopic level (such as catalyst preparation procedures) and their consequences at the molecular level, i.e., processes such as diffusion and chemical reactions with the surface, and the states (either stable or metastable) of TMCs resulting from such processes.

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Authors and Affiliations

  1. Laboratoire de Réactivité de Surface (UMR7609 CNRS), Université Pierre et Marie Curie, Paris, France

    J. F. Lambert & M. Che

  2. Institut Universitaire de France, France

    M. Che

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  1. J. F. Lambert
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  2. M. Che
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Editors and Affiliations

  1. University of Messina, Messina, Italy

    Gabriele Centi

  2. Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Blanka Wichterlová

  3. University of California at Berkeley, Berkeley, CA, USA

    Alexis T. Bell

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Lambert, J.F., Che, M. (2001). Towards a better understanding and terminology of the Oxide / Transition Metal Complex interactions. In: Centi, G., Wichterlová, B., Bell, A.T. (eds) Catalysis by Unique Metal Ion Structures in Solid Matrices. NATO Science Series, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0782-5_1

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  • DOI: https://doi.org/10.1007/978-94-010-0782-5_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6875-5

  • Online ISBN: 978-94-010-0782-5

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