Skip to main content

Part of the book series: NATO Science Series ((NAII,volume 10))

Abstract

We present the technique of scanning polarization force microscopy (SPFM), which is based on the use of electrostatic forces in an atomic force microscope. Although, traditionally, electrostatic forces have been used only for imaging of electrically conductive substrates (metal and doped semiconductors), it can be used on insulating materials as well. This is because the electric field at the sharp tip of a conductive AFM cantilever (biased relative to a remote ground) is strong and polarizes the substrate to create an image charge that depends on the local dielectric properties. We will show applications of SPFM to studies of wetting and spreading of various liquids, in particular, the lubricants used in computer hard disks.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Belaidi, S., Lebon, F., Girard, P., Leveque, G. and Pagano, S. (1998), “Finite element simulations of the resolution in electrostatic force microscopy”, Appl. Phys. A 66, S239–S243.

    Article  CAS  Google Scholar 

  • de Gennes, P.G. (1985), “Wetting: statistics and dynamics”, Rev. Mod. Phys. 57, 827–863.

    Article  Google Scholar 

  • Derjaguin, B.V., Churaev, N.V. and Muller, V.M. (1987), Surface Forces, Consultants Bureau, New York.

    Google Scholar 

  • Hao, W.H., Baro, A.M. and Saenz, J.J. (1991), “Electrostatic and contact forces in force microscopy”, J. Vac. Sci. Technol. B 9, 1323–1328.

    Article  Google Scholar 

  • Hu, J., Carpick, R.W., Salmeron, M. and Xiao, X.-D. (1996), “Imaging and manipulation of nanometer size liquid droplets by scanning polarization force microscopy”, J. Vac. Sci. Technol. B14, 1341–1343.

    Google Scholar 

  • Hu, J., Xiao, X.D. and Salmeron, M. (1995a), “Scanning polarization force microscopy: A technique for imaging liquids and weakly adsorbed liquids”, Appl. Phys. Lett. 67, 476–478.

    Article  CAS  Google Scholar 

  • Hu, J., Xiao, X.D., Ogletree, D.F. and Salmerón, M. (1995b), “Imaging the condensation and evaporation of molecularly thin films of water with nanometer resolution”, Science 268, 267–269.

    Article  CAS  Google Scholar 

  • Kim, H.I., Mate, CM., Hannibal, K.A. and Perry, S.S. (1999), “How disjoining pressure drives the dewetting of a polymer film on a silicon surface”, Phys. Rev. Lett. 82, 3496–3499.

    Article  CAS  Google Scholar 

  • Luna, M., Colchero, J. and Baro, A.M. (1999), “Study of Water Droplets and Films on Graphite by Noncontact Scanning Force Microscopy”, J. Phys. Chem. B 103, 9576–9581.

    Article  CAS  Google Scholar 

  • Luna, M., Rieutord, F., Melman, N.A., Dai, Q. and Salmeron, M. (1998), “The adsorption of water on alkali halides surfaces studied by scanning polarization force microscopy”, J. Phys. Chem. A 102, 6793–6800.

    Article  CAS  Google Scholar 

  • Martin, Y., Abraham, D.W. and Wickramasinghe, H.K. (1988), “High-resolution capacitance measurement and potentiometry by force microscopy”, Appl. Phys. Lett. 52, 1103–1105.

    Article  Google Scholar 

  • Pompe, T., Fery, A. and Herminghaus, S. (1999), “Measurement of contact line tension by analysis of the three-phase boundary with nanometer resolution”, J. Adhes. Sci. Technol. 13, 1155–1164.

    Article  CAS  Google Scholar 

  • Pompe, T., Fery, A. and Herminghaus, S. (1998), “Imaging liquid structures on inhomogeneous surfaces by scanning force microscopy”, Langmuir 14, 2585–2588.

    Article  CAS  Google Scholar 

  • Salmeron, M., Xu, L., Hu, J. and Dai, Q. (1997), “High resolution imaging of liquid structures: Wetting and capillary phenomena at the nanometer scale”, MRS Bull. 22, 36–41.

    CAS  Google Scholar 

  • Schoenenbergher, C. and Alvarado, S.F. (1990), “Observation of single charge carriers by force microscopy”, Phys. Rev. Lett. 65, 3162–3164.

    Article  Google Scholar 

  • Sheiko, S., Lermann, E. and Möller, M. (1996), “Self-Dewetting of Perfluoroalkyl Methacrylate Films on Glass”, Langmuir 12, 4015–4024.

    Article  CAS  Google Scholar 

  • Valignat, M.P., Villette, S., Li, J., Barberi, R., Bartolino, R., Dubois-Violette, E. and Cazabat, A.M. (1996), “Wetting and anchoring of a nematic liquid crystal on a rough surface”, Phys. Rev. Letters 77, 1994–1997.

    Article  CAS  Google Scholar 

  • Xu, L., Ogletree, D.F., Salmeron, M., Tang, H., Gui, J. and Marchon, B. (2000a), “De-wetting of lubricants on hard disks”, J. Chem. Phys. 112, 2952–2957.

    Article  CAS  Google Scholar 

  • Xu, L. and Salmerón, M. (2000b), “Wetting and capillary phenomena at nanometer scale with scanning polarization force microscopy”, in Nano-Surface Chemistry (M. Rosoff, ed.), Marcel Dekker, New York. In press.

    Google Scholar 

  • Xu, L., Salmerón, M. and Bardon, S. (2000c), “Wetting and molecular orientation of 8CB on silicon substrates”, Phys. Rev. Lett. 84, 1519.

    Article  CAS  Google Scholar 

  • Xu, L. and Salmeron, M. (1998a), “Scanning polarization force microscopy study of the condensation and wetting properties of glycerol on mica”, J. Phys. Chem. B 102, 7210–7215.

    Article  CAS  Google Scholar 

  • Xu, L., Lio, A., Hu, J., Ogletree, D.F. and Salmerón, M. (1998b), “Wetting and capillary phenomena of water on mica”, J. Phys. Chem. B 102, 540–548.

    Article  CAS  Google Scholar 

  • Xu, L. and Salmeron, M. (1998c), “An XPS and scanning polarization force microscopy study of the exchange and mobility of surface ions on mica”, Langmuir 14, 5841–5844.

    Article  CAS  Google Scholar 

  • Yokoyama, H., Jeffery, M.J. and Inoue, T. (1993), “Heterodyne force-detection for high frequency local dielectric spectroscopy by scanning Maxwell stress microscopy”, Japanese Journal of Applied Physics 32, LI 845–1848, 1993.

    Google Scholar 

  • Zenhausern, F., Martin, Y. and Wickramasinghe, H.K. (1995), “Scanning interferometric apertureless microscopy: optical imaging at 10 angstrom resolution”, Science 269, 1083–1085.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2001 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Salmeron, M. (2001). Nanoscale Wetting and De-Wetting of Lubricants with Scanning Polarization Force Microscopy. In: Bhushan, B. (eds) Fundamentals of Tribology and Bridging the Gap Between the Macro- and Micro/Nanoscales. NATO Science Series, vol 10. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0736-8_49

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0736-8_49

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6837-3

  • Online ISBN: 978-94-010-0736-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics