Abstract
Accelerated catalyst development and its basis on combinatorial as well on experimental procedures and fundamentals has been already described elsewhere (see e. g. [1]). The development of new catalytic materials occurs still mainly on an empirical basis although significant progress has been made in the fundamental understanding of catalysis. Nevertheless, it is still not possible to design a catalyst “ab initio” predicting its required composition and its resulting activity and selectivity for a given reaction; this is particularly true for heterogeneous multi-compounds catalysts.
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References
Buyevskaya, O.V., Brückner, A., Kondratenko, E.V., Wolf, D. and Baerns, M. (2001) Fundamental and combinatorial approaches in the search for and optimisation of catalytic materials for the oxidative dehydrogenation of propane to propene, Catalysis Today 67, 369–378.
Wolf, D. Buyevskaya, O.V. and Baerns, M. (2000) An evolutionary approach in the combinatorial selection and optimisation of catalytic materials, Applied Catalysis A: General 200,63–77.
Buyevskaya, O.V., Wolf, D. and Baerns, M. (2000) Ethylene and propene by oxidative dehydrogenation of ethane and propane—performance of rare-earth oxide-based catalysts and development of redox-type catalytic materials by combinatorial methods, Catalysis Today 62,91–99.
Schultz, P. G., Xiang, X. and Goldwasser, I. (1996) The Combinatorial Synthesis of Novel Materials, WO 96/11878.
Danielson, E., Golden, J. H., Mc Farland, E., Reaves, C. M, Weinberg, W. H. and Wu, X. D. (1997) A combinatorial approach to the discovery and optimisation of luminescent materials, Nature 389,944.
Reddington, E., Sapienza, A., Gurau, B., Viswanathan, R., Sarangapani, S., Smotkin, E. S. and Mallouk, T. E. (1998) Combinatorial electrochemistry: a highly parallel, optical screening method for discovery of better electrocatalysts, Science 280,1735.
Senkan, S.M. (1998) High-throughput screening of solid-state catalyst libraries, Nature 394,350–352.
Senkan, S., Krantz, K., Ozturk, S., Zengin V. and Onal, I. (1999) Hochdurchsatz-Screening von Heterogenkatalysator-Bibliotheken unter Verwendung eines Mehrkammerreaktorsystems und der Massenspektroskopie, Angewandte Chemie 111,2965; (1999) Angewandte Chemie Int Ed. Engl.38,2794.
Rodemerck, U., Wolf, D. Buyevskaya, O.V., Claus, P., Senkan, S. and Baerns, M. (2001) High-throughput synthesis and screening of catalytic materials—Case study on the search for a low-temperature catalyst for the oxidation of low-concentration propane, Chemical Engineering Journal 82,3–11.
Kung, H.H. (1994) Oxidative dehydrogenation of light (C2-C6) alkanes, Adv. Catal., 40,1.
Mamedov, E.A. and Cortes Corberan, V. (1995) Oxidative dehydrogenation of lower alkanes on vanadium oxide-based catalysts: The present state of the art and outlooks, Applied Catalysis A: General 127,1.
Moro-oka, Y. and Ueda, W. (1994) Catalysis 11:Specialist Periodical Reports, Chapter 6.Royal Society of Chemistry, Cambridge, UK.
Cavani, F. and Trifiro, F. (1995) The oxidative dehydrogenation of ethane and propane as an alternative way for the production of light olefins, Catalysis Today 24,307.
Banares, M. A. (1999) Supported metal oxide and other catalysts for ethane conversion: a review, Catalysis Today 51, 319–348.
Spivey, J.J. (1989) Complete catalytic oxidation of volatile organics, Catalysis 8, 157.
Zwinkels, M.F.M., Järås, S.G. and Menon, P.G. (1993) Catalytic materials for high-temperature combustion, Catal. Rev.-Sci. Eng. 35, 319.
Moro-oka, Y., Morikawa, Y. and Ozaki, A. (1967) Regularity in the catalytic properties of metal oxides in hydrocarbon oxidation, Journal of Catalysis 7, 23.
Yu Yao, Y.-F. (1980) Oxidation of alkanes over noble metal catalysts, Ind. Eng. Chem. Prod. Res. Dev. 19, 293.
Herrmann, J.-M., Hoang-Van, C., Dibansa, L., and Harivololona, R. (1996) An in situ electrical conductivity study of a CeO2 aerogel supported palladium catalyst in correlation with the total oxidation of propane, Journal of Catalysis 159, 361.
Schlangen, A., Neuhaus, G.W., Madani, M. and Maier, W.F. (1992) Unterschiede in der Totaloxidation organischer Verbindungen an heterogenen Platin-und Palladiumkatalysatoren, J. prakt. Chem. 334, 465.
O’Malley, A. and Hodnett, B.K. (1999) The influence of volatile organic compound structure on conditions required for total oxidation, Catalysis Today 54, 31.
Bucsa, G., Daturi, M.; Finocchio, E., Lorenzelli, V., Ramis, G. and Willey, R.J. (1997) Transition metal mixed oxides as combustion catalysts: preparation, characterization and activity mechanisms, Catalysis Today 33, 239.
Seyama, T. (1992) Total oxidation of hydrocarbons on perowskite oxides, Catal. Rev. Sci. Eng. 34, 281.
Kalantar Neyestanaki, A., Kumar, N. and Lindfors, L.-E. (1995) Catalytic combustion of propane and natural gas over Cu and Pd modified ZSM zeolite catalysts, Applied Catalysis B: Environmental 7, 95.
Ishikawa, A., Komai, S., Satsuma, A, Hattori, T. and Murakami, Y. (1994) Solid superacid as the support of a platinum catalyst for low-temperature catalytic combustion, Applied Catalysis A: General 110, 61.
Waters, R.D., Weimer, J.J. and Smith, J.E. (1995) An investigation of the activity of coprecipitated gold catalysts for methane oxidation, Catalysis Letters 30, 181.
Pfefferle, L.D. and Pfefferle, W.C. (1987) Catalysis in combustion Catal. Rev.-Sci. Eng. 29, 219.
Rodemerck, U., Ignaszewski, P., Lucas, M. and Claus, P. (2000) Parallel synthesis and fast catalytic testing of catalyst libraries for oxidation reactions, Chemical Engineering Technology 23, 413.
Thorsteinson, E.M., Wilson, T.P., Young, F.G. and Kasai, P.H. (1978) The oxidative dehydrogenation of ethane over catalysts containing mixed oxides of molybdenum and vanadium, Journal of Catalysis 52, 116–132.
Liu, Y., Cong, P., Doolen, R.D., Guan, S. and Woo, L. (2001) Discovery from combinatorial heterogeneous catalysis: a new class of catalyst for ethane oxidative dehydrogenation at low temperatures, Book of Extended Abstracts of 4th World Congress on Oxidation Catalysis 1, 109–111.
Grubert, G., Wolf, D., Dropka, N., Kolf, S. and M. Baerns (2001) Rapid discovery of new catalytic materials for the oxidative dehydrogenation of ethane to ethylene by an evolutionary approach, Book of Extended Abstracts of 4th World Congress on Oxidation Catalysis 1, 113–119.
Hahndorf, I., Buyevskaya, O.V., Langpape, M., Grubert, G., Kolf, S., Guillon, E. and Baerns, M. (to be published) Experimental equipment for high-throughput synthesis and testing of catalytic materials, Chemical Engineering Journal.
Elmasides, C., Kondarides, D.I., Grünert, W. and Verykios, X.E. (1999) XPS and FTIR study of Ru/Al203 and Ru/TiO2 catalysts: reduction characteristics and interaction with a methane-oxygen mixture, J. Phys. Chem. B 103, 5227.
Elmasides, C, Kondarides, D.I., Neophytides, S.G. and Verykios, X.E. (2000) The oxidation state of Ru catalysts under conditions of partial oxidation of methane studied by XPS and FTIR spectroscopy, Stud. Surf. Sci. Catal. 130, 3083.
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Baerns, M., Buyevskaya, O., Grubert, G., Rodemerck, U. (2002). Combinatorial Methodology and its Experimental Validation by Parallel Synthesis, Testing and Characterization of Solid Catalytic Materials. In: Derouane, E.G., Parmon, V., Lemos, F., Ribeiro, F.R. (eds) Principles and Methods for Accelerated Catalyst Design and Testing. NATO Science Series, vol 69. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0554-8_4
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DOI: https://doi.org/10.1007/978-94-010-0554-8_4
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