Abstract
Acid catalysis plays a major role in industrial applications of catalytic processes. In particular, the use of microporous solid acid catalysts has an enormous impact in the petroleum refining industry, where large-scale processes, such as the catalytic cracking of heavy oil fractions, are carried out over very active zeolite catalysts. In this paper we will try to give an overview of the way one can characterise the acidity of a solid catalyst and used this information to predict the activity of the catalyst for a given acid catalysed reaction.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Laidler, K.J.(1987) Chemical Kinetics, 3rd Ed., Harper Collins, New York.
Ostwald, W. (1884) J. Prakt. Chem. 30, 39.
Arrhenius, S. (1888) Z. Phys. Chem. 2, 495.
Arrhenius, S. (1889) Z. Phys. Chem. 4, 244.
Arrhenius, S. (1899) Z. Phys. Chem. 28,317.
Dawson, H.M. and Powis, F. (1913) J. Chem. Soc., 2135.
Brönsted, J.N. (1923) Rec. Trav. Chim. 42, 718.
Brönsted, J.N. and Pedersen, K.J. (1923) Z. Phys. Chem. 108,185.
Brönsted, J.N. (1928) Chem. Rev. 5, 322.
Steinfeld, J.I., Francisco, J.S. and Hase, W.H. (1999) Chemical Kinetics and Dynamics, 2nd Ed, p. 136 and following., Prentice-Hall, London.
Thomas, J.M. and Thomas W.J. (1997) Principles and Practice of Heterogeneous Catalysis, p.616 and following, VCH, Weinheim.
Decroocq, D., Bulle, R., Chatila, S. Franck, J.P. and Jacquin, Y. (1978) Le Craquage Catalytique des Coupes Lourdes, Technip, Paris.
Masel, R.I. (2001) Chemical Kinetics and Catalysis, Wiley, New York.
Cardona-Martinez N. and Dumesic J.A. (1990) J. Catal., 125,427.
Auroux, A., Jin, Y.S. and Vedrine, J.C. (1988) App. Catal., 36, 323.
Hunger, A. and Szombathely, M.V. (1995) Z. Phys. Chem., 190,19.
Karge, H.G., Dondur, V. and Weitkamp, J. (1991) J. Phys. Chem., 95,283.
Ison, A. and Gorte, R.J. (1984) J. Catal., 89,150.
Costa, C., Lopes, J.M., Lemos, F., and Ramôa Ribeiro, F. (1999) Activity-Acidity Relationship in Zeolite Y. Part 2. Determination of the Acid Strength Distribution by Temperature Programmed Desorption of Ammonia, J. Molec. Catal. A Chem. 144,221.
Wang, X., Lemos, M.A.N.D.A., Lemos, F.and Ramoa Ribeiro, F. (2001) Activity-Acidity Relationships in Solid Acid Catalysis—a Quantum Chemical Study, Stud. Surf. Sci. Catal.133,501–506.
Cvetanovic, R.J. and Amenomiya, Y. (1967) Adv. Catal., 17, 103.
Cvetanovic, R.J. and Amenomiya, Y. (1972) Catal. Rev., 10, 21.
Sawa, M., Niwa M. and Murakami Y. (1990) Zeolite, 10,307.
Richards, R.E. and Rees, L.V.C. (1986) Zeolites, 6, 17.
Dima, E. and Rees, L.V.C. (1987) Zeolites, 7, 219.
Hashimoto, K., Masuda, T., and Mori, T. (1986) in Y. Murakmi, A. Lijima and J.W. Word (eds.), Stud. Surf. Sci. Catal.: New Developments in Zeolite Science and Technology, Elsevier, 28,503.
Forni, L. and Magni, E. (1988) J. Catal. 112,437–443
Forni, L., Magni, E., Ortoleva, E., Monaci, R. and Solinas, V. (1988) J. Catal., 112, 444.
Karge, H.G. and Dondur, V. (1990) J. Phys. Chem., 94, 765.
Hunger, B., Szombathely, M.V., Hoffmann, J. and Brauner, P. (1995) J. Therm. Anal., 44,293.
Auroux, A. and Vedrine, J.C. (1985) Stud. Surf. Sci. Catal., 20, 311.
Costa, C., Dzikh, LP., Lopes, J.M. Lemos F. and Ramôa Ribeiro, F. (2000) Activity-Acidity Relationship in Zeolite ZSM-5. Application of Brönsted Type Equations J. Mol Catal. A: Chem., 154,193–201.
Shannon, R.D., Gardner, K.G. and Staley, R.H. (1985) J. Phys. Chem., 89, 4778.
Chen, D.T., Sharma, S.B., Filimonov, I. and Dumesic, J.A. (1992) Catal Lett., 12, 201.
Garrone, E., Fubini, B., Bonelli, B. Onida, B. and Otero Areán, C. (1999) Phys. Chem. Chem. Phys., 1, 513.
Egerton T.A. and Stone, F.S. (1970) Trans. Faraday Soc., 66, 2364.
Li-Feng, C. and Rees, L.V.C. (1988) Zeolites 8, 310.
Rigby, A.M., Kramer, G.J., and. van Santen, R.A (1997) J. Catal 1, 170.
Wang, X., Lemos, M.A.N.D.A., Lemos, F, Costa, C. and Ramôa Ribeiro, F. (2001) Activity-Acidity Relationship in Y Zeolite: an Experimental and Quantum-Chemical Study, Stud. Surf. Sci. Catal., 135,259
Dumesic, J.A., Rudd, D.F., Aparicio, L.M., Rekoske, J.E. and Treviño, A.A. (1993) The Microkinetics of Heterogeneous Catalysis, ch. 11, American Chemical Society, Washington DC.
Marcus, R.A. (1955) J. Chem. Phys., 20, 359.
Marcus, R.A. (1968) J. Chem. Phys., 72, 891.
Gates, B.C. (1992) Catalytic Chemistry, John Wiley, New York.
Taylor, H.S. (1925) Proc. R. Soc. (London) A 108,105.
Constable, F.H. (1925) Proc. R. Soc. (London) A 108,355.
Halsey, G.D. (1949) J. Chem. Phys. 17, 758.
.Lemos, F., Ribeiro, M.F., Lopes, J.M. and Ramôa Ribeiro, (1989) A New Method for the Prediction of Zeolite Cracking Activity Based on Data from Temperature Programmed Desorption of Ammonia, Proceedings of Chempor 89, Lisbon, Portugal.
Costa, C., Lopes, J.M., Lemos, F. and Ramôa Ribeiro, F. (1997) Acidity-Activity Relationship in Zeolite Y. A Preliminary Study for n-Heptane Transformation, Catal Lett., 44, 255–251.
Costa, C., Lopes, J.M., Lemos, F. and Ramôa Ribeiro, F. (1999) Activity-Acidity Relationship in Zeolite Y. Part 3. Application of Brönsted Type Equations, J. Mol Catal. A.Chemical, 144 233–238.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Lemos, F. et al. (2002). Analysis and Modelling of Multi-Site Acid Catalysts. In: Derouane, E.G., Parmon, V., Lemos, F., Ribeiro, F.R. (eds) Principles and Methods for Accelerated Catalyst Design and Testing. NATO Science Series, vol 69. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0554-8_11
Download citation
DOI: https://doi.org/10.1007/978-94-010-0554-8_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-0721-7
Online ISBN: 978-94-010-0554-8
eBook Packages: Springer Book Archive