Skip to main content

29Si and 27A1 MAS NMR Study of Alkali Leached Kaolinite and Metakaolinite

  • Chapter
Magnetic Resonance in Colloid and Interface Science

Part of the book series: NATO Science Series ((NAII,volume 76))

  • 879 Accesses

Abstract

The alkali leaching of two aluminosilicates, kaolin and metakaolin with aqueous sodium hydroxide, has been studied. Both of these silicates give hydroxysodalite with or without the zeolite NaA as intermediate.

The crystallisation kinetics was studied first by X-ray powder diffraction. The progress of the reactions was also followed by high-resolution 29Si and 27A1 MAS-NMR spectroscopic monitoring of the signal ratio of the initial materials and the reaction products.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R.M. Barrer. Hydrothermal Chemistry of Zeolites, Academic Press, London, (1982).

    Google Scholar 

  2. D.W. Breck. Zeolite Molecular Sieves. J. Wiley and Sons, New York (1974).

    Google Scholar 

  3. J. Rocha, J. Klinowski. J. Phys. Chem. Miner. 17, 179, (1990).

    CAS  Google Scholar 

  4. G. Engelhardt, D. Michel. High resolution solid state NMR study of silicates and zeolites. J.Wiley and Sons, New York (1987).

    Google Scholar 

  5. J. Sanz, J. M. Serratosa. J. Am. Chem. Soc., 106, 4790–4793, (1984).

    Article  CAS  Google Scholar 

  6. J. Sanz., A. Madani., J. M. Serratosa, J.S. Moya, S. Aza. J.A.Ceram. Soc.,71, C–418, (1988).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2002 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Benharrats, N., Legrand, A.P., Belbachir, M. (2002). 29Si and 27A1 MAS NMR Study of Alkali Leached Kaolinite and Metakaolinite. In: Fraissard, J., Lapina, O. (eds) Magnetic Resonance in Colloid and Interface Science. NATO Science Series, vol 76. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0534-0_44

Download citation

  • DOI: https://doi.org/10.1007/978-94-010-0534-0_44

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0787-3

  • Online ISBN: 978-94-010-0534-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics